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《Chemical Research In Chinese Universities》 1993-11
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Cationic Photopolymerization of Cyclohexene Oxide Initiated with Iron-arene Complex

CHEN Xu-Dong(Department of Chemistry, Southwest China Normal University, Chongqing, 630715)CHEN Yong-Lie, LIANG Zhao-Xi (Institute of Polymer Sciences, Zhongshan University, Guangzhou, 510275)  
The kinetics of photoinitiated polymerization of cyclohexene oxide (CHO) was studied by using Differential Scanning Calorimeter (DSC). The photoinitiator is a cyclopentadienyl Cumene iron hexafluorophosphate. It is shown that CHO polymerization is the first order reaction, the activation energy for CHO is -9. 87 kJ/mol. Temperature has a marked influence on the polymerization process of CHO. The maximum H of CHO was obtained at 40℃, but the maximum of reaction rate was obtained at 27℃. H and reaction rate drop sharply at elevated temperatures. The initiation mechanism was disclosed by these observations.
【Fund】: 国家自然科学基金
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