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《Journal of Textile Research》 2008-02
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Application of amino-terminated hyperbranched polymers in reactive dyeing of cotton fabrics

ZHANG Feng~(1,2),LIN Hong~1,LU Yanhua~3,CHEN Yuyue~1(1.School of Material Engineering,Soochow University,Suzhou,Jiangsu 215021,China;2.Department of Textile Engineering,Shazhou Institute of Technology,Zhangjiagang,Jiangsu 215600,China;3.College of Material and Chemical Engineering,Eastern Liaoning University,Dandong,Liaoning 118003,China)  
In order to achieve salt-free dyeing of cotton fabrics with reactive dyes,a water-soluble amino-terminated hyperbranched polymer(HBP-NH2) was synthesized from methyl acrylate and diethylene triamine by melt polycondensation.Cotton samples were pretreated with the aqueous solution of HBP-NH2(6 g/L) in the presence of citric acid(2 g/L) and sodium hypophosphite(3 g/L) and then dyed with reactive dyes.Results demonstrated that the pretreated cotton samples displayed markedly enhanced colour strength,and the washing fastness,rubbing fastness and levelling properties were satisfactory.It suggested that HBP-NH2can be applied in reactive dyeing of cotton fabrics as a salt-free auxiliary for various reactive dyes.
【Fund】: 教育部高等学校博士学科点专项科研基金资助项目(20060285004);; 江苏省研究生培养创新工程项目(CX07B-1512)
【CateGory Index】: TS193.8
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