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《Journal of Analytical Science》 2008-05
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Preparation and Evaluation of 2-Chlorophenol Imprinted Polymers by Bulk Polymerization

WANG Yan1,JING Tao1,BAO Xue-wei1,WANG Peng2,ZONG Xu-chen1,LIN Yan-fei2,ZHOU Yi-kai1,MEI Su-rong*1(1.MOE Key Lab of Environment and Health,Institute of Environmental Medicine,TongjiMedical College,Huazhong University of Science and Technology,Wuhan 430030;2.Hubei Entry-Exit Inspection and Quarantine Bureau of PRC,Wuhan 430022)  
A series of molecularly imprinted polymers were synthesized by bulk polymerization using 2-chlorophenol(2-CP) as the template,4-vinylpyridine(4-VP) as the functional monomer and trimethylolpropane trimethacrylate(TRIM) as the cross-linker.Selectivity and adsorption ability were evaluated by selectivity chromatography and static adsorption,respectively.The results indicated that the imprinted factor of the polymer was 1.71,the maximum number of binding sites Bmax was 0.1137 mmol/g and the polymer had the best selectivity and adsorption ability,when toluene was used as the porogenic solvent and the molar ratio of the functional monomer to the template was 2∶1.
【Key Words】: Molecular imprinting technology Molecularly imprinted polymers 2-chlorophenol
【Fund】: 国家自然科学基金(No.20407009 30771807);; 国家质检总局资助项目(No.2006-5)
【CateGory Index】: O631.3
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