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《Analytical Laboratory》 2003-05
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Determination of organophosphorus pesticides in environmental water by solid-ph ase microextraction coupled with gas chromatography-mass spectrometry

WANG Xin-ping,YANG Yun,LUAN Wei and LI Gong-ke*(Chemistr y an d Chemical Engineering School, Sun Yat-Sen University, Guangzhou 510275)  
A method for the determination of organophosphorus pesticides(OPPs) in e nvironmental water by solid-phase microextraction(SPME) coupled with gas chroma tography-mass spectrometry was developed. The studied OPPs were diazinon, methy l-parathion, parathion and isocarbophos. A polyacrylate (PA) fibre was u sed throughout the work. The experimental conditions of SPME, such as extraction time, pH and ion strength of the extraction solution, desorption temperature an d time were optimized. The linear ranges were from 0.001 to 10 μg/L for diazi non and isocarbophos, from 0.001 to 100 μg/L for methyl-parathion and parathio n. The detection limits were 0.015, 0.020, 0.013 and 0.039 μg/L for diazinon, m ethyl-parathion, parathion and isocarbophos, respectively. The method was used for the determination of trace OPPs in spiked tap water, mineral water and lake water samples, the recovery was from 89.0% to 102%, the RSD was from 2.1% to 1 4.1%.
【Fund】: 国家自然科学基金资助项目(29977029);; 广东省自然科学基金资助项目(990292)
【CateGory Index】: O657.63
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