Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chemical Research In Chinese Universities》 1993-10
Add to Favorite Get Latest Update

Studies on Thermodynamics of Stoichiometric Displacement Model for Adsorption of Solute from Liquid-Solid System

CHEN Yu-Yin, GENG Xin-Du (Department of Chemistry, Northwest University, Xi'an, 710069)  
Free energy change of stoichiometric displacement process for adsorption(SDM-A) of solute in a liquid-solid system was investigated. An expression which elucidates the contributions of each solute, solvent and adsorbent in the system to Gibbs free energy change was derived and the physical meaning of each parameter of the expression was also explained. Gibbs free energy change of adsorption for solute determined with traditional method can be divided into two independent fractions relating to the adsorption of solute and to the desorption of solvent, respectively. A linear relationship between two linear parameters BBBBBBBa and q/Z of the SDM-A and the reciprocal of absolute temperature was derived. And, each of the changes in both enthalpy and entropy of the SDM-A of solute can also be separately divided into two independent fractions. The derived equations were tested with experimental data in literatures and a conformable result between the both was obtained.
【Fund】: 陕西省自然科学基金
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 10 Hits
1 WANG Xu-zhen, JIAO Qing-zhu, GUO Xiang-kun (Department of Chemistry, Yantai Teachers University, Yantai, P.R. China 264025).;Adsorption and Inhibition of Benzalkonium Chloride on Aluminum in HCl Solution[J];Materiais Protection;2001-06
2 GENG Xin peng (Dept.of Chemistry and Chemical Eng.,NWITST,Xian 710048,China);Stoichiometric displacement model for adsorption from liquid/solid system and its thermdynamics[J];Basic Sciences Journal of Textile Universities;2001-02
3 GENG Xinpeng, XIE Fengxia(College.of Environment and Chemistry and Chemical Eng.,XAUEST, Xian 710048,China);Study on stoichiometric displacement model for the adsorption of cationic surfactants onto wool fibers[J];Basic Sciences Journal of Textile Universities;2002-04
4 WU Yani~(1,2), GENG Xinpeng~1, CHEN Licheng~1, GENG Xindu~2, XING Jianwei~3(1. College of Environment & Chemical Eng.,XAUEST,Xi'an 710048,China;2. Institute of Modern Separation Science, Northwest University,Xi'an 710069,China;3.College of Textile & Material,XAUEST,Xi'an 710048,China);Study on lysozyme adsorption at the hydrophobic surface[J];Basic Sciences Journal of Textile Universities;2005-01
5 DAI Li,GENG Xin-peng(School of Environmental & Chemical Engineering,Xi′an Polytechnic University,Xi′an 710048,China);Study on thermodynamics of dyestuff adsorbed onto the acrylic surface using stoichiometric displacement theory[J];Basic Sciences Journal of Textile Universities;2007-01
6 Geng Xinpeng (Department of Textile Chemical Engineering,Northwest Institute of Textile Science & Technology,Xian 710048,PRC);Calculation on the Fractions of Thermodynamic Function Changes with the Stoichiometric Displacement Model for Adsorption of Solute from a Liquid Solid System[J];BASIC SCIENCES JOURNAL OF TEXTILE UNIVERSITIES;1997-02
7 WEI Rui-Xia 1,2*, CHEN Jin-Long1, CHEN Lian-Long1, FEI Zheng-Hao1, LI Ai-Min1, ZHANG Quan-Xing1 (1. State Key Laboratory of Pollution Control and Resources Reuse, Department of Environmental Engineering, Nanjing University, Nanjing 210093, China; 2. Resource and Environmental College, Hebei Polytechnic University, Tangshan 063009, China);Adsorption Thermodynamics and Kinetics of 2-Thiopheneacetic Acid on Three Types of Resin[J];Chemical Research In Chinese Universities;2004-11
8 LIU Fuqiang, CHEN Jinlong, LI Aimin, ZHANG Quanxing (State Key Laboratory of Pollution Control and Resources Reuse, School of the Environment, Nanjing University, Nanjing 210093);COMPARISON STUDIES ON THE STATIC ADSORPTION PERFORMANCE OF AMINO-NAPHTHOL-SULFONIC ACID ONTO WEAKLY BASIC RESIN ANDMODIFIED HYPERCROSSLINKED POLYMERIC ADSORBENT[J];Acta Polymerica Sinica;2004-05
9 HAN Cheng-li(School of Chemical Engineering,Qiqihar University,Qiqihar161006,China);Adsorption and its corrosion inhibition of solium furan—formaldehyde on aluminum surface in fluoboric acid solution[J];Journal of Science of Teachers' College and University;2006-04
10 SONG Yinghua,ZHU Jiawen,CHEN Kui,WU Bin (Chemical Engineering Research Centre,East China University of Science and Technology, Shanghai 200237,China);Adsorption of erythromycin on macroporous resins and thermodynamic analysis[J];Journal of Chemical Industry and Engineering(China);2006-04
China Proceedings of conference Full-text Database 1 Hits
1 Lin Guodong Geng Xinpeng Dai Li (School of Environmental & Chemical Engineering,Xi'an Polytechnic University,Xi'an 710048,China);Study on thermodynamics of stoichiometric displacement theory for disperse dye solubilized dyeing to wool by auxiliary[A];[C];2006
【Citations】
Chinese Journal Full-text Database 1 Hits
1 ZHAO ZHEN-GUO GU TI-REN~*(Department of Chemistry, Peking University);ADSORPTION FROM SOLUTIONS Ⅶ. SELECTIVE ADSORPTION OF ALCOHOLS, KETONES AND ESTERS FROM OYCLOHEXANE ONTO SILICA GEL[J];Acta Chimica Sinica;1983-12
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Zhao Zhen-guo and Gu Ti-ren (Laboratory of Surface and Colloid Chemistry, Department of Chemistry, Beijing University);THE ADSORPTION OF VAPOURS OF ALIPHATIC ACIDS AND CARBON TETRACHLORIDE BY SILICA GEL[J];Chinese Journal of Catalysis;1984-03
2 Shi Yali; Geng Xindu~*(Laboratory of Modern Separation solace, Department of Chemistry, Northwest University, Xi′an 710069);A New Characterization Paramter Z in Liquid Chromatography——Ⅰ. Separation System of Apolar Solutes With Small Molecular Weight in Reversed-phase Liquid Chromatography[J];Chinese Journal of Analytical Chemistry;1992-09
3 Zhang Weiping , Gao Juan, Geng Xindu (Institute of Modern Separation Science, Northwest University, Xi′an 710069);The Influencing Factors of Column Phase Ratio in Reversed Phase Liquid Chromatography[J];Chinese Journal of Analytieal Chemistry;2002-10
4 Zhao Zhenguo, Wu Yin and Lin Yao (Department of Chemistry, Peking University, Beijing);The Adsorption of Oxy-Aromatic Compounds from Cyclohexane onto Silica Gel[J];Chemical Research In Chinese Universities;1986-05
5 Zhao Zhenguo,Shao Changsheng,Qin Shoufeng,Lin Yao,Lin ZhenkunGu Tiren(Department of Chemistry,Peking University,Beijing);The Thermal Stability and Adsorbability of the Mechylated Silica Gel[J];高等学校化学学报(英文版);1987-02
6 Yang Lirong\ \ Yao Shanjing\ \ Zhu Ziqiang (Zhejiang University, Hangzhou 310027) Jiao Chaohui (Linhai Pharmaceutic Factory, Linhai 317000);Adsorption and Thermodynamics of Butanol in Aqueous Solution[J];JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES;1997-03
7 Zhao Zhenguo Dai Dong ( Department of Chemistry, Beijing University, Beijing);Thermodynamic Study of Adsorpton of Aromatic Compounds from Cyc-phexane onto Activel Carbon[J];Journal of Hebei University(Natural Science Edition);1986-02
8 Zhao Zhen-Guo~* Zhang Lan-Hui Lin Yao (The Institute of Physical Chemistry, Peking University, Beijing);Adsorption of Cyclohexanone and Benzoic Acid from Cyclohexane onto Silica Gel[J];Acta Chimica Sinica;1988-01
9 Zhao, Zhen-Guo Fan, Ai-Xing(Department of Chemistry, Peking University, Beijing, 100871);The Adsorption Properties of the Silanized Active Carbon[J];Acta Chimica Sinica;1994-05
10 Zhao, Zhen-Guo(Department of Chemistry, Peking University, Beijing, 100871)Davydov, V. Ya.(Chemistry Department M. V. Lomonosov State University of Moscow);Correlation between the Structure of Adsorbed Molecules and the Adsorption Constants from Solution[J];Acta Chimica Sinica;1994-12
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Yang Zedong Li Liangjun Lu Xianzhang (Anhui Center for Remote Sensing in Geology);A STUDY ON REMOTE SENSING APPLICATION IN THE EVALUATION OF HEFEI URBAN LAND[J];GEOLOGY OF ANHUI;1997-01
2 Liu Li Chen fei(TheInspectionandExaminationInstituteoftheEnvironmentofHefei,230031);The Analysis and the Research of Control Countermeasure about Acid Rain Pollution of Hefei[J];Anhui Chemical Industry;2002-04
3 Bi Gang;Inhibition of N-Substituted Alkyl-Isoquinoline Quaternary Ammonium Salt[J];Materials Protection;1997-02
4 Mu Guannan, Zhao Tianpei;Synergistic Effect of Ce(Ⅳ) Ion and OP on Corrosion Inhi\| btion of Zinc[J];MATERIAIS PROTECTION;1999-10
5 MU Guan-nan, LI Lin, Zhang Shun;Corrosion Inhibition of Organic Compounds Containing Nitrogen for Zinc in Phosphoric Acid[J];MATERIAIS PROTECTION;2000-10
6 WANG Xu-zhen, JIAO Qing-zhu, GUO Xiang-kun (Department of Chemistry, Yantai Teachers University, Yantai, P.R. China 264025).;Adsorption and Inhibition of Benzalkonium Chloride on Aluminum in HCl Solution[J];Materiais Protection;2001-06
7 DING Yan-wei, JIAO Qing-zhu, WANG Jia, et al (Department of Chemisty of Liaoning Normal University, Dalian, 116029 Chi na) .;Inhibition and Adsorption Thermodynamics of Cetylpyridini um Bromide for Zinc in HC1 Solution[J];Materials Protection;2004-07
8 ;Development of Molybdate Series Inhibitors[J];MATERIAIS PROTECTION;1995-08
9 ;EC932 Corrosion Inhibitor for Picking Brass Tube[J];MATERIAIS PROTECTION;1995-10
10 GAO Zhi ling, LIU Jian ling, LIAO Wen hua (College of Resources and Environment Sciences, Agricultural University of Hebei, Baoding 071001, China);Situation of cadmium pollution caused by application of phosphate fertilizer and the countermeasure of prevention and control of cadmium[J];Journal of Agricultural University of Hebei;2001-03
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 NIE Fa-hui~1,WU Xiao-fu~2,HU Yue-li~2 (1.East China Jiaotong University, Nanchang, 330013, China; 2.Institute of Environment Engineering Research, CSFU, Zhuzhou 412006, China);NH_4-N Removal Capacity of Vermiculite Stuffing in Constructed Wetland[J];Urban Environment & Urban Ecology;2003-06
2 YIN Bao-lin,WEI Xi-lian,SUN De zhi(Department of Chemistry,Liaocheng Teachers University,Liaocheng 252059,China);Adsorption of a cationic surfactant on activated carbon[J];China Surfactant Detergent & Cosmetics;2002-05
3 Song He fu,Chen An guo,Xia Chang bin(Institute of Environmental Engineering &Chemical Hi Technology,Xiangtan Polytechnic University,Xiangtan,P.R.China 411201).;Study on the Adsorption of Zn~(2+)Cd~(2+)Ions with Activated Bentonite[J];Materiais Protection;2001-09
4 DING Yan-wei, JIAO Qing-zhu, WANG Jia, et al (Department of Chemisty of Liaoning Normal University, Dalian, 116029 Chi na) .;Inhibition and Adsorption Thermodynamics of Cetylpyridini um Bromide for Zinc in HC1 Solution[J];Materials Protection;2004-07
5 GENG Xin peng (Dept.of Chemistry and Chemical Eng.,NWITST,Xian 710048,China);Stoichiometric displacement model for adsorption from liquid/solid system and its thermdynamics[J];Basic Sciences Journal of Textile Universities;2001-02
6 GENG Xinpeng, XIE Fengxia(College.of Environment and Chemistry and Chemical Eng.,XAUEST, Xian 710048,China);Study on stoichiometric displacement model for the adsorption of cationic surfactants onto wool fibers[J];Basic Sciences Journal of Textile Universities;2002-04
7 WU Yani~(1,2), GENG Xinpeng~1, CHEN Licheng~1, GENG Xindu~2, XING Jianwei~3(1. College of Environment & Chemical Eng.,XAUEST,Xi'an 710048,China;2. Institute of Modern Separation Science, Northwest University,Xi'an 710069,China;3.College of Textile & Material,XAUEST,Xi'an 710048,China);Study on lysozyme adsorption at the hydrophobic surface[J];Basic Sciences Journal of Textile Universities;2005-01
8 DAI Li,GENG Xin-peng(School of Environmental & Chemical Engineering,Xi′an Polytechnic University,Xi′an 710048,China);Study on thermodynamics of dyestuff adsorbed onto the acrylic surface using stoichiometric displacement theory[J];Basic Sciences Journal of Textile Universities;2007-01
9 Geng Xinpeng (Department of Textile Chemical Engineering,Northwest Institute of Textile Science & Technology,Xian 710048,PRC);Calculation on the Fractions of Thermodynamic Function Changes with the Stoichiometric Displacement Model for Adsorption of Solute from a Liquid Solid System[J];BASIC SCIENCES JOURNAL OF TEXTILE UNIVERSITIES;1997-02
10 LU Sheng(School of Chemical Engineering and Material Science,Liaodong University,Dandong 118003,China);Adsorption Characteristics of Zn(II) by Two Kinds of Activated Carbon[J];Environmental Science & Technology;2008-04
China Proceedings of conference Full-text Database 3 Hits
1 Yang Wenzhong Tian Feng Han Bo Liu Ying Yin Xiaoshuang Tang Yongming (College of Science,Nanjing university of Technology,Nanjing 210009,China);Corrosion inhibition of carbon steel by cerium citrate conpound in NaCl medium[A];[C];2008
2 Li Dai,Xin-Peng Geng,Guo-dong Lin(School of Environment & Chemical Engineering,Xi′an Polytechnic University,Xi′an 710048,China);Thermodynamic study on the adsorption of sodium dodecyl sulfonate by wool fiber[A];[C];2006
3 Lin Guodong Geng Xinpeng Dai Li (School of Environmental & Chemical Engineering,Xi'an Polytechnic University,Xi'an 710048,China);Study on thermodynamics of stoichiometric displacement theory for disperse dye solubilized dyeing to wool by auxiliary[A];[C];2006
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved