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Study on P450 Enzymic Model Compound with Calix arene\|bismetalloporphyrins.Catalytic Performance on the Epoxidation of Cyclohexene

LI Donghong CHEN ShuhuaZHAO Huaming (Department of Chemistry Sichuan University Chengdu 610064)  
Catalytic performance of P450 enzymic model compound with calix arene\|bismetalloporphyrins was studied and the effects of the properties of oxidant, temperature, substrate concentration, catalyst concentration, substituent on the benzene ring of porphyrin, and solvent, etc, on the reaction rate were investigated. The results show that calixarene\|bismetalloporphyrin has a much higher catalytic activity than the correspoding monometalloporphyrin, and the reactions obey the Michaelis\|Menten kinetic law. The excellent catalytic property of calixarene\|bismetalloporphyrin was a result of the multiple recognition and cooperative catalysis (macrocyclic ring of calix arene as the hydrophobic binding site and two metallporphyrins as the catalytic sites).
【Fund】: 国家自然科学基金
【CateGory Index】: O643.32
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