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《Chemical Research In Chinese Universities》 1983-06
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STUDIES ON RARE-EARTH COMPLEXES OF CROWN ETHER (Ⅲ)——COMPLEXES OF THE LIGHT RARE-EARTH AND YTTRIUM NITRATES WITH 2,3,11,12-TETRAPHENYL-1,4,7,10,13,16- HEXAOXO-2,11-CYCLOOCTADECADIENE

Wang Jingqiu, Yang Zhikuan, Wan Jie, Ji Zhenping and Xiao Wenjin(Department of Chemistry, Wuhan University, Wuhan)  
Six complexes of the light rare-earth (Ⅲ,Ⅳ)and Yttrium (Ⅲ) nitrates with the title ligand (Ⅲ) have been prepared in methyl-cyanide and benzene. The results of their elemental analyses, infrared spectra, NMR spectra, differential thermal analysis (DTA), thermogravimetry (TG), molar conductance and solubility preliminarily indicated: 1. These complexes are nonelectrolytes in methyl-cyanide; 2. The 1:1 complexes are formed with each Ln(Ⅲ,Ⅳ) ion; 3. Three series have been obtained with formulate Ln(NO3)3·crown ether (n) (Ln = La, Ce, Pr, Nd), Ce(NO3)4·crown ether (1) and Y(NO3)3·crown ether (Ⅲ)·5H2O, and 4. The co-ordination numbers of each Ln ion are about 9-12. The characteristics both thermal stability and solubility of Ln(NO3)3·crown ether (Ⅲ) Ln(NO3)3-dibenzo-18-C-6 and Ln(NO3)3·18-C-s ether were discussed.
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【References】
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【Citations】
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【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Yang Yansheng and Zhu Jiaqin (Department of Chemistry, Zhongshan University, Guangzhou);DETECTION OF COMPLEXATIOM BETWEEN CROWN ETHERS AND RARE EARTH IONS BY CHROMATOGRAPHIC METHOD[J];Chemical Research In Chinese Universities;1982-01
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7 Liang Fupei Qin Chengzhen He Hui(Department of Chemistry);SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF LIGHT RARE EARTH PICRATES WITH CROWN ETHER[J];Journal of Guangxi Normal University(Natural Science);1991-01
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【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Ren Jingqing, Li Lemin, Wang Xiuzhen, Hsu Kwanghsien Department of Chemistry;The INDO Method Applicable to the Electronic Structure Calculation of Lanthanide Compounds I. The Formulas Required for Computer Programming[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1982-03
2 Wu Jinlan Zhang Yonghua(Chang Yunhua) (Changchun Institute of Applied Chemistry,Acade(?)ia Sinica);Construction of a Rare Earth Ion-selective Electrode[J];Chinese Journal of Analytical Chemistry;1983-05
3 Wang Genglin, Yan Shiping and Li Xueyao (Department of Chemistry, Nankai University, Tianjin);STUDY ON SYNTHESIS ANp CHARACTERIZATION OF THE COMPLEX OF Eu (Ⅱ) PERCHLQRATE AND DIBENZO-18-CROWN-6[J];Chemical Research In Chinese Universities;1983-01
4 Tan Minyu, Wang Liufang and Ma Tairu (Department of Chemistry, Lanzhou University, Lanzhou)Shu Cisheng, Yu Lanping and Qian Limin (Coatinginstitute of Chemical Industry Department);STUDIES ON COMPLEXES OF RARE EARTH AND CROWN ETHERS(Ⅲ)——SYNTHESIS AND CHARACTERIZATION OF THE COMPLEXES OF Sc(NO3)3WITH o-BENZENEDIKE- TONES-17-CROWN-5 AND o-BENZENEDIKETO- NES-14-CROWN-4[J];Chemical Research In Chinese Universities;1983-03
5 Huang Zaifu and Yu Zongyuan (Department of Chemistry, Wuhan University, Wuhan);SYNTHESIS OF CROWN ETHERS FROM SATURATED URUSHIOL AND SEPARATION OF THEIR POSITIONAL ISOMERS[J];Chemical Research In Chinese Universities;1983-03
6 KAO YUAN NI JIAZAN (Changchun Institute of Applied Chemistry, Academia Sinica, Changchun);A STUDY ON THE EXTRACTION OF RARE EARTH ELEMENTS WITH CROWN ETHERS[J];Journal of Nuclear and Radiochemistry;1983-02
7 WAN ZHU-LI~* RAO ZI-HE LIANG DONG-CAI (Institute of Biophysics, Academia Sinica, Beijing) YAO XIN-KAN YAN SHI-PING WANG GENG-LIN (Department of Chemistry, Nankai University, Tianjin);THE MOLECULAR AND CRYSTAL STRUCTURE OF THE COMPLEX OF 1, 8-NAPHTHO-16-CROWN-5 WITH LANTHANUM NITRATE[J];Acta Chimica Sinica;1982-12
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【Secondary References】
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