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《Chinese Journal of Analytical Chemistry》 2003-11
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Resonance Scattering Spectra Study on the Association Particle System of Berberine Hydrocholoride-Sodium Dodecylbenzene Sulfonate and Its Analytical Application

Zou Jieming 1, Pan Hongcheng 2, Jiang Zhiliang 2, Yuan Weien 2, Wang Lisheng 1 1(Guilin Sanjin Pharmaceutical Company Limited, Guilin 541004) 2(Department of Resource and Environmental Science, Guangxi Normal University, Guilin 541004)  
In pH 4.8 acetate buffer solution, the berberine hydrocholoride(BH +) and sodium dodecylbenzene sulfonate(DBS -) combine into hydrophobic (BH-DBS) n association particle by means of static gravitation and hydrophobic forces. There is a resonance scattering (RS) peak at 470 nm. With increasing DBS concentration, the peak enhances greatly, because there is enhanced scattering effect of association particle. And the berberine absorption peak at 345 nm decreases, that is, there is the fading effect. The influence of various factors on the determination of BH has been considered. A new RS method has been developed for the determination of (0.35~4.4)×10 -5 mol/L BH. Satisfactory results have been obtained for the determination of BH in Chinese traditional medicine samples.
【Fund】: 广西自然科学基金资助项目 (No .0 14 40 3 )
【CateGory Index】: O657.3
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