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《JOURNAL OF MOLECULAR CATALYSIS (CHINA)》 2000-01
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Effect of Promoters on the Hydrogenation Properties of Ni/Sepiolite Catalysts

LUO Lai tao, LI Song jun, DENG Geng feng, SONG Nen an (Institute of Applied Chemistry, Nanchang University, Nanchang 330047)  
Sepiolite modified by acid was used as the nickel catalyst support. A series of Ni/sepolite catalysts containing different promoters were prepared by impregnation. Methanation of CO 2 and benzene hydrogenation were selected as probe reactions. The activity and sulfur resistance of catalysts were investigated using the techniques of pulse and continuous microreactions. The surface of catalysts has been studied by XPS, CO absorption and H 2 TPD. The results show that both sepiolite and Sm can increase the catalytic activity, the sulfur resistance, the active surface area, and the electronic cloud density of the nickel atom, and decrease the activation energy of CO 2 methanation. At the same time, we found the proper temperature for CO 2 methanation on the basis of themodynamics.
【Fund】: 国家自然科学基金!(No.29863002);; 江西省自然科学基金!(No.982002)资助项目
【CateGory Index】: O643.38
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