Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chemical Research In Chinese Universities》 2002-10
Add to Favorite Get Latest Update

Raman and DRIFT Spectra of Kaolinite/Formamide Intercalation Compound

WANG Lin-Jiang 1,2, WU Da-Qing 1*, YUAN Peng 1, LIN Zhong-Yu 3, DIAO Gui-Yi 1, PENG Jin-Lian 1 (1. Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China; 2. State Key Laboratory for Physical Chemist  
Raman spectroscopy and diffuse reflectance infrared spectroscopy(DRIFT) techniques have been used to study kaolinite and its intercalation compound with formamide. In the hydroxyl stretching vibration region of Raman spectrum, the formamide intercalation resulted in the decrease of the intensities of kaolinite inner surface hydroxyl bands at 3 699, 3 682, 3 665 and 3 642 cm -1, and the appearance of additional bands at 3 610, 3 628 cm -1. The two additional bands are attributed to the inner surface hydroxyls which formed hydrogen bond with the formamide CO group. In the low frequency region of Raman spectrum, the ν 1(A 1g) mode of kaolinite Al(O,OH) 6 octahedra consists of two bands at 180 and 193 cm -1, which shift to a high frequency and become a single band centred at 201 cm -1 after intercalation. It shows that the intercalation process decreases structural difference among the inner surface hydroxyls and makes them have a same orentation. The fact that the Raman active bands at 3 628 and 3 610 cm -1 were not observed in the DRIFT spectrum shows that the CO group is linearly linked with the inner surface hydroxyls and that the vibration group is highly symmetric. In the NH stretching region of DRIFT spectrum, there were two bands at 3 336 and 3 466 cm -1 corresponding to the two types of the hydrogen bonds between formamide NH group and kaolinite. In the carboxyl stretching region, an additional band at 1 667 cm -1 is assigned to CO group that bonded to the inner surface hydroxyl of kaolinite. The formamide intercalation induces that the inner hydroxyl Al-OH vibration band 930 cm -1 shift to high frequency 933 cm -1, which is due to that the formamide NH group was keyed into the ditrigonal hole of kaolinite. The formamide intercalation not only resulted in the breaking of the hydrogen bonds between the Al(O,OH) 6 octahedral hydroxyl groups and the SiO 4 tetrahedral oxygens, but also the formation of new different type hydrogen bonds between formamide molecule and kaolinite inner surface hydroxyl and the SiO 4 tetrahedral oxygen.
【Fund】: 国家自然科学基金(批准号 :40 0 72 0 14 );; 广东省自然科学基金 (批准号:0 10 496);; 厦门大学固体表面物理化学国家重点实验室开放基金(批准号 :9911)资助
【CateGory Index】: O657.3
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 8 Hits
1 Zhao Shunping1,2 Wang Tao1,2 Xu Heng1,2 Guo Yu3(1 School of Chemistry and Chemical Engineering,Anqing Teachers college,Anqing 246011;2 Anhui Province Key Laboratory of Light,Electricity,Magnetic Functional Complexes and Nano-complexes,Anqing 246011;3 School of Physics and Electrical Engineering,Anqing Teachers college,Anqing 246011);Preparation of Kaolinite/p-Toluene Sulfonic Acid Intercalation Compound by Melting Method[J];Non-Metallic Mines;2009-04
2 Du Yitinga,b, Wang Linjianga,b, Xie Xianglib (a.Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education; b. Department of Materials and Chemistry Engineering. Guilin Univerisity of Techology, Guilin 541004 China);Synthesis and Characterization of Silver Nano-particles in Interlamellar Space of Kaolinite Composites[J];China Powder Science and Technology;2008-04
3 QIN Fang-Fang1,HE Ming-Zhong1*,CUI Jing-Wei2,CHEN Qiang3(1.Faculty of Material Science and Chemical Engineering,2.State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China;3.China National South Aeroengine Company,Zhuzhou 412001,China);Thermokinetics Study on the Deintercalation Reaction of Intercalating Composite Kaolinite/Dimethyl Sulphoxide[J];Chemical Journal of Chinese Universities;2007-12
4 Gu Tao Zou Zhengguang (Dept. of Materials and Chemical Engineering, Guilin University of Technology , Guilin 541004);Study on Kaolinite/Organic Intercalated Composites and Their Appli cations[J];Bulletin of the Chinese Ceramic Society;2005-04
5 FENG Li,LIN Ze,LIU Jiongtian,LU Fakui(School of Chemical Engineering and Technology,China University of Mining and Technology,Xuzhou 221008,Jiangsu,China);PREPARATION OF KAOLINITE /ORGANIC INTERCALATION COMPOUNDS BY SONOCHEMISTRY METHOD[J];Journal of the Chinese Ceramic Society;2006-10
6 Guo Shan Lin Jinhui Wei Shuangfeng(Department of Material Science & Engineerin,Chengdu University of Technology,Chengdu 610059);Preparation and characterization of kaolinite-ACN intercalation composite[J];New Chemical Materials;2008-05
7 Wang Wan-jun,Wu Zhi-qiang,Zhang Xiao-dong,et al.(Institute of Resources and Environment,He'nan Polytechnic University,Jiaozuo 454000,China);Preparation and Characterization of Hard Kaolinite-Benzamide Intercalation Compound[J];Conservation and Utilization of Mineral Resources;2008-04
8 Wang Wanjun1 Wu Zhiqiang2 Guo Fangfang1 Zhao Yanqiao1(1.School of Resources and Environment,Henan Polytechnic University;2.East China Geological & Mining Exploration and Development Institute for Non-ferrous Metals);Preparation and Characterization of Intercalation Compound of Coal Series Kaolin and Potassium Acetate from Pingxiang of Jiangxi[J];Express Information of Mining Industry;2008-08
【Citations】
Chinese Journal Full-text Database 2 Hits
1 CHEN Guang Ming, MA Yong Mei, QI Zong Neng  (State Key Laboratory of Engineering Plastics, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China);Self-assembly Behavior in PS/ Montmorillonite Nanocomposite[J];Chemical Research In Chinese Universities;2001-05
2 WANG Yi Zhong , WU Bao Hua, YU Ding Sheng (College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029);Preparation and Characterization of Poly(ethylene oxide)/ Montmorillonite Intercalation Compound[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1999-07
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Ge Mingliang (National Engineering Research Center of Polymer, South China University of Technology, Guangzhou 510640)Xu Weibing (College of Chemical Engineering, Hefei University of Technology 230009);ADVANCE IN THE RESEARCH OF POLYMER/MONTMORILLONITE NANOCOMPOSITES BY INTERCALATION[J];Engineering Plastics Application;2002-05
2 Wang Jin, Zhu Fangming, Lin Shang'an(Center of Technology, Zhuzhou Times Rubber and Plastics Co. ,Ltd. 412007; Institute of Polymer Science, Zhongshan University, Guangzhou 510275);MECHANICAL PROPERTY RESEARCH OF sPS/PET/SsPS/MTA COMPOSITES[J];Engineering Plastics Application;2002-06
3 WANG Yi-Zhong~, ZHANG Li-Qun, YU Ding-Sheng (School of Material Science & Engineering, Beijing University of Chemical Technology, Beijing 100029, China);Studies on Butadiene/Styrene/4-Vinyl Pyridine Copolymer-montmorillonite Intercalated Hybrid[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-07
4 WANG Yue-Lin 1, WU Qing 1, DU Rong-Ni 2, WANG Yong 2, GAO Xiao-Ling 2, FU Qiang 2  (1. Institute of Polymer Science, Zhongshan University, Guangzhou 510510, China; 2. Department of Polymer Science & Materials, Sichuan University, State Ke;Reinforcement Property in Silicon Sealant by Nano CaCO_3 Particles[J];Chemical Research In Chinese Universities;2002-10
5 ZHAO Chun-Gui, YANG Ming-Shu , FENG Meng (1. State Key Laboratory of Engineering Plastics, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, Chinas 2. Graduate School, Chinese Academy of Sciences, Beijing 100039, China);Preparation and Properties of Chi orosilane-modified Montmorillonites[J];Chemical Research In Chinese Universities;2003-05
6 ZHANG Rui~1,HU Yuan~2,WANG Shi-Long~1*(1.School of Life Science and Technology,Tongji University,Shanghai 200092,China;2.State Key Lab of Fire Science,University of Science and Technology of China, Hefei 230026,China);Synthesis of Polyacrylamide/α-Zirconium Phosphate Nanocomposite by in-situ Intercalative Polymerization and the Characterization of Its Structure[J];Chemical Research In Chinese Universities;2005-11
7 MA Xiaoyan, LU Haijun, LIANG Guozheng, YAN Hongxia (Department of Chemical Engineering, Northwestern Polytecnical Univers ity, Xi'an\ 710072);PREPARATION AND PROPERTIES OF INTERCALATED RECTORITE/POLYPROPYLENE NANOCOMPOSITES[J];Acta Polymerica Sinica;2004-01
8 GAO De-yu~1, Robert B Heimann~2, Berthold Tomas~2, LI Hong~3, LIU Yu-guang~1, HOU Jing~1, ZHENG Hui~1, NI Jing-bin~1 (1.Technical Physics Institute of Heilongjiang Academy of Sciences, Harbin 150086, China; 2. Freiberg University of Mining and Technology, Freiberg, Germany; 3.Heilongjiang University, Harbin 150080, China);STUDIES ON THE STRUCTURE OF POLY(ACRYLAMIDE)- MONTMORILLONITE NANOCOMPOSITE[J];Polymeric Materials Science & Engineering;2005-04
9 LIU Xian-yong,HE Hui,JIA De-ming (College of Material Science and Engineering,South China University of Technology,Guangzhou 510640,China);Development of Polymer/Kaolinite Nanocomposites[J];Polymer Materials Science & Engineering;2007-03
10 LAN Jiang,CHEN Jin-yao,CAO Ya,LI Hui-lin(State Key Laboratory of Polymer Materials Engineering(Sichuan University),Polymer Research Institute of Sichuan University,Chengdu 610065,China);The Mechanical Properties and Rheological Behaviors of Polylactide/Montmorillonite Nanocomposites[J];Polymer Materials Science & Engineering;2009-07
China Proceedings of conference Full-text Database 3 Hits
1 WANG Bao-Xiang, YAO Yuan, Zhao Xiao-Peng (Institute of Electrorheological Technology, Northwestern Polytechnical University, Xi'an 710072, China);The preparation of kaoIinite/DMSO/CMS ternary nanocomposite and its electrorheological effect[A];[C];2004
2 Huang Zhaohui,Huang Juntong,Wu Xiaoxian,Sun Zhanxing,Fang Minghao,Liu Yangai (School of Materials Science and Engineering,China University of Geosciences,Beijing 100083,China);Research Progress of Synthesizing Sialon Powders from Minerals and Ores[A];[C];2009
3 WANG Lin-jiang~1, WU Da-qing~2 1. Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, Guilin University of Technology, Guilin 541004, China 2. Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;IN-SITU SYNTHESIS OF β'-SIALON FROM KAOLINITE- POLYACRYLAMIDE INTERCALATION COMPOUND[A];[C];2005
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 TANG Ding-xing~1,ZHAO Yun~2 (1. Dept. of Bioch. Engn., Anhui University of Technology and Science, Wuhu 241000, China; 2. Dept. of Appl. Math. & phys., Anhui University of Technology and Science, Wuhu 241000,China);Dehydration kinetics of Ni(CH_3COO)_2·4H_2O by non-isothermal analysis[J];Journal of Anhui University of Technology and Science;2003-04
2 Zhang Chenglong (Wuxi Resin Plant);STUDIES ON PHYSICAL AND CHEMICAL PROPERTIES OF UNSATURATED POLYESTER RESINS[J];FIBER REINFORCED PLASTICS/COMPOSITE;1998-05
3 LI Xian-zhou~1,LIU Yan~2,LIU Li-hua~1,NING Wei-kun~1,FAN Hai~31.College of Material Science & Engineering,Jilin University,Changchun 130025,China2.Liaoning Science and Technology College,Benxi,Liaoning 117022,China3.Avigation University of Air-Force,Changchun 130022,China;The Preparation and Characterization of the Kaolin-Hydrazine Intercalation Complex[J];Journal of Jilin University(Earth Science Edition);2006-04
4 ;Research Advances in Polymer/Layered Inorganics Nanocomposites[J];Materials Review;1998-02
5 ZHANG Sheng-hui,XIA Hua,YANG Wei,ZHAO Shun-ping,HAN Li-xiong (Faculty of Material Science and Chemical Engineering, China University of Geoscience, Wuhan 430074,China);Preparation and Characterization of Kaolinite-pNA Intercalation Compound[J];Journal of Materials Engineering;2004-03
6 Wang Yulin Wan Yizao Cheng Guoxiang Dong Xianghong Tao Haiming (Department of Materials Science and Engineering,Tianjin University);Silver Coating Process of Activated Carbon Fiber and Its Surface Morphology[J];JOURNAL OF MATERIALS ENGINEERING;1998-09
7 CAO Xiu-hua, WANG Liang-shi (Institute of Material Science and Engineering, South China University of Technology, Guangzhou 510640,China);Preparation, Structure and Application of Intercalated Kaolinite Hybrids[J];Materials Science and Engineering;2003-03
8 ZHAO Shun\|ping, XIA Hua, ZHANG Sheng\|hui (Institute of Materials Science and Chemical Engineering, China University of Geoscience, Wuhan\ 430074,China);Reasearch Advances in Kaolinite/Organics Intercalated Complex[J];Materials Science and Engineering;2003-04
9 YAN Lin-lin, XU Zheng, ZHANG Cun-man(School of materials science and engineering, Tongji University, Shanghai 200092, China);Possible Mechanism and Modeling of Potassium Acetate Intercalating into Kaolinite[J];Journal of Materials Science and Engineering;2005-04
10 YAN Lin-lin~1,ZHANG Cun-man~2,XU Zheng~1(1.School of Materials Science and Engineering,Tongji University,Shanghai 200092; 2.Institute of Hydrogen Technology,School of Automotive Studies,Tongji University,Shanghai 201804,China);Intercalation-Sonication Delamination of Kaolinite and Emergence of a Novel Nanoclub-like Crystal[J];Journal of Materials Science and Engineering;2007-02
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LI Li1,WANG Bao-hui1,TONG Mao-song2(1.School of Chemistry and Chemical Engineering,Daqing Petroleum Institute,Daqing 163318,China;2.R&D Center of Well Logging Company,Daqing Petroleum Administrative Bureau,Daqing 163412,China);Research on humidity sensing properties of pan-poly-vanadium-molybdenum acid nanocomposites[J];Transducer and Microsystem Technologies;2007-11
2 LUO Zhongtao1,MA Baoguo1,LI Xiangguo1,WANG Xingang2,WANG Yingbin1(1 Key Laboratory for Silicate Materials Science&Engineering of Ministry of Education,Wuhan University of Technology,Wuhan 430070;2 School of Civil Engineering and Architecture,Nanchang University,Nanchang 330031);Analysis on Evaluation Methods of Activity of Inorganic Cementitious Materials with Silicon-Aluminum Character[J];Materials Review;2009-01
3 ZHANG Wei1,ZHANG Shouting1,WANG Yanchun1,LIU Weidong2(1 State Key Laboratory of Geological Processes and Mineral Resources;Key Laboratory of Underground Information Detection Technique and Instrument of Ministry of Education,China University of Geosciences,Beijing 100083;2 Department of Materialsand Chemical Engineering,Liaoning Institute of Technology,Jinzhou 121001);Bond Network Analysis and Calculation of Valence Electron Structure of Kaolinite[J];Materials Review;2009-02
4 Zhao Shunping1,2 Wang Tao1,2 Xu Heng1,2 Guo Yu3(1 School of Chemistry and Chemical Engineering,Anqing Teachers college,Anqing 246011;2 Anhui Province Key Laboratory of Light,Electricity,Magnetic Functional Complexes and Nano-complexes,Anqing 246011;3 School of Physics and Electrical Engineering,Anqing Teachers college,Anqing 246011);Preparation of Kaolinite/p-Toluene Sulfonic Acid Intercalation Compound by Melting Method[J];Non-Metallic Mines;2009-04
5 LIU Xian-yong,HE Hui,JIA De-ming (College of Material Science and Engineering,South China University of Technology,Guangzhou 510640,China);Development of Polymer/Kaolinite Nanocomposites[J];Polymer Materials Science & Engineering;2007-03
6 FENG Li,LIU Jiong-tian,SONG Suo-jiang,YIN Wen-xuan,LIN Ze(School of Chemical Engineering and Technology,University of Mining and Technology of China,Xuzhou 221008,China);Preparation and Characterization of Unsaturated Polyester Resin/Kaolinite Intercalation Nanocomposites by in Situ Polymerization[J];Polymer Materials Science & Engineering;2008-03
7 Wang linjiang (1Key Lab. of Nonfenous Mater, and New Processing Technology, Ministry of Education, GuiLin 541001; 2 Dept. of Mater. & Chem. Engineering, Guilin Institute of Technology, Guilin 541004 Wu Daqing (Guangzhou Institute of Genochemistry, Chinese Academy of Sciences, Guangzhou 510640);Progress in the Synthesis of β'-Sialon[J];Bulletin of the Chinese Ceramic Society;2004-03
8 Gu Tao Zou Zhengguang (Dept. of Materials and Chemical Engineering, Guilin University of Technology , Guilin 541004);Study on Kaolinite/Organic Intercalated Composites and Their Appli cations[J];Bulletin of the Chinese Ceramic Society;2005-04
9 JIA Zhao1,YANG Yan-gong2(1.Lutai College of Textile and Clothing,Shandong Universty of Techology,Zibo 255049,China;2.College of Materials Science and Engineering,Shandong University of Technology,Zibo 255049,China);Preparation and Characterization of PAN/Kaolinite Intercalation Compound by Solution Intercalation[J];Bulletin of the Chinese Ceramic Society;2010-04
10 LIN Zhe,FENG Li,WANG Yongtian,GUO Jin,LIU Jiongtian(School of Chemical Engineering and Technology,China University of Mining and Technology,Xuzhou 221008,Jiangsu,China);INFLUENCING FACTOR ON KAOLINITE/DIMETHYL SULPHOXIDE INTERCALATED COMPOSITE PREPARED BY ULTRASONIC RADIATION[J];Journal of the Chinese Ceramic Society;2007-05
China Proceedings of conference Full-text Database 2 Hits
1 Huang Zhaohui,Huang Juntong,Wu Xiaoxian,Sun Zhanxing,Fang Minghao,Liu Yangai (School of Materials Science and Engineering,China University of Geosciences,Beijing 100083,China);Research Progress of Synthesizing Sialon Powders from Minerals and Ores[A];[C];2009
2 NIU Hong-mei,LI Kan-she,YAN Lan-ying,ZHANG Jie-bing,LI Jin, KANG Jie,DENG Ru (College of Chemistry and Chemical Engineering,Xi'an University of Science and Technology,Xi'an 710054);Preparation of Intercalated Complexes of Kaolin with Hydrazine-hydrate and Exfoliated Kaolin[A];[C];2010
【Secondary Citations】
Chinese Journal Full-text Database 4 Hits
1 CHEN Guang Ming, QI Zong Neng *(State Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China);A Shear-induced Ordered Structure in PS/Montmorillonite Nanocomposite(Ⅰ)——Wide Angle X-ray Diffraction and Transmission Electron Microscopy Studies[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1999-12
2 CHEN Guang Ming 1, SHEN De Yan 2, CHEN Shi Juan 1, QI Zong Neng 1 [WT5”BX](1. State Key Laboratory of Engineering Plastics; 2. State Key Laboratory of Polymer Physics, Center for Molecular Science, Institute of Chemistry, Chinese Acad;A Shear-induced Ordered Structure in PS/Montmorillonite Nanocomposite(Ⅱ)──Infrared Dichroism Study[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-04
3 Chen Guangming, Li Qiang, Qi Zongneng ** , Wang Fosong (State Key Laboratory of Engineering Plastics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080);Advance in Polymer Layered Silicate Nanocomposites[J];POLYMER BULLETIN;1999-04
4 Liu Qinfu(Beijing Graduate School, China University of Mining &. Technology, Beijing. 100083)Ding Shu li(Hebei Construction Science and Technology institute. Handan, 056038);THERMAL BEHAVIOR OF POTASSIUM ACETATE COMPLEX OF KAOLINITE IN COAL-BEARING STRATA[J];ACTA MINERALOGICA SINICA;1997-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved