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《Analytical Laboratory》 2005-11
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Study on electrochemical behavior of doparmine at a glassy carbon electrode modified with polymeric amino-β-cyclodextrine films

MA Jian-guo, PENG Dao-feng,LIU Yun-hai and YING Min(Applied Chhemistry Department of East China Institute of Technology,Fuzhou 344000)  
A polymeric 6-amino-6-deoxy-β-CD(PACD)thin film-modified glassy carbon electrode was prepared by electropolymerization.Then,its electrochemical behavior towards the oxidation of dopamine(DA) was investigated.Experimental results showed that PACD modified electrode could reduce the oxidation overpotential of DA in pH 6.0 phosphate buffer solution,and the oxidation peak current was proportional to the concentration of DA over the range from 4×10~(7) to 1.5×10~(-4)(mol/L)(r=0.9921)with a detection limit of 2.3×10~(-7)(mol/L).The methods have been applied to determine DA in some samples, and satisfactory results have been obtained.
【Fund】: 东华理工学院硕博基金资助项目(DHS0426)
【CateGory Index】: O657.1;O621.3;
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