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《Chinese Journal of Analytical Chemistry》 2006-11
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Supramolecular System of meso-Tetrakis(4-methoxyl-3-sulfonatophenyl) porphyrin with Cyclodextrins by Three Different Methods

Zhang Hongfen~(1,2),Pan Jinghao~(*1),Gao Xiaoling ~(1),Guo Yujing ~(1)~1(School of Chemistry and Chemical Engineering,Shanxi University,Taiyuan 030006)~2(School of Pharmaceutical Science,Shanxi Medical University,Taiyuan 030001)  
The supramolecular systems of water-soluble porphyrin, meso-terakis(4-methoxyl-3-sulfonato-(phenyl)) porphyrin(T(4-Mop)PS_(4)),with five cyclodextrins(CDs),including α-,β-,γ-cyclodextrin(α-CD,(β-CD),γ-CD),hydroxylpropyl-β-CD(HPβ-CD),sulfurbutylether-β-CD(SBE-β-CD),have been studied by polarography,ultraviolet spectrometry and fluorescence spectrometry.The results show that T(4-Mop)PS_(4) can interact with the five CDs and form 1∶1 supramolecular systems.The inclusion constants of the corresponding(supramolecular) systems were determined by polargraphy,ultraviolet-visible spectrometry and fluorescence spectrometry,respectively.Furthermore,the inclusion ability of different kinds of CDs with T(4-Mop)PS_4 was compared,which(provided) some elemental data for application of porphyrins and CDs.
【Fund】: 国家自然科学基金(No.20375024);; 山西省自然科学基金资助
【CateGory Index】: O641.3
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