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《Chinese Journal of Analytical Chemistry》 2012-12
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Comparison of Mercury-free Microsensors Based on Gold Nanoparticles for Heavy Metals Detection

WANG Jin-Fen1,2,BIAN Chao1,TONG Jian-Hua1,SUN Ji-Zhou1,XIA Shan-Hong*1 1(State Key Laboratory of Transducer Technology,Institute of Electronics, Chinese Academy of Sciences,Beijing 100190,China) 2(Graduate University of Chinese Academy of Sciences,Beijing 100190,China)  
This paper presents two kinds of mercury-free electrochemical microsensors for simultaneous detection of heavy metals,which are L-aspartic acid/L-cysteine/gold nanoparticles(Asp/Cys/GNPs/microelectrode chip) and Sn film/gold nanoparticles modified microelectrode chip(Sn/GNPs/microelectrode chip).Electrochemical analysis of metal ions on Asp/Cys/GNPs/microelectrode chip was investigated by square wave voltammetry under the optimized conditions.The microsensor exhibited wide linear range from 5 μg/L to 2000 μg/L for Cu2+ and Pb2+ ions,with limit of detection of 1 μg/L.In situ tin film deposition was used in detection of heavy metals for the forming of alloy with heavy metals.Electrochemical analysis of metal ions on Sn/GNPs/microelectrode chip was investigated by square wave stripping voltammetry.The Sn/GNPs/microelectrode chip showed high sensitivity to Cu2+,Pb2+ and Zn2+ ions.This microsensor revealed good linear behavior in the examined concentration ranges from 5 to 500 μg/L for Cu2+ and Pb2+,from 10 to 500 μg/L for Zn2+,with a limit of detection of 2 μg/L for Cu2+,3 μg/L for Pb2+ and 5 μg/L for Zn2+.In addition,metal ions detection method using the two kinds of microsensor are green,simple,reused and compatible with the microfluid chip for on-site analysis.
【Fund】: 国家重点基础研究发展规划“973”项目(No.2009CB320300)资助
【CateGory Index】: O657.1;TP212
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【References】
Chinese Journal Full-text Database 1 Hits
1 PANG Jun;SONG He-xing;LIU Bo;GAO Wen-hui;College of Biological Science and Engineering,Hebei University of Science and Technology;;Rapid Determination of Hydrogen Peroxide Residues in Milk[J];China Dairy Cattle;2013-19
【Citations】
Chinese Journal Full-text Database 4 Hits
1 Gong Wei-Lei,Du Xiao-Yan,Wang Shu-Ran,Jiang Xian-Chen,Sun Qian(Public Health College,Harbin Medical University,Harbin 150081);Ex-situ Plating Bismuth Film on Platinum Electrode for the Determination of Trace Lead and Cadmium by Differential Pulse Stripping Voltammetry[J];Chinese Journal of Analytical Chemistry;2008-02
2 LIU De-Meng1,2,JIN Yan1,2,JIN Qing-Hui1,ZHAO Jian-Long11(State Key Lab of Transducer Technology,Shanghai Institute of Microsystem and Information Technology,Chinese Academy of Sciences,Shanghai 200050)2(Graduate School of the Chinese Academy of Sciences,Beijing 100039);Bismuth Microelectrode Array for Adsorptive Stripping Voltammetry to Detect Lead and Cadmium in Beverage[J];Chinese Journal of Analytical Chemistry;2011-11
3 LI Dong-Yue1,2,JIA Jian-Bo1,WANG Jian-Guo2 1(State Key Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry, Chinese Academy of Sciences,Changchun,130022) 2(College of Chemistry,Liaoning University,Shenyang 110036);Preparation and Application of Chemically Modified Bismuth Film Electrode[J];Chinese Journal of Analytical Chemistry;2012-02
4 LU Mei-bin,WANG Bu-jun,LI Jing-mei,LI Wei-xi,YANG Xiu-lan,SONG Jing-ke Institute of Crop Science,Chinese Academy of Agricultural Sciences and Supervision and Testing Center of Cereal Quality,Ministry of Agriculture,Beijing 100081,China;Research of Heavy Metals Determination in Cereals by Inductively Coupled Plasma Mass Spectrometry[J];Spectroscopy and Spectral Analysis;2012-08
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 SU Wen-bin(Faculty of Chemistry and Material Science,Lang Fang Teachers College,Langfang,Hebei 065000);Simultaneous Determination of Zinc and Copper in Foods by Differential Pulse Stripping Voltammetry Based on Bismuth-film Electrode[J];Journal of Anhui Agricultural Sciences;2011-03
2 YU Peng1, ZHANG Liangxiao1, CHEN Hui1, LUO Yueping2, SI Shihui1 1.College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China; 2.HunanEnvironmentalMonitoringCenter, Changsha 410004, China;Conductive Polymer Electrode for the Simultaneous Determination of Trace Copper,Lead,Cadmium,Zinc[J];Chinese Journal of Sensors and Actuators;2010-09
3 LIU De-Meng1,2,JIN Yan1,2,JIN Qing-Hui1,ZHAO Jian-Long11(State Key Lab of Transducer Technology,Shanghai Institute of Microsystem and Information Technology,Chinese Academy of Sciences,Shanghai 200050)2(Graduate School of the Chinese Academy of Sciences,Beijing 100039);Bismuth Microelectrode Array for Adsorptive Stripping Voltammetry to Detect Lead and Cadmium in Beverage[J];Chinese Journal of Analytical Chemistry;2011-11
4 LI Dong-Yue1,2,JIA Jian-Bo1,WANG Jian-Guo2 1(State Key Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry, Chinese Academy of Sciences,Changchun,130022) 2(College of Chemistry,Liaoning University,Shenyang 110036);Preparation and Application of Chemically Modified Bismuth Film Electrode[J];Chinese Journal of Analytical Chemistry;2012-02
5 SONG Wen-Jing1,2,WANG Xue-Wei1,DING Jia-Wang1,ZHANG Jun1,ZHANG Rui-Ming1,QIN Wei*1 1(Chinese Academy of Sciences and Shandong Provincial Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research,Chinese Academy of Sciences,Yantai 264003,China) 2(Graduate University of the Chinese Academy of Sciences,Beijing 100049,China);Electrochemical Sensing System for Determination of Heavy Metals in Seawater[J];Chinese Journal of Analytical Chemistry;2012-05
6 CHANG Yan-bing1,HE Qiong2(1.Proceed Education College of Qujing Normal University,Qujing 655000;2.Chemistry and ChemicalEngineering College of Qujing Normal University,Qujing 655000);Determination of Trace Lead and Cadmium in Waste Water by Anodic Stripping Voltammetry using Pre-plated Bismuth Film Electrode[J];Journal of Analytical Science;2010-04
7 Dan De-zhong,LENG Geng and HUANG Pu-xin(Department of Environmental Science and Engineering,Sichuan University,Chengdu 610065);Analysis of environmental samples[J];Chinese Journal of Analysis Laboratory;2010-07
8 LI Zhi-ying,XIAO Yang,ZHOU Chang-li and SUN Dan-zi(School of Chemistry and Chemical Engineering,University of Jinan,Jinan 250022);Electrocatalytic reduction of chloramphenicol on a bismuth/alizarin S film electrode[J];Chinese Journal of Analysis Laboratory;2011-03
9 ZHAO Wen-jing,WANG Zhen-hui and LI Quan-min(College of Chemistry and Environment Science,Henan Normal University,Henan Key Laboratory for Environmental Pollution Control,Xinxiang 453007);Studies on the fabrication and application of the bismuth film nichrome electrode[J];Chinese Journal of Analysis Laboratory;2012-02
10 MA Mei-Ping WANG Wen-Wei CAO Jian-Ming ZHENG Wei-Wei(School of Environmental Science and Public Health,Wenzhou Medical College,Wenzhou,Zhejiang 325035,P.R.China);Determination of Lead in the Popcorn by in Situ Plating-Bismuth Film Electrode[J];Chinese Journal of Spectroscopy Laboratory;2011-03
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 WANG Zhi-qin1,WANG Jun 2,XUE Zheng-fen2,WANG Tie-nan 2,LI Chun1,LUO Cui1,TANG Xiao-nan1(1.College of Animal Medicine,Xinjiang Agricultural University,Urumqi 830052,China 2.Xinjiang Academy of Animal Science,Urumqi 830000,China);The Research on the Quick Test-Paper of Detection for H_2O_2 Adulteration in Milk[J];Grass-Feeding Livestock;2010-03
2 ZHANG Ren-Yan,ZHANG Xue-Ao,JIA Hong-Hui,LI Xin-Hua(Institute of Project Physics,College of Science, National University of Defense Technology,Changsha 410073,China);An Formaldehyde Biosensor Based on Carbon Nanotubes Modified Electrode[J];Chinese Journal of Analytical Chemistry;2012-06
3 LI Zheng MA Yu-Tinga CHEN Yi WU Yingb(Yuhang District Center for Disease Control and Prevention,Hangzhou 311100,P.R.China)a(Yuhang District Supervising&Testing Center for Agricultural Product,Hangzhou 311100,P.R.China)b(College of Chemistry and Chemical Engineering,Suzhou University,Suzhou,Jiangsu 215123,P.R.China);Electrocatalytic Properties of Au Core-Pt Shell Nanoparticle-Glassy Carbon Modified Electrode for Nitrite[J];Chinese Journal of Spectroscopy Laboratory;2011-05
4 XIE Li1,DOU Yan-feng2,GUO Hui-can3,ZHANG Cong-sha1,SHI Wei1(1.Hebei Institute of Biology,Shijiazhuang 050081,China)(2.Shijiazhuang Pharmaceutical Co.,Ltd,Shijiazhuang 050051,China)(3.Shijiazhuang Vocational Technology Institute,Shijiazhuang 050051,China);Preparation of a Fast Test Paper for Hydrogen Peroxide in Food[J];Modern Food Science and Technology;2011-09
5 WANG Xiao-kun,SUN Zheng,ZHANG Xin-yan,GE Li-hua,MIAO Cong-cong,TIAN Zhen-chuan.Capital Medical University School of Stomatology,Beijing 100050,China.;Effect of hydrogen peroxide on 4NQO induced oral carcinogenesis[J];Beijing Journal of Stomatology;2012-03
6 LI Yueting,LIU Ying,WANG Jingxian,LI Jing,XIAO Tingting, WANG Aimin,LIAO Shanggao,WANG Yonglin(School of Pharmacology,Guiyang Medical College,Guiyang 550004,Guizhou,China);Damage Effect of Hydrogen Peroxide on Primary Cardiac Myocytes and H9c2 Cells[J];Journal of Guiyang Medical College;2012-03
7 Xia,Qianfang Huang,Yingjuan Yang,Xue Li,Zaijun(School of Chemical and Materials Engineering,Jiangnan University,Wuxi 214122);Preparation and Its Application of Novel Graphene/Gold/Functional Conducting Polymer/Hydrogen Peroxide Biosensor[J];Acta Chimica Sinica;2012-11
8 ZHANG De-xin1,CHENG Lu-ping2,YAO Qun-feng1(1.Hubei College of Traditional Chinese Medicine,Wuhan,430065,China2.Wuhan City No.3 Hospital,430062);The Fluorescence Spectrometric Determination of Hydrogen Peroxide Remaining in Food[J];Journal of Hubei College of Traditional Chinese Medicine;2007-04
9 LI Xiao-Xiaa,LI Yan-Qingb,MIAO Miaoa,MIAO Li-Xiaoa(a.College of Chemistry & Chemical Engineering;b.College of Life Sciences,Yan′an University,Yan′an 716000,China);Determination of Heparin at Polymethylene Blue-Multiwalled Carbon Nanotube Modified Electrodes[J];Journal of Henan University of Science & Technology(Natural Science);2011-02
10 DING Jian-ying1,SHEN Tang1,NI Wei-wei1,ZHANG Gen-hua1,ZHAN Yue-hua1,QUAN Ying1,HAN Jian-zhong2(1.College of Biotechnology and Food Engineering,Changshu Institute of Technology,Changshu 215500,China; 2.Food Quality and Safety Key Laboratory of Zhejiang Province,Zhejiang Gongshang University,Hangzhou 310035,China);Fabrication of Enzyme Biosensor for Hydrogen Peroxide Detection in Milk[J];Food Science;2011-22
【Secondary Citations】
Chinese Journal Full-text Database 8 Hits
1 Li Jianping 1,2, Peng Tuzhi 1, Zhang Xuejun 1 1(Department of Chemistry, Xixi Campus, Zhejiang University, Hangzhou 310028) 2(Department of Applied Chemistry, Guilin Institute of Technology, Guilin 541004);Determination of Lead, Cadmium, Zinc Using Bismuth-film Electrodes by Potentiometric Stripping Analysis[J];Chinese Journal of Analytieal Chemistry;2002-09
2 Huang Wensheng *, Yang Chunhai, Zhang Shenghui (Department of Chemistry, Hubei Institute of Nationalities, Enshi 445000);Anodic Stripping Voltammetric Determination of Cd~(2+) and Pb~(2+) Using Dithizone-Modified Glassy Carbon Electrode[J];Chinese Journal of Analytieal Chemistry;2002-11
3 Gong Wei-Lei,Du Xiao-Yan,Wang Shu-Ran,Jiang Xian-Chen,Sun Qian(Public Health College,Harbin Medical University,Harbin 150081);Ex-situ Plating Bismuth Film on Platinum Electrode for the Determination of Trace Lead and Cadmium by Differential Pulse Stripping Voltammetry[J];Chinese Journal of Analytical Chemistry;2008-02
4 LIU Lei YANG Yana(Laboratory of Chaidamu Comprehensive Geology Investigation Team,Golmud,Qinghai 816000,P.R.China)a(No.1 Middle School of Golmud,Golmud,Qinghai 816000,P.R.China);Determination of Trace Elements in Chinese Traditional Medicine by ICP-AES[J];Chinese Journal of Spectroscopy Laboratory;2010-05
5 PANG Yan-Hua XIAO Shan-Shan SUN Xing-Quan DONG Zhen-Lin YANG Chun-Guang(Liaoning Entry-Exit Inspection and Quarantine Bureau,Dalian,Liaoning 116001,P.R.China);Comparison Between ICP-MS and GFAAS for Determination of Lead and Cadmium in Alga Food[J];Chinese Journal of Spectroscopy Laboratory;2011-01
6 Fang Zheng-fa, Deng Wen-fang, Meng Yue, Tan Yue-ming, Huang Su-qing, Xie Qing-ji (Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, Ministry of Education, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China);Recent development of anodic stripping voltammetry at non-mercury electrodes and relevant bioanalysis applications[J];Chemical Sensors;2009-04
7 LIU Jun,CHEN Jian-ping(Guangdong Key Laboratory of Chemical Emergency Test,China National Analysis Center,Guangzhou 510070,China);Determination of Gemanium and Selenium in Ganoderma iucidum Spore Powder by Using ICP-MS with Microwave Digestion[J];Food Science;2008-12
8 XIE Nan,GE Yu,XU Hong-bin,CAO Cheng-ming(National Food Quality Supervision and Inspection Center(Shanghai),Shanghai Institute of Quality Inspection and Technical Research,Shanghai 200233,China);Determination of Lead,Arsenic,Cadmium,Chromium,Copper,Manganese,Zinc and Nickel in Spices by Inductively Coupled Plasma Mass Spectrometry with Microwave Digestion[J];Food Science;2011-02
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