Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Analytical Science》 2006-04
Add to Favorite Get Latest Update

Inhibitory Kinetic Spectrofluorimetric Determination of Trace Phenol by Stop-flow Technique

MIAO Ji-gen~*,WU Xiao-hua,CHEN Jian-rong,FANG Ke-ming (College of Chemistry and Life Sciences,Zhejiang Normal University,Jinhua,Zhejiang 321004)  
The fluorescence quenching reaction of butyl rhodamine B oxidized by bromate ion with phenol as a suppressant in sulfuric acid medium by stop-flow technique has been investigated.The reaction mechanism has been discussed.A highly sensitive and simple inhibitory kinetic spectrofluorimetric method for the determination of trace phenol based on its effect on incubation period of the reaction was proposed.The detection limit was 1.4×10~-8 g·L~-1,the linear range was 0.4~15.0 μg·L~-1and the relative standard deviation(7.0 μg·L~-1,n=11) was 2.1% for phenol.The method has been applied to the determination of trace phenol in samples of pharmaceutical wastewater and ketchup with satisfactory results.
【Fund】: 浙江省分析测试基金(No.03099)
【CateGory Index】: O657.3;O625.3
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
Chinese Journal Full-text Database 2 Hits
1 DAN De-zhong,YAO Yu-ling and JIANG Wen-jing(Department of Environmental Science and Engineering,Sichuan University,Chengdu 610065);Analysis of environmental samples[J];Chinese Journal of Analysis Laboratory;2008-04
2 LI Ji-rui,YU Lian-ying(Hunan Techno-vocational College of Chemical Industry,Zhuzhou 412004,China);Application and Development of Stop-flow Spectroscopic Technique[J];Physical Testing and Chemical Analysis(Part B:Chemical Analysis);2009-03
Chinese Journal Full-text Database 10 Hits
1 Tang Guina, Wang Lijun, Wang Baoning(Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun 130022);Kinetic-Simultaneous Spectrophotometric Determination of Iron(Ⅱ) and Iron(Ⅲ) by Flow Injection-stopped Flow Technique[J];Chinese Journal of Analytieal Chemistry;1995-09
2 Liu Qinwei, Chen Guoshu * (Department of Chemistry and Material Science, Nanchang University, Nanchang 330047);Inhibitory Kinetic-Spectrophotometric Determination of Trace o-dinitrobenzene[J];Chinese Journal of Analytieal Chemistry;2001-03
3 Zhang Aimei, Wang Shuhao, Cui Hui (Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059);Kinetic Spectrophotometric and Fluorimetic Determination of Micro Amounts of Iodine Based on Its Inhibitory Effect in Nitrite-Potassium Bromate-Pyronine B System[J];Chinese Journal of Analytieal Chemistry;2001-10
4 Chen Yahong, Cai Ruxiu * (Department of Chemistry, Wuhan University, Wuhan 430072 );Highly Sensitive Determination of Nicotinamide Adenine Dinueleotide by Inhibited Spectrofluorimetry[J];Chinese Journal of Analytical Chemistry;2004-06
5 Gong Zhengjun 1 , Huang Yuming 2, Zhang Zhujun 2 1(School of Environment Science and Engineering, Southwest Jiaotong University, Chengdu 610031) 2(Institute of Analytical Science, Southwest Normal University, Chongqing 400715);Determination of Phenol with Luminol-Potassium Permanganate-Phenol Chemiluminescence System[J];Chinese Journal of Analytical Chemistry;2004-06
6 Sun Yanhua 1, Yang Jingzhi *2 , Zhou Jie 1, Fu Lei 1 (College of Chemistry and Material Science 1, College of Life Science 2, Shandong Agricultural University, Tai′an 271018);Determination of Trace Tryptophan and Tyrosine by Catalytic Spectrophotometry[J];Chinese Journal of Analytical Chemistry;2004-08
7 CHEN Wen li 1 , OUYANG Yi de 2, LI Lei 1, CHEN Zhong 2(1. Analysis and Test Center, Wuhan Institute of Chemical Technology;2.Department of Chemical Engineering, Wuhan Institute of ChemicalTechnology, Wuhan 430073);Determination of Salicylic Acid and Its Correlation Compound Using High Performance Liquid Chromatography[J];Journal of Analytical Science;2003-03
8 JIA Li-ping~1, ZHANG Ai-mei~(2*), NIU Xue-li~2 (1. Institue of Material Science and Engineering, Liaocheng University; 2. Institute of Chemistry and Chemical Technology,Liaocheng University, Liaocheng, Shandong 252059);Inhibitory Kinetic Spectrophotometric Determination of Trace Nitrilotriacetic Acid[J];Journal of Analytical Science;2004-02
9 WANG Rui-yong, CAI Ru-xiu~(*)(Department of Chemistry,Wuhan University,Wuhan 430072);Application of the Stopped-Flow Spectroscopy in Biomedical Analysis and Kinetic Mechanism[J];Journal of Analytical Science;2004-06
10 Hu Xiaoya et al. (Dept. Of Chem. Teacher'S School, Yangzhou Univ,Yangzhou 225002);Response Characteristics of Phenol on a Tyrosinase Biosensor[J];CHINESE JOURNAL OF ENVIROMENTAL SCIENCE;1995-03
Chinese Journal Full-text Database 10 Hits
1 DENG Wen-hong~1;ZHANG Feng-juan~2;JIN You-ju~1.1 Biology Center of Beijing Forestry University,100083,P.R.China;2 Department of Life Science,Hebei Normal University of Science & Technology,Changli County,066600,P.R.China.;Determination of salicylic acid in the plant tissues using RP-HPLC.[J];Journal of Beijing Forestry University;2007-01
2 WANG Lei, LIU Zhi-Jiang, ZHANG Dong (School of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang 110168, China);Simultaneous Determination of Chromium (Ⅴ) and Manganese (Ⅶ) in Industrial Wastewater by Differential Reaction Rate Kinetic Spectropbotometry[J];Materials Protection;2007-02
3 SU Xiao-huan Department of City and Environmental Science,City College of Dongguan University of Technology,Dongguan 523106,China; LU Ping Chemistry and Environment College,South China Normal University,Guangzhou 510006,China;Application of Inhibitory Kinetic Spectrophotometry in Determination of Organic Compound[J];Journal of Dongguan University of Technology;2007-03
4 ZHANG Zhen xin,SUN Deng ming,ZHU Qing ren,CHEN Hong (Department of Chemistry,Huaibei Coal Industry Teachers College,235000,Huaibei,Anhui,China);Determination of Trace Amounts of Iodine by Inhibition Kinetic Spectrophotometry[J];Journal of Huaibei Industry Teachers College (Natural Sciences Edition);2004-04
5 Miao Jigen, Chen Jianrong, Wu Xiaohua, Xu Jinya (Department of Chemistry, Zhejiang Normal University, Jinhua 321004) Cai Ruxiu, Zeng Yun' e (Department of Chemistry, Wuhan University, Wuhan 430072);Kinetic-Spectrophotometric Determination of Nickel With Xylenol Orange-Cetyltrimethylammonium Bromide-Nickel Ternary Complex System[J];Chinese Journal of Analytieal Chemistry;1997-02
6 Sun Dengming , Zhou Weiling (Department of Chemistry, Huaibei Coal Normal College, Huaibei 235000);Simultaneous Determination of Iron and Copper by Extraction-Catalytic Spectrophotometry[J];Chinese Journal of Analytieal Chemistry;2001-11
7 Gong Zhengjun, Huang Yuming, Zhang Zhujun * (Institute of Analytical Science, Southwest Normal University, Chongqing 400715);Determination of Phenol in Water by Flow-injection Chemiluminescence Analysis[J];Chinese Journal of Analytieal Chemistry;2002-09
8 Zhang Aimei *, Jia Liping, Niu Xueli (College of Chemistry and Chemical Technology, Liaocheng University, Liaocheng 252059);Inhibitory Kinetic Spectrophotometric Determination of Trace Oxalic Acid with Surfactant Sensitizer[J];Chinese Journal of Analytical Chemistry;2003-09
9 Liu Daojie *, Zhang Aimei, Tian Linqin (Department of Chemistry, Liaocheng University, Liaocheng 252059);Catalytic Kinetic Spectrophotometric Determination of Rutin by Potassium Peridate-Butyl Rhodamine B System[J];Chinese Journal of Analytical Chemistry;2003-10
10 Gong Zhengjun 1 , Huang Yuming 2, Zhang Zhujun 2 1(School of Environment Science and Engineering, Southwest Jiaotong University, Chengdu 610031) 2(Institute of Analytical Science, Southwest Normal University, Chongqing 400715);Determination of Phenol with Luminol-Potassium Permanganate-Phenol Chemiluminescence System[J];Chinese Journal of Analytical Chemistry;2004-06
China Proceedings of conference Full-text Database 1 Hits
1 Mu Dongyan (Beijing Tsinghua Novel Environmental Protection Co.,Ltd.);Study on A Tyrosinase-memberane Electrode Modified with Maltodextrin for Detection of Phenols[A];[C];2004
Chinese Journal Full-text Database 10 Hits
1 ZHOU Qing-xiang et al(Chemistry and Environmental Sciences College,Henan Normal University,Xinxiang,Henan 453007);Advances of Hyphenated Technique Coupled to Capillary Electrophoresis for Detection[J];Journal of Anhui Agricultural Sciences;2007-02
2 CHEN Jun-bo,ZHANG Bing(Anhui Provincial Center for Disease Control and Prevention,Hefei Anhui,230061,China);Investigation of Volatile Halohydrocarbons in Drinking Water by Headspace Capillary Gas Chromatography[J];Anhui Journal of Preventive Medicine;2007-04
3 SU Wen-hui GUO Yu-hua HOU Shao-gang (Department of Chemistry and Environmental Engineering, Anyang Institute of Technology, Henan Anyang 455000);A New Sample Pretreatment Technique:Liquid-Phase Microextraction[J];Journal of Anyang Institute of Technology;2006-04
4 Xing He Shi Jie (1.China National Environmental Monitoring Center,Beijing 100029,China) Wang Lingling (2.Henan Province Environmental Monitoring Center,Zhengzhou 450004,China);Status and Development on Analytical Mentods of Emergency Monitoring[J];Environmental Science and Management;2007-03
5 DONG JinBin1 WANG JinHua2 LU XiaoYu2 XU ChaoYi2 YANG JunJiao1 (1.School of Science,Beijing University of Chemical Technology,Beijing 100029; 2.Beijing Entry-Exit Inspection and Quarantine Bureau Technology Centre,Beijing 100026,China);Multi-residue determination of 42 pesticides in tea by gas chromatography-mass spectrometry[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2007-05
6 QIN Zong-hui~1,TAN Rong~2,FU Wei-quan~3(1.Department of Chemistry and Environmental Sciences,Fuling Normal College,Chongqing 408003,China;2.Fuling Pharmaceutical Factory,Tiji Group,Chongqing 408000,China;3.Chongqing Fuling Fifth Middle School,Chongqing 408000,China);Spectrophotometric Determination of Cationic Surfactants in Water with Coomassie Brilliant Blue G250[J];Journal of Jiangxi Normal University(Natural Sciences Edition);2006-05
7 ;URBAN ENVIRONMENT & URBAN ECOLOGY vol.19(2006)[J];Urban Environment & Urban Ecology;2006-06
8 YI Zheng-hui(Tianjin city construct college,Tianjin 300384,China);Design and implementation of distributed WebGIS on environment monitoring and analyzing[J];Science of Surveying and Mapping;2007-01
9 WANG Qian,SHAO Mi-hua,TAO Ping(Environmental Science & Eng.College,Dalian Maritime Univ.,Dalian 116026,China);Determination of total petroleum in halobios by fluorescence spectrophotometry[J];Journal of Dalian Maritime University;2006-01
10 QU Yuan-yuan~*,ZHOU Ji-ti,WANG Jing,XIA Yuan-hua,LIU Guang-fei,TAN Liang(School of Environ.and Biol.Sci.and Technol.,Dalian Univ.of Technol.,Dalian 116024,China);Novel approach for rapid extraction of genomic DNA from activated sludge and its fingerprinting analysis[J];Journal of Dalian University of Technology;2006-03
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Wang Zunben, Zheng Zhuzi and You Liufang (Department of Chemistry, Xiamen University);DETERMINATION OF COMPOSITIONS AND STABILITY CONSTANTS OF POLYNUCLEAR COMPLEXES BY STRAIGHT-LINE METHOD[J];Chinese Journal of Analytical Chemistry;1987-10
2 Hu Bin, Jiang Zucheng , Zeng Yun'e (Department of Chemistry, Wuhan University ,Wuhan 430072);Direct Determination of Microamount of Vanadium and Titanium in NIST Coal by Slurry Sampling Combined With Fluorination Assisted Electrothermal Vaporization-Inductively Coupled Plasma-Atomic Emission Spectrometry[J];Chinese Journal of Analytical Chemistry;1993-01
3 Gong Guoquan, Jia Li ,Su Chen (Department of Chemistry, Lanzhou University, Lanzhou 730000);A Fluorescence Quenching Method for the Determination of Trace Iodide With Dichlorofluorescein and Cetyl Pyridine Chloride[J];Chinese Journal of Analytieal Chemistry;1994-05
4 Li Xiuling, Lu Yan, Qu Lianjia, Chen Lu (Department of Applied Chemistry, Shandong Institute of Building Materals Industry, Jinan 250022);Study on the 1. 5th Order Differential Adsorption Voltammetry of Tin-Bathophenanline Complex[J];Chinese Journal of Analytieal Chemistry;1995-08
5 Liu Changjiu, Zhang Hua (Department of Applied Chemistry, Guilin Engineering College, Guilin 541004);Kinetic Spectrophotometric Determination of Trace of Iodine Based on Inhibitory Decoloration Reaction of Toluidine Blue[J];Chinese Journal of Analytieal Chemistry;1998-02
6 Wang Quanlin, Liu Zhihong, Yuan Hong, Cai Ruxiu (Department of Chemistry, Wuhan University, Wuhan 430072);Micelle Enhanced Catalytic-Fluorimetric Determination of Hemoglobin[J];Chinese Journal of Analytieal Chemistry;2001-04
7 Liu Wei, Li Baoxin, Zhang Zhujun (Department of Chemistry, Shaanxi Normal University, Xi'an 710062);A Chemiluminescence Method for the Determination of Rifampicin[J];Chinese Journal of Analytieal Chemistry;2002-01
8 Ding Yayun, Xie Mengxia , Kang Juan (Analytical & Testing Center, Beijing Normal University, Beijing 100875);Quantitative Analysis of Amino Acids in Protein Hydrolysates[J];Chinese Journal of Analytieal Chemistry;2002-04
9 Wang Hui 1, Dai Zhongpeng 1, Wang Li 2, Bai Jiling 2, Lin Bingcheng 1 (Biochemical Separation and Analysis Group 1, State Key Laboratory of Molecule Reaction Dynamics 2, Dalian Institute of Chemical Physics, Chinese Academic of Sciences;Enantiomer Separation of Amino Acids on Microchip-based Electrophoresis[J];Chinese Journal of Analytieal Chemistry;2002-06
10 Wang Quanlin 1, Liu Zhihong 2, Cai Ruxiu 2, Lü Gongxuan *1 1(State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000) 2(Department of Chem;Highly Sensitive Determination of Hydrogen Peroxide with Hemoglobin as Catalyst[J];Chinese Journal of Analytieal Chemistry;2002-08
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved