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《Chemical Research In Chinese Universities》 2002-09
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Kinetic Studies on Catalytic Oxidation of CS_2 over Atmospheric Particles

WANG Lin, SONG Guo\|Xin, ZHANG Feng, CHEN Jian\|Min\+* (Department of Environmental Science & Engineering, Fudan University, Shanghai 200433, China)  
Heterogeneous interaction between carbon disulphide and atmospheric particles was investigated by means of FTIR, XPS, TG\|DTG\|DTA and \%in situ\% XRD analysis. COS and orthorhombic \%α\%\|S\-8 were the main products at ambient temperature. And SO\+\{2-\}\-4 was identified on the surface of atmospheric due to the further oxidation of sulfur species. Based on the static\|state FTIR study and the analysis of sulphur species on the surface of atmospheric particles by XPS, a model of mechanism on heterogeneous interaction between the surface of atmospheric particles and CS\-2 was given. The reaction is confirmed to be a pseudo\|secondary one when O\-2 is overloaded. The apparent rate constant is 6.98×10\+\{-22\} cm\+3·mol\+\{-1\}·s\+\{-1\} at 296 K, and apparent activation energy is 34.6 kJ/mol. In an industrial zone with CS\-2 exhaust emission standard of 10 mg/m\+3(GB 3 095), the CS\-2 wastage of the heterogeneous interaction is 41% of that of the reaction between CS\-2 and OH\+·, which confirms the significance of the heterogeneous interaction in developing countries.
【Fund】: 国家教育部归国留学人员基金资助
【CateGory Index】: O643.3
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