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《Journal of Analytical Science》 2006-06
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Study on Catalytic Reaction of Iron-(4-sulphophenyl) Porphyrin and Its Analytic Application

LUO Yong-jun~(1),HUANG Ying-ping~(*1),ZHU Sheng-ji~(1),LUO Guang-fu~(1),YUAN Ding~(2),LIU Li-min(1.Research Center for Eco-Environmental Sciences,China Three Gorges University,Yingchang,Hubei 443002;2.College of Medicine,China Three Gorges University,Yingchang,Hubei 443002)  
Iron-(4-sulphophenyl) porphyrin(FeTPPS_(4)) was used as a mimetic enzyme of Horeseradish Peroxidase(HRP).In the reaction system of FeTPPS_(4)/H_(2)O_(2)/MG,H_(2)O_(2) was catalyzed to oxidize the hydrogen-donor substrate Malachite Green(MG).Under the best reaction conditions,the apparent molar absorption for determination of H_(2)O_(2) was found to be 5.54×10~(3) L·mol~(-1)·cm~(-1) with a detection limit of 3.61×10~(-6) mol/L.The method was applied to the determination of trace H_(2)O_(2) in rain water,and used to detect the concentration of glucose with glucose oxidase(GOD) with a satisfied results.
【Fund】: 国家自然科学基金(No.20373074);; 宜昌市科技攻关项目(No.A04401-6)
【CateGory Index】: O643.32
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【Citations】
Chinese Journal Full-text Database 2 Hits
1 Huang Yingping 1 , Cai Ruxiu 2 1(Department of Chemistry, Three gorges University, Yichang 443000) 2(Department of Chemistry, Wuhan University, Wuhan 430072);Simulation in Enzyme Catalytic Reaction and Its Analytical Application[J];Chinese Journal of Analytieal Chemistry;2002-05
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【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 ZHAI Tong-yu,LIU Wei-hua(College of Science,Agricultural University of Hebei,Baoding 071001,China);Effects of the Solvent and the Micelle on Catalytic Activity of Glucose Oxidase[J];Journal of Baoding University;2008-04
2 Huang Yingping  (Department of Chemistry, Three gorge University, Yichang 443000) Cai Ruxiu (Department of Chemistry, Wuhan University, Wuhan 430072);A New Kinetic Method for the Determination of Laccase Activity Based on the Measure of the Intermediate[J];Chinese Journal of Analytieal Chemistry;2002-10
3 Huang Yingping  (Institute of Chemistry, Chinese Academy of Science, Beijing 100080) Cai Ruxiu (Department of Chemistry, Wuhan University, Wuhan 430072);The Study on the Micelle Enzyme Catalytic System Using Hemoglobin as Mimetic Peroxidase[J];Chinese Journal of Analytical Chemistry;2003-01
4 Huang Yingping 1, Luo Guangfu 1, Luo Yongjun 1, Cai Ruxiu 2 1(Department of Chemistry, Chinese three Gorges University, Yichang 443002) 2(Departerment of Chemistry, Wuhan University, Wuhan 430072);The Influence of Spatial Structures of Mimetic Peroxidases and Medium Microheterogenous for Enzyme Catalytic Reaction[J];Chinese Journal of Analytical Chemistry;2005-05
5 HUANG Ying ping 1 , LI Yang 1, CHEN Bai ling 1, YAN Ke mei 1, LUO Guang fu 1, CAI Ru xiu 2 (1.Department of Chemistry, The Three Gorges University, Yichang, 443003; 2. Department of Chemistry, Wuhan University, Wuhan, 430072);Studies on the Oxidation of Recessive Brilliant Green by H_2O_2 Catalyzed by Horseradish Peroxidase[J];Journal of Analytical Science;2003-02
6 HUANG Ying-ping*,FANG Yan-fen,XU Wen-nian,DAI Fang-xi,SONG Qiu-ju,ZHAO Cai-xia,ZHANG Yi(Research Center for Eco-Environmental Sciences,China ThreeGorges University,Yingchang,Hubei 443002);Determination of Phenol in Environmental Sample by Using the Mimetic Enzyme Catalytic Reaction[J];Journal of Analytical Science;2008-01
7 HUANG Xiu-ling1,WANG Qi-hui2,LIU Hui-hong*1,2(1.College of Chemistry,Central China Normal University,Wuhan 430079;2.Department of Chemistry & Biology,Xiangfan University,Xiangfan,Hubei 441053);The Electrochemistry and Electrochemical Catalysis of Hematin-agarose Modified Electrode[J];Journal of Analytical Science;2008-01
8 HUANG Ying-ping, LIU Feng, CHEN Bai-ling, LUO Guang-fu, YAN Ke-mei, LI Yang (Department of Chemistry, Three Gorges University, Yichang, 443003),Fenxi Shiyanshi,2003,22(1):12~15;Determination of hydrogen peroxide using hemoglobin as mimetic peroxidase[J];Analytical Laboratory;2003-01
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