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《Journal of Textile Research》 2008-11
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Mechanism of salt-free dyeing of HBP—NH_2 grafted oxidized cotton fabrics

ZHANG Feng~(1,2),CHEN Yuyue~1,ZHANG Desuo~1,HUA Yanrong~1,ZHAO Bing~1(1.School of Material Engineering,Soochow University,Suzhou,Jiangsu 215021, China;2.Department of Textile Engineering,Shazhou Institute of Technology, Zhangjiagang,Jiangsu 215600,China)  
In order to reveal the mechanism of salt-free dyeing of HBP—NH_2 grafted oxidized cotton fabrics(HGCF) with reactive dyes,the ζ-potential of HGCF in the liquid phase,dyeing thermodynamics,dyeing dynamics and hue changes of HGCF dyed with reactive dyes were examined.As a result,the ζ-potential of the HGCF is positive at pH′s lower than 6.5.The dyeing behaviour of reactive brilliant yellow A-4GLN on HGCF was found to follow a Langmuir-type adsorption curve,and the value of adsorption constant and saturated adsorbing capacity decreased when the temperature was raised,the dyeing entropy is(-4.51 kJ/mol.) Compared to ungrafted cotton fabrics,HBP—NH_2 grafted oxidized cotton fabrics can improve the speed of dyeing,the equilibrium dye uptake and the diffusion coefficients.Meanwhile,there was slight hue changes on HGCF dyed with reactive dyes in salt-free dyeing.
【Fund】: 高等学校博士学科点专项科研基金项目(20060285004);; 江苏省研究生培养创新工程项目(CX07B-151z)
【CateGory Index】: TS193.5
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