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《Chemical Research In Chinese Universities》 1987-08
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Detection of the Intermediate of the Electrocatalytic Reduction of Carbon Dioxide Using Optically Transparent Thin-Laver Electrode

Cao Xizhang and Zheng Guodong (Department of Chemistry Jilin University, Changchun)  
In this work, optically transparent thin-layer electrode (OTTLE) was used to detect the intermediate of electrocatalytic reduction of CO2. The results showed that in the presence of imidazole (Im),the intermediate CO2·Co(Ⅰ) TMAPI·lm, was detected by UV/Vis absorption pectrum at-1.0V (SCE). The characteristic peaks were 434.0nm, 555.4nm and 603.6nm. We can come to the concolusion that CO 2 was activated by the formation of the intermediate CO2-Co(Ⅰ)-TMAPI.
【Fund】: 中国科学院科学基金
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【References】
Chinese Journal Full-text Database 1 Hits
1 Wei Quan, Guan Yousheng, Cao Xizhang (Department of Chemistry,Jilin University,Changchun);XPS Studies of Tetraphenyl-2-Nitro-porphyrin Metal Complexes[J];Chemical Research In Chinese Universities;1989-02
【Citations】
Chinese Journal Full-text Database 1 Hits
1 Cao Xizhang, Xiu Zhengkun, Wang Maolian, Liu Zheiroag and Yu Lianxiang (Department of Chemistry, Jilin University, Changchun);Synthesis and Characterization of a New Water Soluble Cobalt Porphyrin Coordination Compound[J];Chemical Research In Chinese Universities;1985-01
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Cao Xizhang, Mu Ying, Wang Maolian and Huang Chubao (Department of Chemistry, Jiiin University, Changchun);Investigation of the Electrocatalytic Reduction of Carbon Dioxide (Ⅱ)——The Electrocatalytic Activity of Metallo-Porphyrins Under Different Conditions[J];Chemical Research In Chinese Universities;1986-04
2 Cao Xizhang, Wang Qingmin, Shi Tongsun (Department of Chemistry, Jilin University, Changchun);Studies on Preparation and Carrying Oxygen of A New Tailed Porphyrincobalt(Ⅱ)[J];Chemical Research In Chinese Universities;1989-11
3 Cao Jun (Dept. of Chem.,Changsha Univ. of Electr. Power, Changsha, 410077) Liu Shengquan; He Lifuang; Shi Wei; Huang Suqiu (Wuhan Univ.,Wuhan,430070);STUDY ON THE PHYSICAL AND CHEMICAL PROPERTIES IN THE COORDINATE REACTION OF OCTAETHYLPORPHYRIN WITH CO(Ⅱ)[J];JOURNAL OF CHANGSHA UNIVERSITY OF ELECTRIC POWER(SOCIAL SCIENCE);1995-03
4 TURSUN Erkin1, AHMAT Dilbar2, AHTAMUVA Elinur1, YIMITI Abliz1(1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China; 2. School of Sciences, Xinjiang Education Institute,Urumqi 830043, China);Synthesis of Tailed Mono-5-{2-[1-(2-pyridylazo)-2-naphthyl]tetramethylene dioxy phenylene}-10,15,20-tri(4-chlorophenyl)Porphyrin and Its Pd~(2+) Complexes[J];Chinese Journal of Synthetic Chemistry;2008-04
5 YANG Guo - Yu WANG Qing - Min ZHANG Jie YU Lian - Xiang CAO Xi - Zhang XU Ji - Qing(Department of Chemistry, Jilin University, Changchun, 130023);Studies on the Photochemical Reactions Catalyzed by Metalloporphyrin Complexes Ⅱ . Affect Photosensitized Reaction by AroundSubstituting Group and Axial Coordination of Metalloporphyrin Complexes[J];Acta Chimica Sinica;1996-04
6 Zeng Tian-Xian;Huang Jin-Wang;Cheng Te-Qiang;Ji Liang-Nian Chemistry Department, Zhongshan University, Guangzhou;Studies on the Polymerization and the Axial Coordination of Tetrakis-(p-trimethylammoniumphenyl) porphyrinatoiron (Ⅲ)-iodide Coordination Compound[J];Acta Chimica Sinica;1989-02
7 Cao Xi-Zhang;Zheng Guo-Dong;Teng Yong-Fu Department of Chemistry Jilin University, Changchun;Studies on the Electrocatalytic Reduction of Carbon Dioalde——IV. Studies on the Mechanism of the Electrocatalytic Reduction Reaction by Optically Thansparent Thin layer Electrode (OTTLE)[J];Acta Chimica Sinica;1989-06
8 Zheng Guodong, Shi Tongshun and Cao Xizhang (Department of Chemistry, Jilin University, Changchun);The Cyclic Vol tammetry of Cobalt ( Ⅱ ) Porphyrin Catalytic System——Studies on the Electrocatalytic Reduction of Carbon Dioxide ( Ⅵ )[J];Journal of Jilin University (Science Edition);1992-02
9 Zheng, Guo-Dong Yan, Yan Cao, Xi-Zhang Xu, Ji-Qing(Department of Chemistry, Jilin University, Changchun, 130023)Gao, Sai (Department of Environment Science, Jilin University, Changchun, 130023)Tong, Shan-Ling(Changchung School of Light Industry, 130021)Gao, De(Department of Chemical Engineering, Hunan University, Changsha, 410082);Electrocarboxylation of Organic Compounds with Carbon dioxide Catalyzed by Metalloporphyrins Ⅰ. Catalytic Activities of Metalloporphyrins for Electrocarboxylation of Benzyl Chloride[J];Acta Chimica Sinica;1995-03
10 Yang Guangdi (Institute of Theoretical Chemistry of Jilin University) Cao Xizhang, Wang Fengshan and Zheng Guodong (Department of Chemistry, Lilin University);Crystal Structure of Cobalt(Ⅲ)Diimidazole Tetrakis (4-Trimethyilaniline) Porphyrin Iodide Hydrate[J];Journal of Jilin University (Science Edition);1988-03
【Co-references】
Chinese Journal Full-text Database 2 Hits
1 Cao Xizhang and Mu Xihai (Department of Chemistry, Jilin University, Changchun);Studies on Carbon Monoxide Complex of a New Tailed Porphyriniron[J];Chemical Research In Chinese Universities;1986-01
2 DA YOU-XIAN LIU YUN-QI ZHU XIU-CHANG (Institute of Chemistry,Academia Sinica,Beijing);THE STUDY OF POLYTETRAPHENYLPORPHYRIN AND ITS METAL COMPLEXES BY MEANS OF XPS[J];Acta Chimica Sinica;1985-01
【Secondary References】
Chinese Journal Full-text Database 2 Hits
1 WU Jun-feng,SONG Sai-nan,YU Lian-xiang,LI Dong-mei,SHI Tong-shun,LIU Guo-fa (College of Chemistry,Jilin University,Changchun 130023,China);Syntheses and characterization of Schiff-base unsymmetrical porphyrin with benzaldhyde and its lanthanide complexes[J];Journal of Molecular Science;2007-03
2 SHI Tong-Shun , WEI Quan, CAO Xi-Zhang(Department of Chemistry, Jilin University, Changchun, 130023);An XPS Study on Tetra-(p-nitrophenyl) Porphyrin Transition Metal Complexes[J];Chemical Research In Chinese Universities;1993-10
【Secondary Citations】
Chinese Journal Full-text Database 2 Hits
1 Cao Xizhang, Huang Chubao and Wang Maolian (Department of Chemistry, Jilin University, Changchun);INVESTIGATION OF THE ELECTROREDUCTION OF CARBON DIOXIDE (Ⅰ)——ELECTROCATALYTIC ACTIVITY OF COBALT PORPHYRIN COORDINATION COMPOUND[J];Chemical Research In Chinese Universities;1983-05
2 Liu Guofa, Wang Yutian, Zhao Yongnian and Liang Yingqiu (Institute of Theoretical Chemistry, Jilin University, Changchun);RAMAN SPECTRA OF RARE EARTH ACETYLACETONATE COMPLEXES (Ⅱ)[J];Chemical Research In Chinese Universities;1983-01
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