Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Molecular Catalysis (China)》 2002-04
Add to Favorite Get Latest Update

Surface Acidity and the Catalytic Activity of ZSM-5 Zeolite

ZHANG Jin, XIAO Guo\|min (Department of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, China)  
The surface acidity of various modified ZSM\|5 zeolites with different SiO\-2/Al\-2O\-3 ratios has been determined quantitatively by TPD and IR technique. The catalytic activity in condensation reaction of aldehydes and ammonia has been correlated with the acidity of the zeolite catalysts. It is found that excessive acid sites can lead to by\|reactions and reduce the activity and selectivity of the catalyst when the ratios of SiO\-2/Al\-2O\-3 is low. The catalytic activity achieves the top and the yield of pyridine base is 60% when the ratio is about 120. CoZSM\|5 and FeZSM\|5 have less Lewis acid sites than HZSM\|5. The reducing of Lewis acid sites will decrease the ability of NH\-3 adsorption. This phenomenon insure that the exploring of adequate acid sites is favorable to reacting with aldehydes. Using CoZSM\|5 catalyst, the yields of pyridine base can come up to 78%.
【CateGory Index】: O643.32
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 10 Hits
1 WEN Yanlong,ZHANG Yuecheng,FENG Cheng,ZHANG Di,XU Weihua,ZHAO Jiquan School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China;Preparation of Polymetallic ZSM-5 Catalysts and Their Catalytic Performance for 2,6-Lutidine Synthesis[J];Chinese Journal of Catalysis;2011-01
2 HUANG Qi-wei, ZHANG Shi-ying(Department of Applied Chemistry and Environmental Science, Changsha University, Changsha 410003, China);Studies on Esterification Reactions of Carboxylic Acids over Silicoaluminophosphate Molecular Sieve Catalysts[J];Journal of Molecular Catalysis;2003-06
3 JIA Tai-xuan1,2,LIU Zi-li1,2,CHEN Sheng-zhou2,KE Gang2,LIANG Hong2(1.College of Chemistry & Chemical Engineering,Guangxi University,Nanning 530004,China;2.College of Chemistry & Chemical Engineering,Guangzhou University,Guangzhou 510006,China);Preparation of MoFe/HZSM-5 catalysts and study on its performance[J];Journal of Functional Materials;2009-04
4 HUANG Ke-lin1,3,WANG Ze-fen2,SUN Guo-song1,ZHANG Xue-wang1,MO Bin-hui1,WEI Yi1,2,WANG Gui-ying1,2,LIU Yu-hong1,NING Hong1(1.Guangxi Research Institute of Chemical Industry,Nanning 530001,China;2.School of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China;3.Guangxi Xinjing Science & Technology Co.,Ltd.,Nanning 530001,China);Synthesis Progress of Ethylenediamine[J];Technology & Development of Chemical Industry;2010-08
5 JIANG Jie, MAO Dong-sen, YANG Wei-min, LU Guan-zhong (1. School of Chemistry and Pharmacy , East China University of Science & Technology, Shanghai 200237, China; 2. Shanghai Research Institute of Petrochemical Technology, Shanghai 201028, China);Catalytic synthesis of alkylpyridine over Co-ZSM-5 zeolite[J];Industrial Catalysis;2003-08
6 SUN Shuhong1,WANG Ningsheng2,YAN Weijian3(1.Petrochemical Research Institute of PetroChina Lanzhou Petrochemical Company,Lanzhou 730060,Gansu,China;2.Catalyst Works of PetroChina Lanzhou Petrochemical Company,Lanzhou 730060,Gansu,China;3.Sinopec Ningbo Engineering Co.Ltd.,Ningbo 315103,Zhejiang,China);Advances in synthesis and modification of ZSM-5 zeolite[J];Industrial Catalysis;2007-06
7 LI Wensong~(1,2) ,LU Jun~(2*) , WU Legang~2(1. Kunming Institute of Precious Metals, Kunming 650106, Yunnan, China;2. Kunming Guiyan Catalysts Co. , Ltd. , Kunming 650101, Yunnan, China);Preparation of modified HZSM-5 catalytic material for purification of exhaust gases from natural gas fueled vehicles[J];Industrial Catalysis;2009-08
8 LI Xu~(1*), LIU Yan~1, CHEN Yongsheng~2, ZHANG Yi~1 (1. School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China; 2. CNOOC Tianjin Research & Design Institute of Chemical Industry, Tianjin 300131, China);Study on reaction condition of aldehyde-ammonia condensation catalyzed by Zn-ZSM-5 zeolite[J];Industrial Catalysis;2010-07
9 ZHANG Wei,REN Li-jun,GUAN Chong,QI Jing(Coal Chemical Company Research and Development Center,Shenhua Ningxia Coal Group, Ningxia Yinchuan 750411,China);The Overview on Synthesis,Modification and Application of Small Crystal ZSM-5 Molecular Sieve[J];Guangzhou Chemical Industry;2012-02
10 YANG Chao-qin1,WANG Ya-ming1,WU Le-gang2,LI Wen-song2(1.Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming 650500,China; 2.Kunming Sino-paltinum Metals Catalyst Co.Ltd,Kunming 650221,China);The Option of Molecular Sieve Material of the Exhaust Purifying Catalyst on CNG Vehicle[J];Bulletin of the Chinese Ceramic Society;2012-04
China Proceedings of conference Full-text Database 2 Hits
1 QIAO dan,SUN xiaoyan,XIANG shuguang (Hi-Tech Institute for Petroleum Refining and Chemical Industry,Qingdao University of Science and Technology, Qingdao 2660421);Quantum Chemistry Study on the Br nsted acidity of Ga modified ZSM-5 zeolite[A];[C];2013
2 QIAO dan;SUN xiaoyan;XIANG shuguang;Hi-Tech Institute for Petroleum Refining and Chemical Industry,Qingdao University of Science and Technology;;Quantum Chemistry Study on the Br?nsted acidity of Ga modified ZSM-5 zeolite[A];[C];2013
【Citations】
Chinese Journal Full-text Database 2 Hits
1 Xiao Guomin Zhang Jin (Department of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, China);Study on the Reaction Mechanistic of Vapor Phase[J];Journal of Southeast Univwrsity(Natural Science Edition);2001-05
2 ZHOU Huan wen 1,YU Shi jun 1,XU Jie 1,ZHU Dan 2 (1.Dalian Research Institute of Chemical Physics,Chinese Academy of Sciences, Liaoning Dalian 116012,China;2.Chemistry Department,Liaoning Normal University, Liaoning Dalian 11602;Development of and application prospect for the methods for catalytic synthesis of pyridine and its derivatives[J];Gongye Cuihua (Industrial Catalysis);2001-03
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 WEN Yanlong,ZHANG Yuecheng,FENG Cheng,ZHANG Di,XU Weihua,ZHAO Jiquan School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China;Preparation of Polymetallic ZSM-5 Catalysts and Their Catalytic Performance for 2,6-Lutidine Synthesis[J];Chinese Journal of Catalysis;2011-01
2 ZHOU Dan, FENG Ya-qing, MENG Shu-xian, FU Xue-jing (School of Chemical Engineering, Tianjin University, Tianjin 300072, China);Study on Preparation of Pyridine from Tetrahydrofurfuryl Alcohol Catalyzed by Pd/Al_2O_3[J];Journal of Chemical Engineering of Chinese Universities;2006-02
3 LI Xu~(1*), LIU Yan~1, CHEN Yongsheng~2, ZHANG Yi~1 (1. School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China; 2. CNOOC Tianjin Research & Design Institute of Chemical Industry, Tianjin 300131, China);Study on reaction condition of aldehyde-ammonia condensation catalyzed by Zn-ZSM-5 zeolite[J];Industrial Catalysis;2010-07
4 WANG Jia-ming(Sichuan Chemical Works Group Ltd.,Sichuan Chengdu 61030,China);Production Status and Market Prospect of Pyridine Alkali[J];Guangzhou Chemical Industry;2009-01
5 Geng Qingbao;Xue Lianhai;;Study on Synthesizing 2-Picoline[J];Journal of Chuzhou University;2014-02
6 Yang Fengfu Shi Yulong Ding Chunnian Sun Qiming(Red Sun Group Nanjing No.1 Pesticide Factory,Jiangsu Nanjing,211300);Study on Synthetic Technology of 2-methylpyridine and 4-methyipyridine[J];Chemical Industry Times;2004-11
7 Wang Jiaming(Sichuan Chemical Works Group Ltd.,Chengdu 610301,China);Production status and market prospect of polyphenylene sulfide fiber[J];Chemical Technology Market;2009-05
8 Zou Hua-sheng Pan Xue-min Lin Gang(School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China);Synthesis Technology of 2-Methylpyridine[J];Journal of South China University of Technology(Natural Science Edition);2008-11
9 XU Zhe,ZHANG Wei-hong,FENG Ya-qing,MENG Shu-xian(School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China);Preparation of Catalyst for Synthesizing Pyridine Using THFA as the Starting Material[J];Chemical Industry and Engineering;2011-06
10 ZHOU Dan~1,FENG Ya-qing~(1*),FU Xue-jing~1,ZHANG Jia-xin~2(1.School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China;2.Huai′an College of Information Technology,Huai′an 223001,Jiangsu,China);Preparation of Pyridine from Tetrahydrofurfuryl Alcohol with MoO_3/γ-Al_2O_3 Catalyst[J];Fine Chemicals;2005-10
China Proceedings of conference Full-text Database 1 Hits
1 ZHOU Dan FENG Ya-qing, MENG Shu-xian FU Xue-jing (School of Chemical Engineering, Tianjin University, Tianjin 300072, China)$$$$;Study on Preparation of Pyridine from Tetrahydrofurfuryl Alcohol with Pa/Al_2O_3[A];[C];2005
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Liu Li Chen fei(TheInspectionandExaminationInstituteoftheEnvironmentofHefei,230031);The Analysis and the Research of Control Countermeasure about Acid Rain Pollution of Hefei[J];Anhui Chemical Industry;2002-04
2 ZHANG Li-li(Anhui Medical & Pharmaceutical Design Institute,Hefei 230022,China);Characteristics,Upgrading and Application of Bio-oil[J];Anhui Chemical Industry;2011-02
3 ZHANG Yue et al (Institute of Fine Chemical Engineering,Jiangsu Polytechnic University,Changzhou,Jiangsu 213164);Study on the Modified Zeolites Catalytic to Prepare Pesticide Intermediate Acrylate with Butyl Lactate[J];Journal of Anhui Agricultural Sciences;2010-08
4 Cao Zhiqing Luo Mingrun (Dept.of Chem.);NON—MERCURIC COMPLEX CATALYST FOR THE SYNTHESIS OF VINYL CHLORIDE[J];Journal of Anhui Normal University(Natural Science);1986-04
5 SHAO Kang-qun ZHI Pei-hong SHEN Xia SONG Mei-na Pan Qiu-yue(Applied Engineering,Zhejiang Economic & Trade Polytechnic,Hangzhou Zhejiang 310018);Research Progress on Synthesis of Medium-chain Triglyceride[J];Modern Agricultural Sciences and Technology;2011-04
6 SHAO Kang-qun ZHI Pei-hong SHEN Xia SONG Mei-na PAN Qiu-yue (Department of Applied Engineering,Zhejiang Economic and Trade Polytechnic,Hangzhou Zhejiang 310018);Research on Catalytic Synthesis of Middle Chain Friglyceride with Solid Super Acid[J];Modern Agricultural Sciences and Technology;2011-07
7 XIE Youchang\ TANG Youqi (College of Chemistry and Molecular Engineering,Peking University,Beijing,100871);Spontaneous Dispersion of Oxides and Salts to Zeolites and Its Applications[J];ACTA SCICENTIARUM NATURALUM UNIVERSITIS PEKINESIS;1998-Z1
8 ZHANG Yuanhang\ SHAO Kesheng\ TANG Xiaoyan (Center of Environmental Sciences,Peking University, State Key Laboratory of Atmospheric Environmental Simulation,Beijing,100871) LI\ Jinlong (Department of Technical Physics,Peking University,Beijing,100871);The Study of Urban Photochemical Smog Pollution in China[J];ACTA SCICENTIARUM NATURALUM UNIVERSITIS PEKINESIS;1998-Z1
9 XING Jun ZHU JiQin LI JianWei LIU Hui LI ChengYue(State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Preparation of monolithic catalysts and their performance in the hydrodesulfurization of thiophene[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2009-06
10 BAI BingYang JIA ZhiGang JI ShengFu TIAN ShuXun LV DanDan(State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Preparation of HZSM-5/cordierite monolithic catalysts and their catalytic performance in methanol to olefin conversion[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2011-05
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 WEN Yanlong,ZHANG Yuecheng,FENG Cheng,ZHANG Di,XU Weihua,ZHAO Jiquan School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China;Preparation of Polymetallic ZSM-5 Catalysts and Their Catalytic Performance for 2,6-Lutidine Synthesis[J];Chinese Journal of Catalysis;2011-01
2 TANG Jianjun~(1,2),XU Yunshu~1 (1 Institute of Nuclear Physics and Chemistry,China Academy of Engineering Physics,Mianyang 621900; 2 School of Materials Science and Engineering,Southwest University of Science and Technology,Mianyang 621010);Research Progress of Microporous Material[J];Materials Review;2010-S2
3 ZHAO Xiu-tai,BAI Ying-rui,WANG Zeng-bao,SHANG Xiao-sen(School of Petroleum Engineering,China University of Petroleum(East China),Qingdao,Shandong 266555,China);Effect of sodium dodecyl benzene sulfonate-ethylenediamine on the crude oil emulsification[J];Journal of Daqing Petroleum Institute;2012-02
4 Ma Zhijun Zhang Kuan(College of Mining,Liaoning Technical University,Fuxin,Liaoning 123000);Preparation of Molecular Sieve with Natural Zeolite from Fuxin[J];Non-Metallic Mines;2011-06
5 GU Shan-shan,LIU Hong-run,LI Yan-xin,KONG Biao,KONG Xiang-guo,GAO Gen-zhi(Institution of Chemistry,Qufu Normal University,Qufu Shandong 273165,P.R.China);Synthesis of Alkylpyridine Compounds Catalyzed by Solid Super Acid[J];Journal of Liaoning University of Petroleum & Chemical Technology;2008-03
6 XU Hui-qing,LIU Quan-jie,JIA Li-ming(Fushun Research Institute of Petroleum and Petrochemicals SINOPEC,Fushun 113001,China);Effect of Pore Structure and Acidity of Molecular Sieves on C_8 Aromatic Performance[J];Journal of Molecular Catalysis;2012-03
7 Wang Yanfei,Huang Baohua,Fang Yanxiong,Zhang Kun(Faculty of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006,China);Research Progress of Catalysts System for Esterification[J];Guangdong Chemical Industry;2007-07
8 Li Xiaobao,Yan Yuhong,Ye Judi,Ma Yuejin(College of Chemical Engineering,Nanjing Forestry University,Nanjing 210037,China);Hydrolysis of Glucose to Levulinic Acid over SO_4~(2-)/ZrO_2 Catalyst[J];Guangdong Chemical Industry;2009-11
9 Li Xiaobao,Huang Qiuping,Luo Gongping,Ye Judi,Ma Yuejin (College of Chemical Engineering,Nanjing Forestry University,Nanjing,210037,China);Study on SO_4~(2-)/ZrO_2 Superacids Modified by Complex or Doping Metal ions for Preparation of Levulinic Acid[J];Guangdong Chemical Industry;2010-10
10 JIANG Jie MAO Dong-Sen * YANG Wei-Min * LU Guan-Zhong (College of Chemistry and Pharmaceuty, East China University of Science and Technology,Shanghai 200237,P.R.China) *(Shanghai Research Institute of Petro Chemical Technology,Shanghai 201208,P.R. China);Effects of Calcination on the NMR Spectra of Co-ZSM-5 Zeolite Catalyst Under Aldehyde-Ammonia Condensation[J];Chinese Journal of Spectroscopy Laboratory;2003-05
China Proceedings of conference Full-text Database 1 Hits
1 Kai Wang;Lin Yang;Qingjie Guo;College of Chemical Engineering,Qingdao University of Science and Technology;;Effect of modified CaO on bio-oil produced by catalytic pyrolysis of Nannochloropsis sp.[A];[C];2015
【Secondary Citations】
Chinese Journal Full-text Database 3 Hits
1 Chen Qian-jun, Wang Chang-chun, Zhou Shu-Ian, Zhang Boand Zheng Sheng-an (Department of Chemistry, Fudan University, Shanghai);THE ACID-BASE PROPERTIES AND CATALYTIC ACTIVITY OF MODIFIED ZSM-5 ZEOLITES[J];Chinese Journal of Catalysis;1990-02
2 Xiao Guomin Kong Xiangxiang (Department of Chemistry and Chemical Engineering, Southeast University, Nanjing, Postcode 210096);Study on Synthesis of 2 - ethyl -3,5- dimethylpyridine by Vapor - phase Method[J];Chemical Industry Times;1999-10
3 Xiao Guomin Wu Pingdong (National Laboratory of Secondary Resources, Chemical Engineering Department Zhejiang University, Hangzhou 310027);REACTION KINETICS OF VAPOR PHASE CYCLOCONDENSATION OF PROPIONALDEHYDE[J];CHEMICAL REACTION ENGINEERING AND TECHNOLOGY;1997-02
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved