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《Chinese Journal of Analysis Laboratory》 2006-12
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Simultaneous determination of palladium and gold in waste water by chemometric-spectrophotometry

ZHENG Jing~(*1),ZENG Jia~2,LIN Kai-li~3,ZHOU Wei-liang~4 and PAN Jiao-mai~4(1.Department of Chemical Engineering,Shanghai University of Science Technology,Shanghai 200065;2.Shanghai Environmental Monitoring Center,Shanghai 200050;3.Shanghai Institute of Ceramics,Chinese Academy of Sciences,Shanghai 200050;(4.Department) of Chemistry,East China Normal University,Shanghai 200062)  
A new highly selective reagent 5-(2-hydroxy-3,5-dimethyl-phenylazo)-rhodanine can react with Au(Ⅲ) and Pd(Ⅱ) to form a stable red complex with maximum absorption at 510 nm.Since the absorption spectra were seriously overlapped.In this paper,An artificial neural network-spectrophotometry method for simultaneous determination of Au(Ⅲ) and Pd(Ⅱ) in waste water was studied.The results are satisfactory.
【Fund】: 上海市重点学科建设(P1402)项目资助
【CateGory Index】: X832;O657.3
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