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《Chemical Research In Chinese Universities》 2002-04
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Microstructure and Morphology of PolypropyIene/Clay NanocompositesSynthesized via Intercalative Polymerization

MA Ji-Sheng, ZHANG Shi-Min, QI Zong-Neng, HU You-Liang, ZHANG Shu-Fan(State Key Laboratory of Engineering Plastics, Center for Molecular Science, Institute of Chemistry,Chinese Academy of Sciences, Beijing 100080, China)  
Polypropylene/montmorillonite(PP-MMT) nanocomposites were synthesized via intercalativepolymerization. The morphology evolution and microstructure of the nanocomposites were investigated bymeans of polarized optical microscopy(POM), scanning electron microscopy(SEM), transmssion electronmicroscopy(TEM) and wide angle X ray diffraction (WAXD). It has been found that the big primaryMMT particles were mostly dissociated into smaller secondary particles, which consists of 2~20 individualMMT layers and expanded gallery distance full of PP chains. The morphology evolution model of thePP-MMT during the intercalation polymerization is discussed. It has been also found that the presence ofMMT influences the spherulite morphology of the polypropylene in the PP-MMT nanocomposites with in-creasing of MMT content in nanocomposite, the dimension of the spherulite reduced and the shape becamedistorted.
【Fund】: 国家自然科学基金(批准号:59833130)资助.
【CateGory Index】: TB332
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