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《Journal of Molecular Catalysis》 2007-06
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Characterization and Catalytic Performance of Tungstophosphoric Acid Catalysts Supported on Activated Carbon

LIU Xiao-di,LIU Shi-rong(Southern Yangtze University,School of Chemical and Material Engineering,Wuxi 214122,China)  
The characterization of tungstophosphoric acid(TPA)catalysts supported on activated carbon and catalytic performance in synthesis of butylglycosides were studied.The supported catalysts were prepared by impregnation technique and characterized by FT-IR,XRD and SEM.The characterization results show that the Keggin structure of TPA remains unaltered after being supported on activated carbon.The adsorption process of TPA on activated carbon could be devided into three stages,which are monomolecular adsorption,multimolecular adsorption and packing of crystalline phase.There are complex relationship with the leaching amount of TPA,the TPA loading amount and the glucose conversion during the butylglycosidation.With the increase of TPA loading amounts the leaching amount of TPA increased,while there's no direct relation between the loading amount and the glucose conversion.When TPA loading amount increases from 5% to 60% the key factor controlling the catalytic activaty changes is acidity,specific surface area of the catalysts and amount of the leached TPA respectively.The optimal TPA loading amount on the activated carbon is 20%.
【CateGory Index】: O643.36
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3 ZHANG Hong-wu,MAO Ming-fu,LIU Shi-rong(School of Chemical and Materials Engineering,Jiangnan University,Wuxi 214122,China);Synthesis of alkyl polyglucosides using tungstophosphoric acid catalyst supported on activated carbon[J];Applied Chemical Industry;2009-06
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2 ZHANG Wei\|hua\+1, XU Yang\|zi\+2, ZHOU Li\|qun\+1, LEI Yu\+1, LIU Shi\|zhong\+1 (1. Faculty of Chemistry and Material Science, 2. Faculty of Physics and Electronic Technology, Huebi University, Wuhan 430062, China);Synthesis of Isopropyl Salicylate Catalyzed by New Type Nanoparticle Heteropoly Acid Catalyst H_3PW_(12)O_(40)/SiO_2[J];Journal of Molecular Catalysis;2003-04
3 ZHANG Yan-hong , ZHONG Shun-he(College of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China);Preparation and Characterization of SiO_2 Supported H_6PMo_9V_2Nb_1O_(40) Heteropoly Acid[J];Journal of Molecular Catalysis;2005-04
4 Wu Yue; Ye Xingkai; Yang Xiangguang; Wang Xinping; Chu Weiling; Hu Yucai (Changchun Institute of Applied Chemistry, the Chinese Academy of Sciences, Changchun 130022);Heterogenization of Heteropolyacids A General Discussion on the Preparation of Supported Acid Catalysts[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1996-04
5 YANG Shui-bin~1, ZOU Gui-mei~1, FU He-qing~2(1.Department of Chemistry, Huanggang Normal College, Hubei Huanggang 438000, China;2.Research Institute of Chemical Engineering, South China University of Technology, Guangdong Guangzhou 510640, China);Progress on Study of Alkyl Polyglycosides[J];Chemical Industry and Engineering;2005-04
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2 YIN Qiang,WU Quanzhou,LIAO Jufang,DENG Jingheng,LI Yuguang~*(School of Chemistry and Chemical Engineering,Sun Yat-Sen University,Guangzhou 510275,Guangdong,China);Synthesis and Characterization of Three-Dimensional Ordered Macroporous SiW_(12)/SiO_2 Hybrid Materials[J];Chinese Journal of Catalysis;2005-10
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6 KONG Ai-Guo,ZHANG Su-Mei,ZHANG Da-Wei,L Li-Li,JIN Chao,SHAN Yong-Kui~*(Department of Chemistry,East China Normal University,Shanghai 200062,China);Thermal Decomposition Behavior of Metal-oxygen Clusters with Keggin Structure[J];Chemical Research In Chinese Universities;2005-11
7 SONG Bo,ZUO Lin,ZHOU Ting (School of Chemistry and Chemical Enginering,Qiqihar University,Qiqihar 161006,China);Synthesis of alkyl polyglucoside sulfates with different alkyl groups[J];Journal of Science of Teachers' College and University;2009-02
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9 SONG Hua,Xü Qian,LI Zhengguang(College of Chemistry and Chemical Engineering,Daqing Petroleum Institute,Daqing 163318,Heilongjiang,China);Researches in the heteropoly compound catalysts for selective oxidation of isobutane[J];Industrial Catalysis;2008-09
10 DENG Pei-pei,LIU Zai-man,MIAO Li-jie,HAN Xiao-yan,XU Qing,WANG Bin(School of Chemical and Biological Engineering,Lanzhou Jiaotong University,Gansu Lanzhou 730070,China);The Research Status of Heteropoly Acid in Alkylation's Reaction[J];Guangzhou Chemical Industry;2009-02
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1 YANG Shui jin DU Xin xian LV Bao lan(Department of Chemistry and Environmental Engineering, Hubei Normal University, Hubei Huangshi 435002,China);Synthesis of acetals and ketals catalyzed by phosphotungstic acid supported on active carbon[J];Journal of Beijing University of Chemical Technology;2005-01
2 ISAO Ikeda 1 CUI Zheng gang 2 (1.Dept.of Appl.Chem.,Faculty of Eng.,Osaka University, Yamadaka2-1,Suita,Osaka 565,Japan; 2.School of Chem.and Material Eng., Wuxi University of Light Industry,Wuxi 214036,China);Synthesis and Properties of Novel Gemini Cationic Surfactants(1) ——Bis-quaternary Ammonium Salts with Two Alkyl Chains from Long-chain Alkyldimethylamine,Its Hydrochloride and Epichlorohydrin[J];China Surfactant Detergent & Cosmetics;2001-03
3 HUA Ping 1,ZHANG Yue jun 2 (1.Deparment of Chemical Engineering,Nantong Institute of Technology, Nantong 226007,China;2.School of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China);Study on the relationships between hexyl structures and processing conditions of preparing dihexyl sulfosuccinate[J];China Surfactant Detergent & Cosmetics;2002-02
4 JIA Li hua,GUO Xiang feng,YU Hong wei,DENG Qi gang (Chemical and Chemistry Engineering College of Qiqihaer University,Qiqihaer 161006,China);Synthesis of gemini cationic surfactants with ester bond[J];China Surfactant Detergent & Cosmetics;2002-03
5 ZHAO Jian-xi (Department of Chemistry,Fuzhou University,Fuzhou 350002,China);Oligomeric surfactants-controlling order-aggregate on the level of molecular structure[J];China Surfactant Detergent & Cosmetics;2002-03
6 JIN Rui-di,JIA Xue-ping,WANG Nan-ping (College of Chemistry and Chemical Engineering,Nantong University,Nantong 226007,China);Synthesis and properties of a new gemini surfactant[J];China Surfactant Detergent & Cosmetics;2007-03
7 GONG Hong, YANG Zhonghua, JIANG Heng *, SUN Zhaolin, ZHANG Xiaotong(Department of Material Science, Fushun Petroleum Institute, Fushun 113001, Liaoning, China);Role of Acidic Ligand for Clean Synthesis of Adipic Acid via Catalytic Oxidation of Cyclohexene[J];Chinese Journal of Catalysis;2002-02
8 Chen Zhiyong (College of Chemical and Chemical Engineering, Xinyang Normal University, Xinyang 464000);Catalytic Synthesis of Tri-butyl Citrate by Acidic Bentonite[J];Non-metallic Mines;2005-05
9 Hou Wenhua and Yan Qijie ( Chemistry Department, Nanjing University, Nanjing );CHARACTERIZATION OF SUPPORTED HETEROPOLYACIDS H_4SiMo_(12-n)W_nO_(40)/SiO_2[J];Journal of Molecular Catalysis;1990-01
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【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 LAN Ren hua OYANG Xin ping YANG Zhuo ru CHEN Huan qin [WT4”BZ](Research Institute of Chemical Engineering, South China University of Technology,Guangzhou 510641,China);Influence of Residual Alcohol on Properties of Alkyl Polyglycosides[J];China Surfactant Detergent & Cosmetics;2000-05
2 LIAN Wei LAN Ren hua OUYANG Xin ping CHEN Huan qin (Research Institute of Chemical Engineering, South China University of Technology,Guangzhou 510641,China);The Colour of Alkyl Polyglycosides and Decolored[J];China Surfactant Detergent & Cosmetics;2001-03
3 FAN Li Juan LIN Qiang (Institute of Chemical Engineering,Beijing United University,Beijing 100023,China);The New King of Catalysts for the Synthesis of Alkyl-Polyglycoside[J];China Surfactant Detergent & Cosmetics;2001-05
4 WANG Dawen, ZHONG Shunhe *(College of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China);Study on CuPMo/TiO_2 Catalyst for Direct Synthesis of Methacrylic Acid from Propylene and Carbon Dioxide[J];Chinese Journal of Catalysis;2003-09
5 MAO Xuan, YIN Yuan\|qi (State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000) WANG Hao, ZHONG Bang\|ke (Department of Chemistry, Jinan University, Guangzhou 510632);Heteropolyacid Catalysts for Selective Oxidation of Propene to Acrylic acid[J];Journal of Molecular Catalysis (China);2000-05
6 CHEN Song zhe, ZHONG Shun he, XIN Xiu lan, XIAO Xiu fen (College of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China);Laser Stimulated Surface Reaction of Methanol on Heteropoly Compounds[J];Journal of Molecular Catalysis (China);2001-05
7 CHEN Xiao\|rong, LI Yong\|dan, KANG Hui\|min, ZHANG Jin\|yan, ZHANG Liu (State Key Laboratory of C1 Chemical Technology, Department of Catalytic Science and Engineering, School of Chemical Engineering, Tianjin University, Tianjin 300072, China);Investigation of Interaction between SiO_2 and Keggin Heteropolyacids[J];Journal of Molecular Catalysis (China);2002-01
8 LI Li Dong, LI Wen Jiang, SUN Chang Qing  [WT5”BX](Department of Chemistry, Jilin University, Changchun 130023, China) [WT5HZ];Fabrication of Chemically-modified Electrode Containing 2∶18 Tungstophosphate Anions Based on Sol-gel Technique and Its Electrocatalysis[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-06
9 WANG Shi ming, HUANG Jin feng, ZHENG Ying, CHEN Li juan, WU Quan fa (Department of Chemistry, Fujian Normal University, Fuzhou 350007, China);Synthesis and Properties of Two New Charge Transfer Complexes of Vanadium Substituted Molybdophosphorate with Dawson Structure[J];Chinese Journal of Synthetic Chemistry;2002-02
10 QIN Yong, ZHANG Gao\|yong, KANG Bao\|an, ZHAO Yu\|mei, ZHOU Ji\|wei(China Research Institute of Daily Chemical Industry,Taiyuan\ 030001,China) ;Research on Primary Biodegradation of APG[J];Research of Environmental Sciences;2003-04
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