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《Chinese Journal of Analytical Chemistry》 2011-06
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Application of Molecularly Imprinted Solid Phase Extraction for Determination of Estrogens in River Water,Milk and Urine Samples

XUE Min1,WANG An1,WANG Yu2,WANG Dan1,L Zhi1, MENG Zi-Hui1,ZHANG Wei-Bing2 1(School of Chemical & Environmental Engineering,Beijing Institute of Technology,Beijing 100081) 2(School of Chemistry & Molecularly Engineering,East China University of Science & Technology,Shanghai 200237)  
This paper describes the synthesis and use of a molecularly imprinted polymers(MIPs) against estradiol(E2) and ethynylestradiol(EE) as sorbents for on-column solid phase extraction of E2,EE and Diethylstilbestrol(DES) from aqueous complex samples.Combined with HPLC analysis,the method for estrogen determination based on molecularly imprinted solid phase extraction technology was developed,with lower detection limit of 0.1mg/L,and recovery rate above 80%.The method has been successfully applied to the analysis of estrogens in spiked river water,urine and milk samples,with recoveries of 88%,88% and 82% respectively.
【Fund】: 国家自然科学基金(No.20775007);; 853计划(No.2007AA10Z433);; 环境物理与化学国家重点实验室(No.KF2009-08)资助
【CateGory Index】: R123.1;R155.5
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Chinese Journal Full-text Database 7 Hits
1 ZHAO Huai-Xin1,SUN Xue-Jun1,SUN Zhi-Wei1,HU Bao-Jun1,LIU Qin-Ze1,ZHAO Xin-Quan2,YOU Jin-Mao1,21(College of Chemistry Science,Qufu Normal University,the Key Laboratory of Life-Organic Analysis,Qufu 273165)2(Northwest Plateau Institute of Biology,Chinese Academy of Sciences,Xining 810001);Enhancing Sensitivity for Atmospheric Pressure Chemical Ionization Mass Spectrometry with a Novel Labeling Reagent:Application for the Analysis of Estrogens Derivatives[J];Chinese Journal of Analytical Chemistry;2009-02
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