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《Journal of Molecular Catalysis》 2007-02
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Degradation of 2-CEES (a Simulate Agent of Mustard) with Iron(II) Bipyridine/H_2O_2 System under Visible Irradiation

GUAN Chen1, 2 , XI Hai-ling1, ZHAO Jin-cai2, QIAO Jiang-bo1 , GUO Nan1 (1. The Academy of Chemical Defence, Beijing, 102205, China; 2. Laboratory of Photochemistry, Center for Molecular Sciences, Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, China)  
Degradation of 2-CEES(2-chloroethyl ethyl sulfide, a kind of stimulant of Mustard) using Iron(II) Bipyridine/H2O2 system (Photo-Fenton) under visible irradiation(λ450 nm)was reported. Effects of degradation reaction under different conditions were examined and the high active species which was produced during the reaction progress was confirmed by EPR. Products were analyzed with GC-MS and NMR, and also the evolution of TOC was followed. According to the results, the mechanism of the degradation of 2-CEES under visible irradiation was discussed.
【Fund】: 国家自然科学基金(No.20473113).
【CateGory Index】: O644.1
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