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《Analytical Laboratory》 2003-02
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Determination of rifampin by hexacyanoferrate(Ⅲ) chemiluminescence system

ZHANG Yan tu, YANG Wei ping, ZHANG Zhu jun * and TIAN Sui kang (College of Chemistry and Materials Science,Shaanxi Normal University, Xi′an 710062), Fenxi Shiyanshi,2003,22(2):33~35  
A novel chemiluminescence(CL) method for determination of rifampin combined with flow injection analysis is presented in this paper. It was based on the CL reaction of rifampin and hexacyanoferrate(Ⅲ) in sodium hydroxide medium. The proposed method had a linear range of 0.1~30 mg/L with a RSD of 3% (1.5 mg/L, n =11) for rifampin. The detection limit was 0 06 mg/L. The method was applied to the determination of rifampin in its capsules and ocustilla.
【Fund】: 国家自然科学基金资助课题 (No .2 0 175 0 39)
【CateGory Index】: O657.32
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