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《JOURNAL OF MOLECULAR CATALYSIS (CHINA)》 1995-03
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Study on the High Regioselective Synthesis of Para Myrac Aldehyde Catalyzed by Lewis Acids

Yin Dulin; Yin Donghong; Li Qianhe (Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081)  
The role of high regioselective synthesis of para myrac aldehyde catalyzed by Lewis acids was investigated systemmatically. The optimal reaction conditions were obtained. In the presence of ZnCl_2 catalyst, at 30℃ for 6h, the yield of myrac aldehyde was 70% (mol) and the content of para myrac aldehyde was as high as 94%(p/m≥15). The reaction mechanism catalyzed by ZnCl_2 was studied by UV, IR and  ̄1HNMR methods. It was found that the carbonyl of acrolein complexing with Zn ̄(2+) made the C=C bond polarized, which increased its activity and enhanced the regioselectivity of para myrac aldehyde.
【Fund】: 湖南省自然科学基金
【CateGory Index】: TQ655
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【References】
Chinese Journal Full-text Database 3 Hits
1 YIN Donghong *, YIN Dulin, FU Zaihui, LI Qianhe (College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, Hunan, China);Effects of Surface Acid Properties of Y Zeolite on ZnCl_2/HY Catalyst Prepared by Solid State Interaction under Microwave Irradiation[J];催化学报;2002-06
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【Citations】
Chinese Journal Full-text Database 4 Hits
1 Yin Dulin Ying Donghong (Institute of Fine Catalysis and Synthesis);STUDIES ON THE CATALYTIC MECHANTSM IN HIGHLY REGIOSELECTIVE SYNTHESIS OF PARA-METHYL MYRACLATE[J];湖南师范大学自然科学学报;1993-02
2 Yin Dulin Ying Donghong Li Xichan (Department of Chemistry);STUDIES ON THE DIELS-ALDER REACTION OF MYRCENE WITH METHYL ACRYLATE IN THE PRESENCE OF LEWIS ACID CATALYSTS[J];湖南师范大学自然科学学报;1992-02
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4 Zeng Zhaoguo Li Xicheng (Jiangxi Normal University Nanchang);SYNTHESIS OF MYRAC ALDEHYDE FROM β-PINENE[J];林产化学与工业;1986-04
【Co-citations】
Chinese Journal Full-text Database 8 Hits
1 Yang Ming;Hu Zhihua;Gong Shengzhao;Li Yu;Department of Chemical Engineering, Guangdong Industry Technological College;;Research Advance in Diels-Alder Reaction of Perfume[J];广东化工;2015-04
2 LI Qiu ting 1, LU Shun zhong 2 (1.College of Biotechnologh & Sugar Engineering, Guangxi University, Nanning 530001,China; 2.Guangxi Academy of Forestry, Nanning 530001,China);Synthesis of Myrac Aldehyde with Myrcene[J];广西化工;2002-01
3 Yin Dulin; Li Qianhe; Yin Donghong (Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha, 410081);Synthesis of Series Fine Chemicals from Rosin and Turpentine (Ⅱ)Preparation of Myrcene from the Heterogeneous Catalytic Isomerization of β-Pinene[J];湖南师范大学自然科学学报;1995-04
4 SHI Lei YU Shu-Wen LIAO Shi-Jian YU Dao-Rong SHEN Qi HONG Fang YU Shu-Zhen(Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian, 116023) (Department of Chemistry, Liaoning Normal University, Dalian, 116022) (Department of Chemistry, Suzhou University, Suzhou, 215006);Diels-Alder Reactions Catalyzed by the Mixed Rare Earth Chlorides[J];化学学报;1995-10
5 Yin Donghong; Yin Dulin; Li Qianhe(Institute of fine Catalysis and Synthesis, Hunan Normal University, Changsha, 410081);Studies on the Synthesis of Myrac Nitrile Catalyzed by Lewis Acids[J];湖南师范大学自然科学学报;1995-03
6 Yin Dulin; Yin Donghong; Li Qianhe (Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081);Study on the High Regioselective Synthesis of Para Myrac Aldehyde Catalyzed by Lewis Acids[J];分子催化;1995-03
7 Shi Lei;Tian Xing(Department of chemistry,Liaoning Normal University Chen Tiezheng Dalian 116022);SYNTHESIS OF BUTOXYPYRAN BY Diels-Alder REACTION CATALYZED BY LIGHT RARE EARTH CHLORIDES[J];辽宁师范大学学报(自然科学版);1994-01
8 Yin Dulin Ying Donghong (Institute of Fine Catalysis and Synthesis);STUDIES ON THE CATALYTIC MECHANTSM IN HIGHLY REGIOSELECTIVE SYNTHESIS OF PARA-METHYL MYRACLATE[J];湖南师范大学自然科学学报;1993-02
【Co-references】
Chinese Journal Full-text Database 6 Hits
1 YIN Dulin, YIN Donghong, LI Qianhe, FU Zaihui (Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081, China);Catalytic Performance of ZnCl_2/Y Catalyst Prepared by Solid State Microwave Irradiation for Rearrangement Reaction of α-Pinene Oxide[J];催化学报;2000-03
2 Yin Donghong, Yin Dulin, Fu Zaihui, Li Qianhe (Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081);ZnCl2/NaY CATALYST PREPARED BY SOLIDSTATE INTERACTION UNDERMICROWAVE IRRADIATIONThe DielsAlder Reaction of Myrcene and Acrolein over ZnCl2/NaY[J];催化学报;1999-04
3 Yin Donghong; Yin Dulin (Institute of Fine Cataheis and Synthesis, Hunan Normal University Changsha 410081);Study on the Solid-state Reaction of ZnCl2 and Y Zeolites under Microwave lrradiation[J];物理化学学报;1998-05
4 JIA Dian-Zeng; YANG Li-Xin; XIA Xi(Department of Chemistry, Xinjiang University, Urumqi, 830046)XIN Xin-Quan(Institute of Coordination Chemistry, Nanjing University, Nanjing, 210093);Studies on Application of Microwave Heating Techniques for the Solid State Reactions of Coordination Compounds(Ⅰ)── Synthesis of Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) Complexes by Solid State Reactions Under Microwave[J];高等学校化学学报;1997-09
5 WAN Xinmin XU Ruiqiu(Department of Chemistry ,Peking University ,Beijing , 100871);Syntheses of[α-Alkyl-β-(2,2,3-Trimethyl-3-Cyclopentenyl)Ethyl]Acetate[J];北京大学学报(自然科学版);1995-06
6 Yin Dulin; Yin Donghong; Li Qianhe (Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081);Study on the High Regioselective Synthesis of Para Myrac Aldehyde Catalyzed by Lewis Acids[J];分子催化;1995-03
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LIU Gao-wei;ZENG Gui-feng;ZHOU Yong-sheng;WANG Jian-hao;YAO Chao;WANG Che-li;School of Petrochemical Engineering, Changzhou University;School of Pharmaceutical Engineering & Life Science, Changzhou University;;Preparation and Characterization of Attapulgite Supported ZnCl_2 Catalyst for the Synthesis of C_(22)-Cycloaliphatic Fatty Acid Triesters[J];高校化学工程学报;2015-05
2 LIU Gao-wei;ZENG Gui-feng;ZHOU Yong-sheng;HUANG Ze-en;WU Kang;WANG Jian-hao;WANG Che-li;Changzhou University,School of Petrochemical Engineering;;Preparation of clay-supported ZnCl_2 catalyst and its catalytic Diels-Alder reaction[J];现代化工;2014-08
3 BO Longli LIU Hainan WANG Xiaohui ZHANG Hao SUN Jianyu YANG Li(School of Environmental and municipal Engineering,Xi’an University of Architecture and Technology,Xi'an,710055,China);Study on the catalytic oxidation of toluene under different heating modes[J];环境化学;2013-08
4 LIAN Jian-wei1,HUANG Kun1,WANG Mei1,TANG Xiao-dong1,LI Mei1,XIA Jian-ling*1,2(1.Institute of Chemical Industry of Forest Products,CAF;National Engineering Laboratory for Biomass Chemical Utilization;Key and Open Laboratory on Forest Chemical Engineering,SFA;Key Laboratory of Biomass Energy and Material,Nanjing 210042,China;2.Institute of New Technology of Forestry,CAF,Beijing 100091,China);Synthesis and characterization of 4-(4-methylpent-3-enyl)cyclohex-4-ene-1,2-dicarboxamide[J];化学试剂;2012-06
5 LIAN Jian-wei1,XIA Jian-ling1,2,YANG Xiao-hua1,HUANG Kun1,WANG Mei1(1.Institute of Chemical Industry of Forest Products,CAF;National Engineering Lab.for Biomass Chemical Utilization;Key and Open Lab.on Forest Chemical Engineering,SFA;Key Lab.of Biomass Energy and Material, Nanjing 210042,China;2.Institute of New Technology of Forestry,CAF,Beijing 100091,China);Synthesis and property of bis(2-ethylhexyl)-4-(4-methylpent-3-enyl)cyclohex4-ene-1,2-dicarboxylate[J];现代化工;2011-12
6 LIAN Jianwei1,XIA Jianling1,2,HUANG Kun1,YANG Xiaohua 1,WANG Mei1(1Institute of Chemical Industry of Forestry Products,Chinese Academy of Forestry;National Engineering Lab.for Biomass Chemical Utilization;Key and Lab.on Forest Chemical Engineering,State Forestry Administration,Key Lab.of Biomass Energy and Material,Nanjing 210042,Jiangsu,China;2Institute of New Technology of Forestry, Chinese Academy of Forestry,Beijing 100091,China);Research progress of application of β-myrcene in organic reactions[J];化工进展;2011-08
7 YANG Peng-fei1,2,ZHOU Ji-cheng1,REN Wen-ming1(1.Key Laboratory of Green Catalysis and Chemical Reaction Engineering in College of Hunan Province,School of Chemistry and Chemical Engineering Xiangtan University,Xiangtan 411105,China;2.School of Chemistry and Chemical Engineering,the South China of University,Hengyang 421001,China);Catalytic decomposition of nitrogen oxide over Cu/HZSM-5 catalysts prepared by different methods[J];燃料化学学报;2011-02
8 LIU Zhi-jun1,LIU Jin-hong1,2,HUANG Yan-fang1,YAO Hu-qing2(1.Department of Chemical Engineering,Nantong Vocational College,Nantong 226007,China;2.College of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China);Study on parparation conditions of Ni-Mo/AC catalyst[J];天然气化工(C1化学与化工);2009-03
9 CAI Yan-Hua1,2(1.School of Material Science and Engineering,Southwest University of Science and Technology,Mianyan 621010,China;2.School of Material Science and Engineering,Shanghai University,Shanghai 201800,China);Research Progress in Solid-State Reaction at Low-Heating or Moderate-Heating[J];化工技术与开发;2009-06
10 WANG Ji-lin,LI Li-hua,WANG Lu-lu,ZHANG Jin-sheng(School of Petrochemical Engineering,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,China);THE EFFECT OF MICROWAVE RADIATION ON THE PERFORMANCE OF FCC GASOLINE REDUCTION OLEFIN CATALYST[J];石油学报(石油加工);2007-04
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 Yin Dulin Ying Donghong Li Xichan (Department of Chemistry);STUDIES ON THE DIELS-ALDER REACTION OF MYRCENE WITH METHYL ACRYLATE IN THE PRESENCE OF LEWIS ACID CATALYSTS[J];湖南师范大学自然科学学报;1992-02
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