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《Journal of Molecular Catalysis》 2005-05
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New Preparation Method and Catalytic Activity of Solid Superacid SO_4~(2-)/TiO_2 in Esterification to Form Dibutyl Phthalate

YANG Ke-er,QIU Hong-hua,TONG Shan-ling,YAN YanDepartment of Chemistry,Shantou University,Shantou,515063,Chin  
New preparation method of SO_4~2-/TiO_2 solid superacid is investigated by calcination of titanium white powder together with vitriol oil.The influences of the superacid synthesis conditions on the catalytic esterification of phthalic anhydride with 1-butanol to form dibutyl phthalate are examined in detail.Experimen shows that the yield of dibutyl phthalate can reach more than 99% when the esterification is carried out at 160 ℃ for 4 h.Abstract:New preparation method of SO42-/TiO2solid superacid is investigated by calcination of titanium white powder together with vitriol oil.The influences of the superacid synthesis cond itions on the catalytic esterification of phthalic anhydride with 1-butanol to form d ibutyl phthalate are exam ined in detail.Experimen shows that the yield of d ibutyl phthalate can reach more than 99% when the esterification is carried out at 160℃for 4 h.
【CateGory Index】: O643.32
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