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《Chinese Journal of Analytical Chemistry》 2005-08
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Analysis of Saponins in Extract of Panax Ginseng andPanax Quinquofolium by Liquid Chromatography-Electrospray Ionization Mass Spectrometry

Li Li~(1,2), Liu Chunming~2, Wu Wei~1, Yue Hao~1, Liu Zhiqiang~(*1), Liu Shuying~1, Tian Cheng~3~1(Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022)~2(Department of Chemistry, Changchun Teachers College, Changchun 130032)~3(Manzhouli Inspection and Quarantine Technical Centre, Manzhouli 021400)  
A Liquid chromatography-electrospray ionizaiton mass spectrometry (LC-ESI-MS) method was (developed) for the identification and differentiation of ginsenosides in crude extracts from Panax ginseng and Panax quinquofolium L. The ~- ions of ginsenosides were observed in the negative mode, from which the molecular weights were obtained. The collision induced dissociation (CID) data of the ~- ions (provide) detailed structural information of the ginsenosides. By performing CID experiments for the peaks (3(ginsenoside Rf)) and 8(Pseudoginsenoside F11), these two ginsenosides had different CID behavior, and therefore the (assignment) of the structure for these two isomers was straightforward. The experimental results (indicate) that P. ginseng and P. quinquofolium can be differentiated rapidly and easily by the LC-ESI-MS (experiment).
【Fund】: 国家自然科学基金(No.20173057);; 中国科学院知识创新工程重要方向项目(No.KGCX2-SW-213-06);; 吉林省科技发展计划重大项目(No.20011109)资助项目
【CateGory Index】: O657.63;TQ461
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