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《Chemical Research In Chinese Universities》 2003-12
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Preparation of Au Nanowires by a Liquid Crystal Template

ZHANG Dong-Bai, QI Li-Min, CHENG Hu-Min, MA Ji-Ming * (State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China)  
Au nanowires were synthesized in lamellar liquid crystals of C 12E 4 by using aqueous HAuCl 4 solution as the aqueous phase of the liquid crystals and the C 12E 4 itself as reducing agent. The effects of the reactant concentration, the surfactant/water molar ratio in the liquid crystal system and the reaction time on the morphology and size of the Au particles were investigated. The prepared Au nanoparticles are regular nanowires with a width of about 20 nm and a length of about several microns, showing a large aspect ratio under proper conditions. A lamellar liquid crystal templating mechanism has been proposed to interpret the experimental results.
【Fund】: 国家自然科学基金 (批准号 :2 0 0 0 3 0 0 1 2 0 2 3 3 0 10 );; 教育部优秀博士论文作者专项基金 (批准号 :2 0 0 0 2 0 );; 教育部博士学科点基金 (批准号 :2 0 0 0 0 0 0 15 5 )资助
【CateGory Index】: O614
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