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《Chemical Research In Chinese Universities》 2004-06
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Synthesis and Characterization of ZrW_(1.7)~ⅥW_(0.3)~Ⅴ O_7H_(0.3)(OH)_2·2H_2O

ZHAO Huai-Zhou 1,2 ,ZHAO Xin-Hua 1* ,HAN Bu-Xing 2* [WT5”BX](1. Department of Chemistry,Beijing Normal University,Beijing 100875,China; 2. Center for Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China) [WT5HZ]  
A new sort of heteropoly blue compound,ZrW Ⅵ_ 1.7 W Ⅴ_ 0.3 O_7H_ 0.3 (OH)_2 ·2H_2O,was synthesized by the acidic-steam hydrothermal process and the microemulsion hydrothermal process. XRD pattern proves that the heteropoly blue compound has the same type of crystal structure as that of ZrMo_2O_7(OH)_2· 2H_2O. The rietveld refinement method was used to refine the crystal structure of the heteropoly blue compound. The bond parameters were calculated and the bond valences of atoms were obtained. The EPR result affirmed the subsistence of W Ⅴ ion in the new compound,and the molar ratio of W Ⅴ/W Ⅵ was determined by XPS. Combining with bond valences of atoms and IR spectra analysis,random hydroxylation of W—O3—H_ 0.15 exits in the molecule and the FTIR absorption spectra were assigned. [WT5HZ]
【Fund】: 国家自然科学基金 (批准号 :2 98710 0 6 2 0 13 3 0 3 0 );; 北京市无机化学重点学科项目资助
【CateGory Index】: O614
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