Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chemical Research In Chinese Universities》 1987-12
Add to Favorite Get Latest Update

A Lewis Acid Catalyst Supported by Polymer——Polystyrene-AICI_3/SnCI_4 Dibasic Metal Chloride Complex

Fan Ruicheng, Jia Xinru, Wu Xianghong, Pei Weiwei and Jiang Shuojian (Department of Chemistry, Peking University, Beijing)  
Polystyrene-divinylbenzene(4%) beads were combined with anhydrous aluminium chloride and stannic chloride (1:1) in chloroform to form a stable complex containing 7.73% of chlorine, in which the ratio of metal aluminium to metal tin is 2/1. It correspond to (0.278 mmol SnCl4 + 0.557mmol AlCl3)/1g complex beads. The complex beads (PS-Al/Sn) can be used to catalyze a lot of organic reactions, such as esierifications, acetalizations, ketal formations, ethe-rification and the Friedel-Crafts alkylations. The greater reactivity of the PS-Al/Sn compared to PS-A1C13(6) and PS-SnCl4(7) was confirmed in these reactions. It is important that the dibasic metal complex PS-Al/Sn as a fine catalyst can be reused at least 10 times in high yields.
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 8 Hits
1 YU SHan-xin1, LIU Mei-yan1, GUAN Shi-bin1, WEN Rui-ming2 (1. College of Chemistry and Chemical Engineering, Hunan Normal University, CHangsha Hunan 410081; 2. Department of Chemistry and Environmentally Engineering, Hunan City University, Yiyang Hunan 413000);Progress on Synthesis of Cyclohexanone 1,2-propylene Ketal Catalyzed by Solid Acid[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-03
2 YU Shan-xin1, WEN Rui-ming2, YOU Pei-qing2(1.College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha, Hunan, 410081;2.Department of Chemistry and Environmentally Engineering, Hunan City University, Yiyang, Hunan, 413000);Research advances of polymer-supported lewis acid catalyst[J];Journal of Hunan University of Arts and Science(Science and Technology);2008-04
3 WANG Jin Feng, JIA Xin Ru *, JIN Zhong, ZHANG Wei Cheng, FAN Yu, LI Ming Qian [WT5”BX](College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China) WEI Yen (Department of Chemistry, Drexel University, Philadel;PAMAM Dendritic Titanium Tetrachloride Complexes and Their Catalytic Reactivity[J];Chemical Research In Chinese Universities;2001-04
4 ZHANG Zhi-hua, XU Yan-lian, LIN Jin-huo (College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China);Catalytic Synthesis of Ketal by Urushiol-Formaldehyde Neodymium Polymer[J];Chinese Journal of Synthetic Chemistry;2004-02
5 WEN Ruiming1,YOU Peiqing1,YU Shanxin2(1 Hunan City University,Yiyang 413000,Hunan,China;2 School of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081,Hunan,China);Progress of synthesis of cyclohexanone ethylene ketal catalyzed by solid acids[J];Chemical Industry and Engineering Progress;2007-11
6 Yu Shanxin Lei Cunxi Long Liping(Department of Chemistry, Hunan Yiyang Teacher's College, Yiyang 413049);Research on Catalytic Synthesis of Cyclohexanone Ethylene Ketal[J];Advances in Fine Fetrochemicals;2001-01
7 You Peiqing~1 Wen Ruiming~1 Yu Shanxin~2 1.Hunan City University,Yiyang 413000; 2.College of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081;Synthesis of n-Butyl Propionate Catalyzed by Solid Catalyst[J];Advances in Fine Petrochemicals;2007-09
8 Tian Zhixin\ Wu Zhikun\ Li Juren\ Gong Jian (Chemistry and Chemical Engineering College,Hunan Normal University,Changsha 410081);Catalytic Synthesis of n Butyl Acetate by Niobic Acid[J];Shaanxi Chemical Industry;1999-03
【Citations】
Chinese Journal Full-text Database 1 Hits
1 Ran Ruicheng, Pei Weiwei, Jia Xinru, Shen Ji and Jiang Shuojian (Department of Chemistry, Peking University, Beijing);A Lewis Acid Catalyst Supported by Polymer. Polystyrene AlCl_3/TiCl_4 Complex[J];Chemical Research In Chinese Universities;1986-07
【Co-citations】
Chinese Journal Full-text Database 9 Hits
1 RAN Ruicheng, MAO Guoping (Department of Chemistry);Polymer-Supported Stannic Chloride Complex Catalysts Ⅲ. Copoly (Styrene-N-Vinylcarbazole) -Stannic Chloride Complex[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1989-06
2 YU SHan-xin1, LIU Mei-yan1, GUAN Shi-bin1, WEN Rui-ming2 (1. College of Chemistry and Chemical Engineering, Hunan Normal University, CHangsha Hunan 410081; 2. Department of Chemistry and Environmentally Engineering, Hunan City University, Yiyang Hunan 413000);Progress on Synthesis of Cyclohexanone 1,2-propylene Ketal Catalyzed by Solid Acid[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-03
3 Ran Rui-cheng and Mao Guo-ping (Department of Chemistry, Peking University);POLYMER-SUPPORTED STANNIC CHLORIDE COMPLEX CATALYSTS Ⅵ. COPOLY (STYRENE-4-VINYLPYRIDINE) -STANNIC CHLORIDE COMPLEX[J];Chinese Journal of Catalysis;1989-01
4 Liu Fuan, Tian Mingyuan, Li Yaoxian, Huang Huaming (Department of Chemistry, Jilin University, Changchun 130023);Ion Exchange Resin-Supported SnCl_4: Synthesis, Characterization and Esterification[J];Journal of Molecular Catalysis;1993-05
5 Ran Ruicheng, Mao Guoping (Department of Chemistry, Peking University, Beijing);Polymer-Supported Stannic Tetrachloride Complex Catalysts (Ⅱ )——Copolymer (Styrene-Methyl Methacrylate)-Stannic Tetrachloride Complex[J];Chemical Research In Chinese Universities;1989-07
6 Han Ying; Hao Aiguo; Shao Zuofan; Li Mingyang(Department of Chemistry, dalian Medical University , Dalian 116027,China);The Catalytical Synthesis of 1, 4 - Dioxaspiro[4.5] decane by Anhydrous Calcium Chloride[J];GUANGZHOU CHEMISTRY;1998-01
7 WEN Ruiming1,YOU Peiqing1,YU Shanxin2(1 Hunan City University,Yiyang 413000,Hunan,China;2 School of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081,Hunan,China);Progress of synthesis of cyclohexanone ethylene ketal catalyzed by solid acids[J];Chemical Industry and Engineering Progress;2007-11
8 Ran Ruicheng Mao Guoping (Department of Chemistry,Beijing University);Polymer-supported stannic chloride complex catalysts Ⅴ.Copoly(styrene-acrylonitrile)-stannic chloride complex[J];Chemical Reagents;1990-02
9 Yu Shanxin Lei Cunxi Long Liping(Department of Chemistry, Hunan Yiyang Teacher's College, Yiyang 413049);Research on Catalytic Synthesis of Cyclohexanone Ethylene Ketal[J];Advances in Fine Fetrochemicals;2001-01
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 YANG Shui jin DU Xin xian LV Bao lan(Department of Chemistry and Environmental Engineering, Hubei Normal University, Hubei Huangshi 435002,China);Synthesis of acetals and ketals catalyzed by phosphotungstic acid supported on active carbon[J];Journal of Beijing University of Chemical Technology;2005-01
2 Lin Shijing Sun Yangzhao Tong Laga Ding Hong He Jiajie (Department of Chemical Engineering , Beijing Institute of Petro-chemical Technology , Beijing 102617;State Environmental Protection Administration, Beijing 100035);Research on Synthesis of N-butyl Propionate Catalyzed by P-toluenesulfonic Acid Supported on Activated Carbon[J];Journal of Beijing Institute of Petro-Chemical Technology;2006-01
3 XU Zhao-hui~1,WEI Xu-yuan~2,CHEN Wei~1,LI Xiao-ming~2,WANG Sheng~1 (1.Institute of Chemistry,Jiangxi Normal University, Nanchang 330027,China;2.Chemical Ltd of Jiangxi Normal University,Nanchang 330027,China);Synthesis of Cyclohexanone Glycol Ketal by Zr(SO_4)_2·4H_2O as a Catalyst[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2004-03
4 Yu Shanxin; Ping Weijun; Zheng Ying (College of Chemistry and Chemical Engineering, Hunan Normal University, Changgsha,410081);Catalytic Synthesis of Isopentyle Lactate with Polvinyle Chloride-Ferric Chloride Resin[J];JOURNAL OF CHANGDE TEACHERS UNIVERSITY;1999-03
5 YU SHan-xin1, LIU Mei-yan1, GUAN Shi-bin1, WEN Rui-ming2 (1. College of Chemistry and Chemical Engineering, Hunan Normal University, CHangsha Hunan 410081; 2. Department of Chemistry and Environmentally Engineering, Hunan City University, Yiyang Hunan 413000);Progress on Synthesis of Cyclohexanone 1,2-propylene Ketal Catalyzed by Solid Acid[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-03
6 Ran Rui-cheng, Huang Jin, Jia Xin-ru and Shen Ji (Department of Chemistry,Beijing University);A POLYMER-SUPPORTED LEWIS ACID CATALYST: COPOLY(STYRENE-N-VINYLCARBAZOLE)-TITANIUM TETRACHLORIDE COMPLEX[J];Chinese Journal of Catalysis;1987-04
7 Ran Rui-cheng and Mao Guo-ping (Department of Chemistry, Peking University);POLYMER-SUPPORTED STANNIC CHLORIDE COMPLEX CATALYSTS Ⅵ. COPOLY (STYRENE-4-VINYLPYRIDINE) -STANNIC CHLORIDE COMPLEX[J];Chinese Journal of Catalysis;1989-01
8 Li Bao, Zhan Yong-fu, Li Lian-zhong and Zhang Xiao-mei (Department of Chemistry, Jilin Teachers College, Jilin);Zr(SO_4)_2·4H_2O AS CATALYST FOR ESTERIFICATION[J];Chinese Journal of Catalysis;1989-03
9 Liu Fu-an, Zhao Jun-xiu and Huang Hua-min(Department of Chemistry, Jilin University, Changchun 130023);SYNTHESIS OF ION EXCHANGE RESIN-SUPPORTED TITANIUM TETRACHLORIDE AND ITS APPLICATIONS[J];Chinese Journal of Catalysis;1991-05
10 Ran Ruicheng, Pei Weiwei, Jia Xinru, Shen Ji ( Department of Chemistry, Peking University, Beijing );A POLYMER-SUPPORTED LEWIS ACID CATALYST, POLYSTYRENE-ZIRCONIUM TETRACHLORIDE COMPLEX[J];Journal of Molecular Catalysis;1988-02
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 YOU Pei-qing~1 LUO Xin-xiang~2 WEN Rui-ming~2 YU SHan-xin~3 (1.Department of Science and Technology,Hunan City University,Yiyang Hunan,413000;2.Department of Chemistry and Environmental,Hunan City University,Yiyang Hunan,413049;3.College of Chemistry and Chemical Engineering,Hunan Normal University,CHangsha Hunan,410081);Study Synthses of Cyclohexanone Ethylene Ketal[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-02
2 YU Shan-xin1,WEN Rui-ming 2,YOU Pei-qing 3 (1.College of chemistry and chemical engineering,Hunan normal university,Hunan,Changsha,410081;2.Department of chemistry and environmentally engineering,Hunan city university,Hunan,Yiyang,413049;3.Department of science and technology,Hunan city university,Hunan,Yiyang,413000);Application of sodium bisulfate monohydrate in organic synthesis[J];Journal of Hunan University of Arts and Science(Science and Technology);2008-01
3 ZHANG Changhua HU Jianqing TU Weiping (School of Chemical and Energy Engineering,South China University of Technology,Guangzhou 510640);Progress in Study on Polyamidoamine(PAMAM)Dendrime in China[J];Materials Review;2005-09
4 PAN Bi-Feng,GAO Feng,GU Hong-Chen(Engineering research center for nano science and technology,Shanghai Jiaotong University,Shanghai,China 200030);PREPARATION OF GOLD NANOCLUSTER USING DENDRIMER AS TEMPLATE AND ITS CHARACTERIZATION[J];Polymeric Materials Science & Engineering;2005-06
5 WU Wen\|juan, XU Dong\|mei, ZHANG Ke\|da, ZHU Xiu\|lin, NING Chun\|hua (Department of Chemistry & Chemical Engineering, Suzhou University, JSuzhou 215006, China);The Application of Polyamidoamine Dendrimers[J];Polymer Bulletin;2003-04
6 ZHENG Shi-zhao, XU Wei-jian  (College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China);Synthesis and Application of Poly(amide amine) Dendrimer[J];Polymer Bulletin;2004-01
7 LIU Hai-feng, WANG Yu-rong~*, REN Yan(Department of Polymer Science and Materials , Dalian University of Technology,Dalian 116012, China);Development of Dendrimers' Practical Using Research[J];Polymer Bulletin;2005-03
8 ZHANG Aihua1,2,LI Zhiping1,YIN Dulin2*(1.College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000,Hunan,China;2.College of Chemistry and Chemical Engineering, Hunan Normal University,Changsha 410081,Hunan,China);Synthesis of cyclohexanone glycol ketal catalyzed by ammonium ferric sulfate under microwave irradiation[J];Industrial Catalysis;2008-01
9 ZHANG Ai-Hua~a YIN Du-Lin~b LIU Wen-Ping~a PENG Zhi-Yuan~a (College of Chemistry and Chemical Engineering,Jishou University,Jishou,Hunan 416000,P.R.China) b(College of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081,P.R.China);The Microwave Synthesis of Cyclohexanone Glycol Ketal Catalyzed by Activated Carbon Supported p-Toluene Sulphonic Acid[J];Chinese Journal of Spectroscopy Laboratory;2009-05
10 Zhao Fenjuan, Guo Xiusheng, Yu Demei, Hu Jiajuan( Department of Applied Chemistry, Xi' an Jiaotong University, Xi' an 710049, China);STUDY ON THE PROPERTIES OF DENDRITIC POLY(AMIDOAMINE) CURED EPOXY RESIN[J];Engineering Plastics Application;2009-12
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 Ran Ruicheng;Jiang Shuojian;Shen Ji Dep. of Chem., Beijing University Beijing Chemical Fiber College;A LEWIS ACID CATALYST SUPPORTED BY POLYMER POLYSTYRENE-TITANIUM TETRACHLORIDE COMPLEX[J];Chinese Journal of Applied Chemistry;1985-01
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved