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《CHEMICAL RESEARCH IN CHINESE UNIVERSITIES》 1997-03
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Mechanism and Energetics of the Reductions of Protonated N-Arylfluroenimine by BNAH

LU Yun; LIU Bo; CHENG Jin-Pei(Department of Chemistry, Nankai University, Tianjin, 300071 )  
Free energy changes of each primary steps in one-step hydride transfer and multistep transfer mechanisms in the reductions of protonated N-arylfluorenimines by an NAD (P) H model, BANH, were derived from approprlate thermodynamic cycles by combining PK. and relevant electrochemical data, The mechanism of the reduction was proposed as onestep hydride transfer from thermodynamic points of view and the isotope-labelling experiments.
【Fund】: 国家自然科学基金;;兰州大学应用有机国家重点实验室资助
【CateGory Index】: O642
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【References】
Chinese Journal Full-text Database 2 Hits
1 Feng,Yisia,b Zhang,Boa Yang,Chunyanga Xu,Huajian,a,b (a School of Chemical and Engineering,Hefei University of Technology,Hefei 230009)(b Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering,Hefei 230009);Study on the Mechanism of Reduction of 9-Fluorenylidenemalononitrile with NaBH_4[J];有机化学;2011-07
2 LU Yun; XIAN Ming; CHENG Jin-Pei(Department of Chemistry, Nankai University, Tianjin, 300071);Studies on the Mg~(2+)-Catalyzed Reductions of N-Arylfluorenimines by NAD(P)H Models[J];高等学校化学学报;1997-09
【Citations】
Chinese Journal Full-text Database 2 Hits
1 LU Yun; CHENG Jin-Pei;WANG Hong-Xing(Department of Chemistry,Nankai University,Tianjin,300071)XIA Chi-Zhong(Department of chemistry,shanxi University);Acid-catalyzed Reductions of N-Arylfluorenimines by NAD(P)H Models[J];高等学校化学学报;1996-05
2 ZHAO Yong-Yu; HUAN Zhen-Wei;CHENG Jin-Pei(Department of Chemistry, Nankai University,Tianjin,300071);Acidities of α-and para-Substituted Anilines and of the Corresponding Radical Cations in DMSO Solution[J];高等学校化学学报;1994-02
【Co-citations】
Chinese Journal Full-text Database 8 Hits
1 Feng,Yisia,b Zhang,Boa Yang,Chunyanga Xu,Huajian,a,b (a School of Chemical and Engineering,Hefei University of Technology,Hefei 230009)(b Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering,Hefei 230009);Study on the Mechanism of Reduction of 9-Fluorenylidenemalononitrile with NaBH_4[J];有机化学;2011-07
2 ZHANG, Hui*,a CAO, Wei-Guoa CHEN, Jiea DENG, Hong-Meib (a Department of Chemistry, Shanghai University, Shanghai 200444) (b Instrumental Analysis and Research Center, Shanghai University, Shanghai 200444);Ortho Substituent-Promoted Simple Synthesis of the Derivatives of 2-Arylsulfanyl Anilines[J];有机化学;2008-04
3 LU Yun XIAN Ming CHENG Jin-Pei(Department of Chemistry, Nankai University, Tianjin, 300071)XIA Chi - Zhong(Department of Chemistry, Shanxi University, Taiyuan ,030006);Investigation on the Reduction of Carbocations by BNAH——Kinetics, Thermodynamics,and Reaction Mechanisms[J];化学学报;1997-12
4 LU Yun; XIAN Ming; CHENG Jin-Pei(Department of Chemistry, Nankai University, Tianjin, 300071);Studies on the Mg~(2+)-Catalyzed Reductions of N-Arylfluorenimines by NAD(P)H Models[J];高等学校化学学报;1997-09
5 CHENG Jin-Pei ; LIU Bo; LU Yun; MI Jiang-Lin; HUAN Zhen-Wei(Department of Chemistry, Nankai University, Tianjin, 300071);Homolytic and Heterolytic C-H Bond Dissociation Energies of a-V (or Ⅵ)-Group Cation-substituted Toluenes and Acetophenones[J];高等学校化学学报;1997-07
6 LU Yun; LIU Bo; CHENG Jin-Pei(Department of Chemistry, Nankai University, Tianjin, 300071 );Mechanism and Energetics of the Reductions of Protonated N-Arylfluroenimine by BNAH[J];高等学校化学学报;1997-03
7 WANG Ji-Tao;YANG Xiao-Ping;XU Yu-Ming;WANG Shan-Wei(Department of Chemistry,National Key Laboratory of Elemento-Organic Chemistry,Experimental Center,Nankai University,Tianjin,300071);Studies on Aldol Condensation of Bicycloazastannoxides with Aldehyde[J];高等学校化学学报;1996-11
8 WANG Ji-Tao, YANG Xiao - Ping, LIU Bo, CHENG Jin - Pei (Department of Chemistry, Nankai University, Tianjin, 300071);Acidities of High Coordinate Bicycloazastannoxides(Ⅳ) in DSMO Solution[J];有机化学;1996-04
【Co-references】
Chinese Journal Full-text Database 5 Hits
1 Xu, Huajiana Xu, Xiaolanb Feng, Yisi,a (a School of Chemical Engineering, Hefei University of Technology, Hefei 230009) (b Department of Chemistry, Anhui Medical University, Hefei 230032);A Novel Reaction of 10-Methylacridinium with Reactive Metals under Grinding[J];有机化学;2009-02
2 HAN, Wei-Huaa LI, Hao-Ran*,a DENG, Dong-Shunb WANG, Yonga (a Department of Chemistry, Zhejiang University, Hangzhou 310027) (b College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014);Quantum Chemistry Study on the Reduction of Prechiral Ketone by Sodium Borohydride[J];化学学报;2006-16
3 LU Yun; XIAN Ming; CHENG Jin-Pei(Department of Chemistry, Nankai University, Tianjin, 300071);Studies on the Mg~(2+)-Catalyzed Reductions of N-Arylfluorenimines by NAD(P)H Models[J];高等学校化学学报;1997-09
4 LU Yun; LIU Bo; CHENG Jin-Pei(Department of Chemistry, Nankai University, Tianjin, 300071 );Mechanism and Energetics of the Reductions of Protonated N-Arylfluroenimine by BNAH[J];高等学校化学学报;1997-03
5 LU Yun; CHENG Jin-Pei;WANG Hong-Xing(Department of Chemistry,Nankai University,Tianjin,300071)XIA Chi-Zhong(Department of chemistry,shanxi University);Acid-catalyzed Reductions of N-Arylfluorenimines by NAD(P)H Models[J];高等学校化学学报;1996-05
【Secondary References】
Chinese Journal Full-text Database 4 Hits
1 TIAN Zong-ming;QIN Yong-hua;PAN Zai-fa;School of Biology and Pharmaceutics,Zhejiang Pharmaceutical College;College of Chemical Engineering,Zhejiang University of Technology;;Recent advance on application and synthesis of malononitrile derivatives[J];化学研究与应用;2015-09
2 Feng,Yisia,b Zhang,Boa Yang,Chunyanga Xu,Huajian,a,b (a School of Chemical and Engineering,Hefei University of Technology,Hefei 230009)(b Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering,Hefei 230009);Study on the Mechanism of Reduction of 9-Fluorenylidenemalononitrile with NaBH_4[J];有机化学;2011-07
3 ZHOU Hong (Department of Chemistry,Nanjing Xiaozhuang College,Nanjing 211171,China);Design and Synthesis of Water Soluble NADH Models Based on β-D-Glucose[J];合成化学;2009-02
4 ZHAO Bing Jun, XIA Chi Zhong , CHENG Jin Pei (Department of Chemistry, Nankai University, Tianjin, 300071; Department of Chemistry, Shanxi University , Taiyuan, 030006);Synthesis and Carbon Unit Transfer Reactions of Methyl Substituted N 5, N 10 Methenyl tetrahydrofolate Coenzymes[J];高等学校化学学报;1998-07
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