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《Chemical Research In Chinese Universities》 2004-02
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Preparation and Properties of Physically Cross-linked Poly(vinyl alcohol)/ Hydroxy-terminated Polyamidoamine Dendrimer Hydrogels

WU Xu-Ye, HUANG Shi-Wen, ZHANG Jian-Tao, ZHUO Ren-Xi * (Key Laboratory of Biomedical Polymers of Minstry of Education, Department of Chemistry, Wuhan University, Wuhan 430072, China)  
Novel physically cross-linked hydrogels, composed of PVA and hydroxy-terminated polyamidoamine(PAMAM) dendrimer G6-OH, were prepared by cyclic freezing/thawing treatment of aqueous solutions containing PVA and G6-OH. FTIR analysis indicates that PAMAM dendrimer G6-OH was successfully introduced into PVA hydrogels. Higher contents of G6-OH in PVA/G6-OH hydrogels resulted in higher swelling ratios, and faster reswelling rates. With the increase of freezing/thawing cyclic times, the swelling ratios and reswelling rates of PVA/G6-OH hydrogels decreased, which is similar to that of physically cross-linked PVA hydrogel.
【Fund】: 国家重点基础研究发展规划 (批准号 :G19990 64 70 3 );; 国家自然科学基金 (批准号 :2 0 2 0 40 0 9)资助
【CateGory Index】: O631
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