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《Chemical Research In Chinese Universities》 1987-08
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Detection of the Intermediate of the Electrocatalytic Reduction of Carbon Dioxide Using Optically Transparent Thin-Laver Electrode

Cao Xizhang and Zheng Guodong (Department of Chemistry Jilin University, Changchun)  
In this work, optically transparent thin-layer electrode (OTTLE) was used to detect the intermediate of electrocatalytic reduction of CO2. The results showed that in the presence of imidazole (Im),the intermediate CO2·Co(Ⅰ) TMAPI·lm, was detected by UV/Vis absorption pectrum at-1.0V (SCE). The characteristic peaks were 434.0nm, 555.4nm and 603.6nm. We can come to the concolusion that CO 2 was activated by the formation of the intermediate CO2-Co(Ⅰ)-TMAPI.
【Fund】: 中国科学院科学基金
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Chinese Journal Full-text Database 1 Hits
1 Wei Quan, Guan Yousheng, Cao Xizhang (Department of Chemistry,Jilin University,Changchun);XPS Studies of Tetraphenyl-2-Nitro-porphyrin Metal Complexes[J];Chemical Research In Chinese Universities;1989-02
Chinese Journal Full-text Database 1 Hits
1 Cao Xizhang, Xiu Zhengkun, Wang Maolian, Liu Zheiroag and Yu Lianxiang (Department of Chemistry, Jilin University, Changchun);Synthesis and Characterization of a New Water Soluble Cobalt Porphyrin Coordination Compound[J];Chemical Research In Chinese Universities;1985-01
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1 Cao Xizhang, Mu Ying, Wang Maolian and Huang Chubao (Department of Chemistry, Jiiin University, Changchun);Investigation of the Electrocatalytic Reduction of Carbon Dioxide (Ⅱ)——The Electrocatalytic Activity of Metallo-Porphyrins Under Different Conditions[J];Chemical Research In Chinese Universities;1986-04
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1 Cao Xizhang and Mu Xihai (Department of Chemistry, Jilin University, Changchun);Studies on Carbon Monoxide Complex of a New Tailed Porphyriniron[J];Chemical Research In Chinese Universities;1986-01
【Secondary References】
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1 Cao Xizhang, Huang Chubao and Wang Maolian (Department of Chemistry, Jilin University, Changchun);INVESTIGATION OF THE ELECTROREDUCTION OF CARBON DIOXIDE (Ⅰ)——ELECTROCATALYTIC ACTIVITY OF COBALT PORPHYRIN COORDINATION COMPOUND[J];Chemical Research In Chinese Universities;1983-05
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