Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chemical Research In Chinese Universities》 1989-09
Add to Favorite Get Latest Update

Studies on the Characteristics of Metastable Zone of the Aqueous K_2SO_4 Solution ( Ⅰ )——Nucleation Characteristics

Wang Zichen, Zhao Qiugang, Yang Yonghua, Zhao Muyu (Department of Chemistry, Jilin University, Changchun)  
Some characteristics of the nucleation kinetics can be obtained by measuring the width of metastable zone during the crystallization of aqueous salt solution. According to the theory of crystal growth, the method of calculation of the nucleation characteristic parameters, including the order of nucleation n, the radius of the critical nucleus rσ, the number of particles in a critical nucleus N * and the specific surface energy σ12 etc from the experimental data is improved in this article. Using an apparatus equipped with a temperature-programmed digital controller and laser detector of the particle appearance , the widths of metastable zone of aqueous K2SO4 solution were measured and the nucleation characteristic parameters were calculated. The data obtained are very satisfactory by comparison with the values in the literatures.
【Fund】: 国家自然科学基金
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 9 Hits
1 Wang Zi-chen, Zhang Li-hua, Yang Yong-hua, Zhao Mu-yu (Department of Chemistry, Jilin University, Changchun, 130023);Studies on the Characteristics of Metastable Zone of the Aqueous K2SO4 Solution ( Ⅲ )——The Induction Period of Nucleation[J];Chemical Research In Chinese Universities;1991-02
2 WANG Zi-Chen,GUO Xin-Xin,ZHANG Li-Hua,XU Bao-Kun,ZHAO Mu-Yu (Department of Chemistry,Mm University,Changchun,130023);A Study of the Properties of Metastable Zone of the K_2SO_4 Aqueous Solution(Ⅳ)——The Effect of Impuritie Li~+ on the Crystallization Process of K_2SO_4 Solution[J];Chemical Research In Chinese Universities;1992-12
3 ZHOU Ying,LIU Hong-jie,ZOU Rong,YI Mei-gui,LIANG Yu-xiang(School of Chemical Engineering,Sichuan University,Chengdu 610065,China);Intercalation Mechanism of Configuration of Potassium Carbonate System in the Bentonite Interlayer[J];Bulletin of the Chinese Ceramic Society;2010-01
4 Gong Xiaozhi~1 Cheng Xuewen~1 Liu Rui~21.Environmenlal Prolection Research Institute,Beijing Research Institute of Chemical Industry,SINOPEC,Beijing 100013,China;2.College of Chemistry and Chemical Engineering,Xiamen University,Xiamen Fujian 361005,China;Recovery of Polyether and Potassium Dihydrogen Phosphate from Polyether Residue[J];Environmental Protection of Chemical Industry;2007-01
5 Wang Zichen; Yang Hua; Shen Lianchun; Zhao Muyu(Department of Chemistry, Jilin University, Changchun, 130023);The Effect of Impurity Cr~(3+) on the Crystallization of K_2SO_4[J];ACTA SCIENTIARIUM NATURALIUM UNIVERSITATIS JILINENSIS;1997-01
6 Chen Jiangzhong Li Songxian Gao Shaokang WangJiahe Chen Yazhen(Department of Chemistry,Fuzhou University , Fuzhou 350002,China)(Received 8 May 1993,accepted 10 September 1993);Investigation of Nucleation of POM Crystal from Dimethyl Sulfoxide Solution[J];JOURNAL OF SYNTHETIC CRYSTALS;1994-02
7 ZHOU Tao,DUAN Zuo-ying, ZHANG Hong-jian, CHEN Jian-xin, MAO Zhong-gui Southern Yangtze University, Wuxi 214036, China);Crystallization Metastable Zone Properties of Glutamic Acid Solution[J];Journal of Wuxi University of Light Industry;2004-01
8 Yi Yangliu; Deng Chaoqun(Research Institute of Technology and Science, Xiangtan University, Xiangtan, 411105, China);RESEARCH ON PRODUCING AGRICULTURAL POTASSIUM SULPHATE BY CONVERSION REACTION OF POTASSIUM CHLORIDE WITH AMMONIUM SULPHATE[J];NATURAL SCIENCE JOURNAL OF XIANGTAN UNIVERSITY;1995-01
9 Li Lijuan;Li Jize(Qinghai Institute of Salt Lake, Academy of Scinences, Xian 710043);Preparation of Crystalline Ball of Potassium Sulphate With Technology of Solvents Extract[J];JOURNAL OF SALT LAKE RESEARCH;1998-04
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Gong Chenli Zhou Tianjian (Department of Materials Engineering);TO ANALYSE THE EQUILIBRIOUS STRUCTURE OF L-S INTERFACE BY A GENERAL BOND MODEL[J];;1995-03
2 AN Zhi-huan1,CHEN Tian-hu2,PENG Shu-chuan2(1.East China Engineering Science and Technology Co,Ltd.,Hefei 230024,China; 2.Dep.of Resource & Environment,Hefei University of Technology,Hefei 230009,China);Research of Ponceau 4R Anion Intercalated Mg/Al-LDH Crystal Lattice Structure[J];Anhui Chemical Industry;2011-01
3 WANG Yue 1,2 ,LI Quan bao 1,HAN Qing lin 1,SONG Bing wen 1,JIE Wan qi 2,ZHOU Yao he 2(1.Kunming Institute of Physics,Kunming 650223,China; 2.State Key Lab.of Solidification Processing,Northwest Polytechnical University,Xi'an 710072,China)$$;Phase Change Procedure during Growth of HgCdTe Crystal by SSR Technique[J];SEMICONDUCTOR OPTOELECTRONICS;2000-01
4 WANG Yue 1,2 ,SONG Bing wen 1,LIU Chao wang 1,WANG Jing yu 1, YANG Yu ling 1,JIE Wan qi 2,ZHOU Yao he 2 (1.Kunming Institute of Physics,Kunming 650223,China; 2.National Key Laboratory of Solidification Processing,Northwest Polytechnical;The Choice of Growth Technology for HgCdTe Epitaxial Growth by MOCVD[J];SEMICONDUCTOR OPTOELECTRONICS;2000-04
5 ZENG Qingke(Dept.of Physics,Guangxi Normal University,Guilin 541001)ZENG Xianfu(South China University of Technology,Guangzbou 510641);Current-controlled LPE growth of In_xGa_(1-x)As_yP_(1-y)[J];SEMICONDUCTOR OPTOELECTRONICS;1995-02
6 Luo Muchang,Yang Deren,Que Duanlin (State Key Laboratory of Silicon Materials,Zhejiang University,Hangzhou 310027);Antimony and Oxygen Impurity in Heavily Antimony doped CZ Silicon Crystals[J];SEMICONDUCTOR TECHNOLOGY;1999-05
7 Deng Shujun1,Gao Yu1,2,Jiang Jian1,Dai Xiaolin1,Wu Zhiqiang1,2,Liu Bing1(1.General Research Institute for Nonferrous Metals,Beijing 100088,China;2.GRINM Semiconductor Materials Co.,Ltd.,Beijing 100088,China);Impact Analysis of Hot Zone Structure on Power Consumption During CZ Silicon Growth[J];Semiconductor Technology;2010-12
8 You Renran/Institute of Mechanics,Academia Sinica,Beijing,100080Hu Wenrui/Institute of Mechanics,Academia Sinica,Beijing,100080;Analysis of Thermo-Solutal-Capillary Convection in Floating Zone[J];Chinese Journal of Semiconductors;1992-04
9 Zhang Hongzhi,Hu Lizhong,Sun Xiaojuan,Wang Zhijun,and Liang Xiuping(State Key Laboratory of Materials Modification by Laser,Ion and Electron Beams, Dalian University of Technology,Dalian 116024,China);GaAs Microtips Grown by Selective LPE for SNOM Sensors[J];Chinese Journal of Semiconductors;2005-06
10 Li Xun;Chen Genxiang and Jian Shuisheng (Lightwave Tech. Res.Ins., Northern Jiaotong University,Beijing 100044);Theory and Expriment of Liquid Phase Epitaxy on Curved InP Surface[J];CHINESE JOURNAL OF SEMICONDUCTORS;1995-02
China Proceedings of conference Full-text Database 7 Hits
1 Peng Liming Zou Qiming Wen Hongquan Mao Xiemin Xu Kuangdi (Inst.Mater.Sc.& Eng.of Shanghai University,Shanghai,200072,China);Review of Researches and Development on Single Crystal Continuous Casting Technology[A];[C];1998
2 HE Zhi-yu ZHAO Bei-jun ZHU Shi-fu REN Rui WEN Cai YE Lin-sen ZHONG Yu-hang WANG Li-miao YANG Hui-guang (The Department of Materials Science,Sichuan University,Chengdu 610064,China);Study on CdSe single crystal growth speed with vapor phase method[A];[C];2007
3 Hang fangxue~(1,2) Qiu taiqiu~1 1.School of Light Industry and Food Engineering,South China University of Technology,Guangzhou 510640,China; 2.School of Light Industry and Food Engineering,Guangxi university,Nanning 530004,Guangxi,China;The application of power ultrasound to andrographolide solventing-out crystallization process[A];[C];2007
4 Wang Zhixian, Zhao Beijun, Zhu Shifu, Qiu ChunLi,Li XinLei,He ZhiYu,Chen BaoJun (Department of Materials Science, Sichuan University, Chengdu,610064);Study of dislocation distribution on Cd_(1-x)Zn_xTe crystal using vertical Bridgman method[A];[C];2008
5 YU Jin, YANG Hui-zhen, ZU Fang-qiu (College of Materials Science and Engineering, Hefei University of Technology Hefei 230009);Effect of Liquid - Liquid Structure Transition on Solidification Behavor and Microstructure of Pb_(26)Sn_(42)Bi_(32) Ternary Alloys[A];[C];2006
6 Li Jun Yuan Junsheng Li Xiulun (Chemical Engineering School,Tianjin University,Tianjin 300072);Effects of Inert-solid Particles on the Circulating Fluidized Crystallization and the Model of Nucleation Rate[A];[C];2000
7 Liang Wang;Hong-Yi Li;Lin-Jiang Yang;Kai Jiao;Yu Wang;Bing Xie;College of Materials Science and Engineering,Chongqing University;State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization;;Sol-gel/hydrothermal method for the synthesis of ultralong NH_4V_3O_8 nanobelts[A];[C];2014
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 XIA Hai-ping,TANG Hai-da,HUANG Hong-fang (Shanghai Desano Biotechnology Limited Company, Shanghai 201302, China);Breeding of L-Glutamine-Producing Strain and Optimization of Ifs Fermentation Process[J];Amino Acids & Biotic Resources;2004-04
2 DING Bang-qin,QIU Xin,Zhou Feng(Nantong Vocational College,Chemical Engineering Department,Nantong 226007, China);Summary of L-Glutamine Biochemical Properties,Application and Production[J];Amino Acids & Biotic Resources;2008-04
3 Zhang Junmin Gao Zhenchuan (Institute of animal science, CAAS 10094);Prograss in Research of Glutamine Nutritional Physiology[J];AMINO ACIDS & BIOTIC RESOURCES;1999-02
4 ;The Surface-Chemical Properties of Sodium Catboxylate Aqueous Solu-tions[J];China Surfactant Detergent & Cosmetics;1992-05
5 LIANG Cheng hua, WEI Li ping, LUO Lei (Shenyang Agricultural University, Shenyang 110161,China);ADVANCE IN RESEARCH ON MECHANISMS OF POTASSIUM RELEASING AND FIXING IN SOILS[J];Advance In Earth Sciences;2002-05
6 Hang Wenrong (Fuzhou Gourmet Powder Factory);The application of Glutamic acid single cell protein(SCP)[J];THE LIGHT & TEXTILE INDUSTRIES OF FUJIAN;1997-02
7 WANG Guili (Jiangsu Lianyungang Sanjili Chemical Industry CO.,Ltd Lianyungang 222047);Determination of Catechol Purity by High Performance Liquid Chromatography[J];ANALYSIS AND TESTING TECHNOLOGY AND INSTRUMENTS;2000-01
8 Gao Shaokang;Lin Jingzhen;Chen Jianzhong(Department of Chemistry,Fuzhou University,Fuzhou,350002);Studies on Nucleation in Supersaturation Solutions of Dioctadecyl Succinate Crystals[J];JOURNAL OF FUZHOU UNIVERSITY(NATURAL SCIENCES EDTION);1994-01
9 Wang Zichen,Zhao Qiugang, Zhang Lihua, Tai Xiuyu, Yang Yonghua, Zhao Muyu(Department of Chemistry, Jilin University, Changchun, 130023);A Study of the Characteristic of Metastable Zone of the Aqueous K2SO4 Solution (Ⅱ)——The Effect of Impurities on the Crystallization Process of K_2SO_4 Solution[J];Chemical Research In Chinese Universities;1990-11
10 Wang Zi-chen, Zhang Li-hua, Yang Yong-hua, Zhao Mu-yu (Department of Chemistry, Jilin University, Changchun, 130023);Studies on the Characteristics of Metastable Zone of the Aqueous K2SO4 Solution ( Ⅲ )——The Induction Period of Nucleation[J];Chemical Research In Chinese Universities;1991-02
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LUO Yang-po et al(School of Life Science,Huzhou Teachers College,Huzhou,Zhejiang 313000);Preparation of Clay based Slow-release Fertilizers Containing Nitrogen,Phosphorus and Potassium and its Release Characteristics[J];Journal of Anhui Agricultural Sciences;2012-02
2 WANG Zi-Chen,GUO Xin-Xin,ZHANG Li-Hua,XU Bao-Kun,ZHAO Mu-Yu (Department of Chemistry,Mm University,Changchun,130023);A Study of the Properties of Metastable Zone of the K_2SO_4 Aqueous Solution(Ⅳ)——The Effect of Impuritie Li~+ on the Crystallization Process of K_2SO_4 Solution[J];Chemical Research In Chinese Universities;1992-12
3 ZHANG Xingfa1, LIU Shouqiang1, HU Zhangwen2, CHEN Min1 (1.School of Chemical Engineering, Hefei University of Technology, Hefei 230009, China; 2.Dept. of Biochemical Engineering, Anhui University of Technology and Science, Wuhu 241000, China);Improving the production of potassium sulfate by adding proper solvent[J];Journal of Hefei University of Technology(Natural Science);2003-04
4 Gong Xiaozhi~1 Cheng Xuewen~1 Liu Rui~21.Environmenlal Prolection Research Institute,Beijing Research Institute of Chemical Industry,SINOPEC,Beijing 100013,China;2.College of Chemistry and Chemical Engineering,Xiamen University,Xiamen Fujian 361005,China;Recovery of Polyether and Potassium Dihydrogen Phosphate from Polyether Residue[J];Environmental Protection of Chemical Industry;2007-01
5 Ding Binghai(Polyether Department,Tianjin Petroleum Chemical Corporation,SINOPEC,Tianjin 300163,China);Recovery of Polyether Polyol and Potassium Dihydrogen Phosphate from Filter Residue in Polyether Polyol Production[J];Environmental Protection of Chemical Industry;2011-05
6 ZHANG Xing-fa (School of Chemical Engineering, Hefei University of Technology, Hefei Anhui 230009, China);Study on the process of synthesizing potassium sulfate with methanol solution sulfate-ammonium method[J];Industrial Minerals and Processing;2004-11
7 TANG Xiu-hua1,2,LI Jun1, ZHOU Kun1,ZHONG Ben-he1(1.Sichuan University,Chengdu Sichuan 610065,China;2.Sichuan University of Science and Engineering,Zigong Sichuan 643000,China);Study on the crystallization metastable zone of ammonium dihydrogen phosphate[J];Industrial Minerals & Processing;2007-06
8 ZENG Xiang-dong,SHA Zuo-liang,CHEN Qi-hua(Tianjin Key Laboratory of Marine Resources and Chemistry,Tianjin University of Science & Technology,Tianjin 300457,China);Study on the solubility and metastable zone of glyphosate in mother liquor[J];Journal of Zhejiang University(Science Edition);2011-04
9 Wang Zichen, Wang Xiaohui, Zhang Lihua and Zhao Muyu (Department of Chemisty, Jilin University, Changchun);Effect of Trace Elements on Thermal Analysis Results of AI-Si Alloys[J];Journal of Jilin University;1991-03
10 Wang Zichen, Guo Xinxin, Li Xi, Xu Baokun and Zhao Muyu (Department of Chemistry, Jilin University, Changchun);Nucleation Characteristic of the Aqueous Na_2B_4O_7 Solution[J];Journal of Jilin University;1992-01
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved