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《Guangdong Chemical Industry》 2011-04
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Teaching Experiment Design of N-butyl Acetate Green Synthesis

Huang Guowen,Gao Huanfang,Chen Zhi,Xu Junqiang,Li Jun,Quan Xuejun(College of Chemistry and Chemical Engineering,Chongqing university of Technology,Chongqing 400054,China)  
Environment-friendly sulphonated carbon materials were made from starch,and the n-butyl acetate were synthesized with sulphonated carbon materials and sulfuric acid.In comparison with the traditional process routes of n-butyl acetate that synthesized with sulfuric acid,the result showed that solid acid catalytic process routes had easily controled reaction conditions,safe and reliable,less by-products,simple post-treatment process,less waste water,catalyst easy to be recycled and reused.Based on the optimization experiment process,an organic synthesis experimental teaching programme had been designed out.Because of the esterification conversion calculated on the basis of collected water,the experimental process had been simplified.Teaching practices showed that students'learning enthusiasm and initiatives were aroused.The experiment design can be used in undergraduate organic synthesis experiment,green process design and kinetic teaching experiment.It will help to establish the environment-friendly chemical engineering laboratory.
【Fund】: 重庆理工大学高教研究项目(20100035);重庆理工大学实验技术开发基金(32-03)
【CateGory Index】: TQ225.241-4
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【Citations】
Chinese Journal Full-text Database 10 Hits
1 QU Zhenping1, TANG Xiaolan1, LI Xinyong1, CHEN Kai2, MA Ding2(1 Key Laboratory of Industrial Ecology and Environmental Engineering, MOE, School of Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, Liaoning, China; 2 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China);Degradation of Methyl Orange over Fe~(2+) Activated Sulphonated Carbon Catalyst[J];Chinese Journal of Catalysis;2009-02
2 DENG Bin1,3,ZHANG Ai-hua2,XU An-wu3(1.Department of Chemistry and Life Science,Xiangnan University,Chenzhou 423000,China;2.College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000,China;3.Hefei National Laboratory for Physical Sciences at Microscale,University of Science and Technology of China,Hefei 230026,China);Study on the Kinetics of Catalytic Synthesid of Esterification Using Nano Composite Solid Superacid SO_4~(2-)/CoFe_2O_4[J];Journal of Xiangnan University;2009-02
3 CHEN Rong-na1, LI qiu-rong1, LI Xiao-bo1, WANG Zhi-bin1 (1.College of Environment and Chemistry Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China);Study on catalytic behavior of cation exchange resin in synthesis of n-butyl acetate[J];Journal of Yanshan University;2005-01
4 Wang Gang Zhao Linyuang Liu Mingdeng (Institute of New Materials,Guangxi Normal University,3 Yucailu,Guilin,Guangxi,541004);The Kinetics of Esterification on Titanium Sulfate[J];GUANGXI SCIENCES;1999-01
5 Qiu Ting Huang Zhixian Cheng Chunbiao Wu Yanxiang (College of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou 350108,China);Kinetics of Synthesis of n-Butyl Acetate over Cation-Exchange Resin Catalyst[J];Chemical Reaction Engineering and Technology;2009-04
6 Tian Zhiming~(1,2) Deng Qigang~2 Yin Yanlei~2 Zhao Defeng~1 (1.State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian Liaoning 116012,China;2.College of Chemistry and Chemical Engineering of Qiqihar University,Qiqihar Heilongjiang 161006,China);Preparation of SBA-15 Molecular Sieve Modified with Lanthanum-SO_4~(2-)and Its Catalytic Activity in Synthesis of n-Butyl Acetate[J];Petrochemical Technology;2008-07
7 SUN Li,WANG Hai-bin,QIANG Gen-rong(Teaching Center of Chemistry Experiment,Zhejiang University of Technology,Hangzhou 310014,China);Exploration of green construction of the experimental teaching in organic chemistry[J];Experimental Technology and Management;2008-08
8 Xu Changlong1,Cao Xiaohua1,Liu Xinqiang1,Liu Minsheng 2(College of Chemistry and Chemical Engineering;Jiujiang University,Jiujiang 332005,China;2.Department of Chemistry,Xiaozhuang University,Nanjing 211171,China);Primary study on design of green chemical experiment[J];Experimental Technology and Management;2009-11
9 Zhou Hua,Qu Xiaoying,Yu Gaoqi (College of Chemical Engineering and Technology,Wuhan University of Science and Technology,Wuhan 430081,China);Synthesis of n-butyl acetate under the catalysis of nano solid superacid SO_4~(2-)/TiO_2[J];Journal of Wuhan University of Science and Technology(Natural Science Edition);2007-06
10 ZHANG Wan-dong,NIE Jian-ming,LIN Tong,KANG Hui-juan(Experiment Teaching Center of Chemistry and Chemical Engineering,Tianjin University,Tianjin 300072,China);Catalytic synthesis of n-butyl acetate with solid super acid——making green chemistry concept permeate into experimental teaching[J];Laboratory Science;2009-05
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 TIAN Xiao-yan1,MA Lan-ying1,LIU Wan-yi1,2(1.School of Chemistry and Chemical Engineering,Ningxia University,Yinchuan 750021,China;2.Key Laboratory of Energy Sources &Engineering,Ningxia University,Yinchuan 750021,China;);Synthesis of n-butylacetate catalyzed by activated carbon modified by H_2SO_4[J];Ningxia Engineering Technology;2007-01
2 JIN Feng-yuan(Liaoning Industry And Economic Information Center,Shenyang 110001,China);Research Progress of Catalysts for Synthesis of Butyl Acetate[J];Liaoning Chemical Industry;2010-01
3 Ouyang Yuzhu,Chen Xiaodong,Peng Xiaochun,Wang Yingchun;Research on Teaching of Fundamental Chemistry Experiment Based on Green Chemistry Concept[J];Higher Education in Chemical Engineering;2010-02
4 Li Huaizeng1,Yang Lina1,Liang Yong′an2,Liu Jing1(1.School of Petrochemical Technology,Liaoning University ofPetroleum & Chemical Technology,Fushun 113001,China;2.No 2 Crude Oil Plant of Fushun Petrochemical Company,PetroChina,Fushun 113001,China);Synthesis of n-butyl acetate catalyzed by high stable sulfoacid-supported mesoporous molecular sieve[J];Petrochemical Technology & Application;2010-03
5 WANG Dan-yang,KUANG Guo-zhu(College of Chemical Engineering,Dalian University of Technology,Dalian 116024,China);Process Analysis of Preparing Ethyl Acetate by Reactive Distillation[J];Liaoning Chemical Industry;2010-08
6 TIAN Zhi-ming1,DENG Qi-gang1,ZHAO De-feng2,LIU Mei-hua1(1.College of Chemistry and Chemical Engineering of Qiqihar University,Qiqihar 161006,China;2.State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116012,China);Solid Phase Synthesi and Catalytic Performance of Ce-SO_4~(2-)/SBA-15 Catalyst[J];Chinese Journal of Synthetic Chemistry;2010-06
7 TIAN Zhi-ming,DENG Qi-gang,LI Le-yuan(College of Chemistry and Chemical Engineering of Qiqihar University,Qiqihar 161006,China);Preparation and catalytic performance of ZrO_2/SO_4~(2-) supported in SBA-15[J];Chemical Reagents;2011-05
8 CAI Shu-lan,ZOU Li-ke,GUO Xiao-qun (Dept.of Chemistry,Sichuan University of Science & Engineering,Zigong 643000,China);Synthesis of n-Butyl Acetate Catalyzed by Nickel Sulfate[J];Journal of Sichuan University of Science & Engineering(Natural Science Edition);2008-01
9 ZHOU Guang-shuai1,XIANG Dan-bo2,ZHU Lin1,FAN Li1,XIE Chang-yu1(1.Graduate Student Department,Southwest Petroleum University,Chengdu 610500,China;2.Sichuan Tianhua Limited Liability Company,Chengdu 610500,China);Study on synthesis of N-propyl acetate by reactive distillation method with solid acid as catalyst[J];Applied Chemical Industry;2008-08
10 Wang Wenge, Wang Liqiu , Liu Changhou (Research Institute of Jinling Petrochemical Corporation,Nanjing Jiangsu 210046,China; School of Chemical Engineering,Dalian University of Technology,Dalian Liaoning 116012,China);Kinetics of a Novel Non-Acidic Catalyst Used to Produce DOP and Its Application in Industry[J];Petrochemical Technology;2004-06
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 LI Xiaoyun,MA Ding,BAO Xinhe(State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,The Chinese Academy of Sciences,Dalian 116023,Liaoning,China);Synthesis of Molybdenum Carbide Catalysts over Different Carbon Supports[J];Chinese Journal of Catalysis;2008-09
2 Dejuan LIN- a,b,Haibo PAN,Shuifa SHEN-a,Naisheng CHEN-a ,Jinling HUANG-a,Qiyu YANG-c and Hanhui ZHANG-c -aInstitute of Research on the Functional Materials,Fuzhou University,350 002 Fuzhou -bDepartment of Chemistry,Fujian Zhangzhou Teachers College,363000 Zhang zhou -cDepartment of Chemistry,Fuzhou University,350002 Fuzhou;FTIR Spectra of SO_4~(2-)/Fe_2O_3 Nanosolid Superacid[J];Spectroscopy and Spectral Analysis;2000-05
3 ZHOU Yuan,LIU Xin ling, WANG Huan long,DAI Li qing, YE Qi yue(Department of Applied Chemistry, Hunan Institute of Engineering,Hunan Xiangtan 411101,China);Synthesis of n-butyl acetate catalyzed by phosphotungstomolybdate heteropolyacid supported on activated carbon[J];Gongye Cuihua (Industrial Catalysis);2001-02
4 LI Chunsheng,ZHOU Chunhui,GE Zhonghua,LI Qingwei,CAI Ye(Laboratory of Advanced Catalyst Materials,College of Chemical Engineering,Zhejiang University of Technology,ZhejiangHangzhou 310014, China);Advances in supported mesoporous molecular sieve catalysts[J];Industrial Catalysis;2003-02
5 LI Qiu-rong,ZHAO Qian(School of Environmental and Chemical Engineering,Yanshan University,Qinhuangdao 066004,Hubei,China);Synthesis of n-butyl acetate catalyzed by solid S_2O_8~(2-)/TiO_2 superacid[J];Industrial Catalysis;2006-07
6 ZHANG Mingwei, Wang Li, GAO Dengzheng (College of Chemical and Environmental Engineering, Shandong University of Science & Technology, Qingdao 266510, Shandong, China);Preparation and catalytic performance of a novel water-tolerant SBA-15-SO_3H solid acid catalyst[J];Industrial Catalysis;2008-05
7 Yu Shitao; Wang Zhiqiang; Yang Jinzong(Dept Fine Chemicals, Dalian Univ Technol, Dalian, Liaoning, 116012);Structural Characterization of SO_4 ̄(2-)/TiO_2-Al_2O_3 Complex Solid Superacid[J];GONGYE CUIHUA (INDUSTRIAL CATALYSIS);1996-04
8 HAO Wen-zheng,YU Shao-ming,LU Ya-ling,CHENG Jun(School of Chemical Engineering, Hefei University of Technology, Hefei 230009, China);n-Butyl acetate synthesis catalyzed by SO_4~(2-) modifiedaluminium pillared interlayer clay[J];Journal of Hefei University of Technology(Natural Science);2005-04
9 Shan Qiujie(School of Chemistry and Chemical Engineering,Qiqihar University,Qiqihar 161006,China);Synthesis of n-butyl acetate by solid heteropolyacids catalyst[J];Journal of Chemical Industry & Engineering;2008-03
10 Duan, Xue Miao, Min Wang, Zuo-Xin Sun, Peng~* (Department of Applied, Chemistry, Beijing Institute of Chemical Technology, Beijing, 100029);A Study for Kinetics of the Esterification of Boric Acid under Non-isothermal Condition[J];Acta Chimica Sinica;1992-11
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