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《Chemical Research In Chinese Universities》 1986-04
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Investigation of the Electrocatalytic Reduction of Carbon Dioxide (Ⅱ)——The Electrocatalytic Activity of Metallo-Porphyrins Under Different Conditions

Cao Xizhang, Mu Ying, Wang Maolian and Huang Chubao (Department of Chemistry, Jiiin University, Changchun)  
The catalytic activity of several water-soluble metallo-porphyrin complexes, M(Ⅱ)[p-N(CH3)3]TPPI (M = Co, Ni, Cu, Zn; [p-N(CH3)3]TPPI = tetrakis (4-trimethylammoniophenyl) porphyrin iodide), for the electroreduction of CO2 has been studied by means of controlled-potential electrolysis in aqueous solutions. It was found that Co( Ⅱ )[p-N(CH3)3]TPPI is active but other metalloporphyrins show no activity. In the presence of Co( Ⅱ )[p-N(CH3)3]TPPl the main product of CO2 reduction was CO, but small amounts of HCOOH were obtained. The effects of electrolytes, catalyst concentrations, electrode materials and potentials on the reduction of CO2 were investigated.
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【Citations】
Chinese Journal Full-text Database 2 Hits
1 Cao Xizhang, Huang Chubao and Wang Maolian (Department of Chemistry, Jilin University, Changchun);INVESTIGATION OF THE ELECTROREDUCTION OF CARBON DIOXIDE (Ⅰ)——ELECTROCATALYTIC ACTIVITY OF COBALT PORPHYRIN COORDINATION COMPOUND[J];Chemical Research In Chinese Universities;1983-05
2 Cao Xizhang, Xiu Zhengkun, Wang Maolian, Liu Zheiroag and Yu Lianxiang (Department of Chemistry, Jilin University, Changchun);Synthesis and Characterization of a New Water Soluble Cobalt Porphyrin Coordination Compound[J];Chemical Research In Chinese Universities;1985-01
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Cao Jun (Dept. of Chem.,Changsha Univ. of Electr. Power, Changsha, 410077) Liu Shengquan; He Lifuang; Shi Wei; Huang Suqiu (Wuhan Univ.,Wuhan,430070);STUDY ON THE PHYSICAL AND CHEMICAL PROPERTIES IN THE COORDINATE REACTION OF OCTAETHYLPORPHYRIN WITH CO(Ⅱ)[J];JOURNAL OF CHANGSHA UNIVERSITY OF ELECTRIC POWER(SOCIAL SCIENCE);1995-03
2 Cao Xizhang, Xiu Zhengkun, Wang Maolian, Liu Zheiroag and Yu Lianxiang (Department of Chemistry, Jilin University, Changchun);Synthesis and Characterization of a New Water Soluble Cobalt Porphyrin Coordination Compound[J];Chemical Research In Chinese Universities;1985-01
3 Cao Xizhang and Zheng Guodong (Department of Chemistry Jilin University, Changchun);Detection of the Intermediate of the Electrocatalytic Reduction of Carbon Dioxide Using Optically Transparent Thin-Laver Electrode[J];Chemical Research In Chinese Universities;1987-08
4 Cao Xizhang, Wang Qingmin, Shi Tongsun (Department of Chemistry, Jilin University, Changchun);Studies on Preparation and Carrying Oxygen of A New Tailed Porphyrincobalt(Ⅱ)[J];Chemical Research In Chinese Universities;1989-11
5 TURSUN Erkin1, AHMAT Dilbar2, AHTAMUVA Elinur1, YIMITI Abliz1(1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China; 2. School of Sciences, Xinjiang Education Institute,Urumqi 830043, China);Synthesis of Tailed Mono-5-{2-[1-(2-pyridylazo)-2-naphthyl]tetramethylene dioxy phenylene}-10,15,20-tri(4-chlorophenyl)Porphyrin and Its Pd~(2+) Complexes[J];Chinese Journal of Synthetic Chemistry;2008-04
6 Zeng Tian-Xian;Huang Jin-Wang;Cheng Te-Qiang;Ji Liang-Nian Chemistry Department, Zhongshan University, Guangzhou;Studies on the Polymerization and the Axial Coordination of Tetrakis-(p-trimethylammoniumphenyl) porphyrinatoiron (Ⅲ)-iodide Coordination Compound[J];Acta Chimica Sinica;1989-02
7 Cao Xi-Zhang;Zheng Guo-Dong;Teng Yong-Fu Department of Chemistry Jilin University, Changchun;Studies on the Electrocatalytic Reduction of Carbon Dioalde——IV. Studies on the Mechanism of the Electrocatalytic Reduction Reaction by Optically Thansparent Thin layer Electrode (OTTLE)[J];Acta Chimica Sinica;1989-06
8 Zheng, Guo-Dong Yan, Yan Cao, Xi-Zhang Xu, Ji-Qing(Department of Chemistry, Jilin University, Changchun, 130023)Gao, Sai (Department of Environment Science, Jilin University, Changchun, 130023)Tong, Shan-Ling(Changchung School of Light Industry, 130021)Gao, De(Department of Chemical Engineering, Hunan University, Changsha, 410082);Electrocarboxylation of Organic Compounds with Carbon dioxide Catalyzed by Metalloporphyrins Ⅰ. Catalytic Activities of Metalloporphyrins for Electrocarboxylation of Benzyl Chloride[J];Acta Chimica Sinica;1995-03
9 YANG Guo - Yu WANG Qing - Min ZHANG Jie YU Lian - Xiang CAO Xi - Zhang XU Ji - Qing(Department of Chemistry, Jilin University, Changchun, 130023);Studies on the Photochemical Reactions Catalyzed by Metalloporphyrin Complexes Ⅱ . Affect Photosensitized Reaction by AroundSubstituting Group and Axial Coordination of Metalloporphyrin Complexes[J];Acta Chimica Sinica;1996-04
10 Cao Xizhang, Wang Maolian, She Tongshun, Feng Yulan and Ding Yu (Department of Chemistry, Jilin University);STUDIES OF THE ADDUCTIVE PROPERTY OF METALLIC PORPHYRIN Co(Ⅱ)[p-N(CH_3)_3]TPPI WITH CO[J];Journal of Jilin University;1985-03
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Wang Xin, Xin Xin-quan and Dai An-bang (A. P. Tai) (Institute of Coordination Chemistry, Nanjing University);STUDIES ON THERMAL STABILITIES OF COORDINATION COMPOUNDS BY GAS CHROMATOGRAPHY XVI. THERMAL DECOMPOSITION OF SUPPORTED NICKEL FORMATE IN HELIUM[J];Chinese Journal of Catalysis;1986-03
2 Jiang Xuan-zhen, Bao Jian-bin, Chen Yan, (Department of Chemistry, Zhejiang University, Hangzhou)Liu Jin-xiang, (Dalian Institute of Chemical Physics, Academia Sinica)and Xu Song-yan (Fujian Institute of Structure of Matter, Academia Sinica, Fuzhou);STUDIES OF CARBON DIOXIDE HYDROGENATION OVER SUPPORTED PALLADIUM CATALYSTS[J];Chinese Journal of Catalysis;1988-02
3 Cao Xizhang, Huang Chubao and Wang Maolian (Department of Chemistry, Jilin University, Changchun);INVESTIGATION OF THE ELECTROREDUCTION OF CARBON DIOXIDE (Ⅰ)——ELECTROCATALYTIC ACTIVITY OF COBALT PORPHYRIN COORDINATION COMPOUND[J];Chemical Research In Chinese Universities;1983-05
4 DENG MIN-ZHI TANG YONG-TI LU DING-AN XU WEI-HUA (Shanghai Institute of Organic Chemistry,Academia Sinica);THE CHEMISTRY OF ORGANOBORATE——Ⅱ.STERIC CONFIGURATION OF MIGRATING GROUP IN THE REACTION OF TRIALKYLALKYNYLBORATE WITH CARBON DIOXIDE[J];Acta Chimica Sinica;1985-02
5 Deng Min-Zhi~* Lu Ding-An Lu Cheng-Yan Xu Wei-Hua(Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai);The Chemistry of Organoborate Ⅲ. The Order of Easiness of Migration for Various Alkyl Group in the Reaction of Trialkylalkynylborate with Carbon Dioxide and the Effect of Reaction Temperature[J];Acta Chimica Sinica;1986-01
6 Cao Xi-Zhang Mu Ying~* Wang Mao-Lian Luan Li(Department of Chemistry, Jilin University, Changchun);The Electrocatalytic Reduction of Carbon Dioxide Using Cobalt Tetrakis (4-trimethylammoniophenyl)-porphyrin under High Pressure[J];Acta Chimica Sinica;1986-03
7 Tian Zailong (Lanzhou Institute of Chemical Physics, Academia Sinica);THE STUDY ON F-COMPLEX Ce(acac)_3H_2O AS HOMOGENEOUS CATALYST FOR THE FIXATION REACTION OF CARBON DIOXIDE[J];Journal of Fuel Chemistry and Technology;1982-02
8 Chen Minsong Fan Dingye Yao Peifang Zhu Bingchen(East China Institute of Chemical Technology, Shanghai);INVESTIGATION OF THE ROLE OF CO_2 IN METHANOL SYNTHESIS UNDER PRESSURE OVER C301 COPPER-BASED CATALYST[J];Journal of Fuel Chemistry and Technology;1989-03
9 Shen Yuenian Guo Qingsong (Department of Chemistry, Inner Mongolia University, Huhehaote) Zhang Li Xi Lin (Service Centre of test, Science Committee of Inner Mongolia, Huhehaote);DISPERSION OF NICKEL AND La_2O_3 IN LOW-CONTAINING Ni-CATALYST OF METHANATION[J];Acta Physico-Chimica Sinica;1986-01
10 Qian Yanlong;Extraction with supercritical gases[J];Modern Chemical Industry;1984-04
【Secondary Citations】
Chinese Journal Full-text Database 2 Hits
1 Liu Guofa, Wang Yutian, Zhao Yongnian and Liang Yingqiu (Institute of Theoretical Chemistry, Jilin University, Changchun);RAMAN SPECTRA OF RARE EARTH ACETYLACETONATE COMPLEXES (Ⅱ)[J];Chemical Research In Chinese Universities;1983-01
2 Cao Xizhang, Huang Chubao and Wang Maolian (Department of Chemistry, Jilin University, Changchun);INVESTIGATION OF THE ELECTROREDUCTION OF CARBON DIOXIDE (Ⅰ)——ELECTROCATALYTIC ACTIVITY OF COBALT PORPHYRIN COORDINATION COMPOUND[J];Chemical Research In Chinese Universities;1983-05
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