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《Chemical Research In Chinese Universities》 2001-08
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Studies on the Technique and Mechanism of Solid Grafting Polypropylene with Dual Monomers

ZHANG Li Feng, GUO Bao Hua, ZHANG Zeng Min  (Institute of Polymer Science & Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China)  
Solid grafting is a promising grafting method, which is simple, cheap and easy to control, to get a polar polypropylene(PP). However, the achieved product may have a severe degradation and the graft ratio cannot satisfy us. In this paper, dual monomers, maleic anhydride(MAH) and tri allyl isocyanurate(TAIC) were used to graft onto PP. It was found that TAIC was efficient to enhance the MAH content of the products and prohibit PPs degradation. The MAH content of the product can reach 7.2% with 4%TAIC. This is prominent when it was compared with melt grafting product and normal solid grafting product. The MAH content and the melt flow rate(MFR) of the product can be adjusted by changing TAICs amount. The reaction mechanism of dual monomers in the grafting polymerization and their composition in the product were also discussed.
【Fund】: 国家自然科学基金资助
【CateGory Index】: TQ316.6
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