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《CHEMICAL RESEARCH IN CHINESE UNIVERSITIES》 2000-06
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The Photocatalytic Properties of Transition Metal Ion doped TiO_2 Nanoparticles ——Photocatalytic Degradation of Rhodamine B

WANG Yan Qin, ZHANG Li, CHENG Hu Min *, MA Ji Ming (College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China)  
The transition metal ion doped TiO 2 nanoparticles were prepared with hydrothermal method, and the effects of doping different metal ions on the ability of TiO 2 in photocatalyzing degradation of rhodamine B(RB) were studied. The results showed that the doping of Fe 3+ , Co 2+ , Ni 2+ and Cr 3+ in TiO 2 nanoparticles made the photocatalytic efficiency of the TiO 2 particles reduce and the higher the initial content of Fe 3+ , the lower the ability of TiO 2 in photocatalyzing the degradation of RB. But the doping of Zn 2+ and Cd 2+ , especially Zn 2+ , made the photocatalytic efficiency of the TiO 2 particles enhance, showing a great increase of the rate constant( k ) and the initial reaction rate( r ini ).
【Fund】: 国家自然科学基金! (批准号 :2 9673 0 0 3 );; 国家教育部博士点专项基金
【CateGory Index】: O643
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