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《Journal of Analytical Science》 1999-06
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Studies on the Polarographic Adsorptive Wave of Zinc (Ⅱ) 1,10 Pheneanthroline Complex

Li Xiuling * (Zhejiang University, Hongzhou , 310029) Lu Yan, Zhuo Changli, He Weibo (Department of Applied Chemistry, Shandong Institute of Building Materials Industry, Jinan, 250022)  
The electrochemical behaviour of Zinc (Ⅱ) 1,10 Pheneanthroline (phen) complex was investigated in a buffer solution of 0.087 mol/L NH 3 NH 4Cl(pH=10.06). The Zn(Ⅱ) phen complex produces a reduction peak at -1.06 V(vs.SCE). Under optimum conditions , the detection limit and the linear range of Zinc(Ⅱ) were 5.0×10 -9 mol/L and 4.0×10 -8 ~2.5×10 -6 mol/L, respectively. The method has been applied to the determination of zinc in hair, cayenne and mineral water with satisfactory results.
【CateGory Index】: O657.14
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