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《Chemical Research In Chinese Universities》 2005-02
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Non-oxidative Aromatization of Methane by Using Propane as Co-reactant over Mo-Zn/HZSM-5 Catalyst

ZHENG Hai-Tao1, LOU Hui1, LI Ying-Hui2, FEI Jin-Hua1, HOU Zhao-Yin1, XU Yan2, WAN Shu-Bao2, WANG Si-Han2, ZHENG Xiao-Ming 1*(1. Institute of Catalysis, Zhejiang University, Hangzhou 310028, China;2. Research Institute of Daqing Petrochemical Company, Daqing 163714, China)  
The non-oxidative conversion of methane(C_1) into aromatic hydrocarbons by using propane(C_3) as co-reactant over x%Mo+6%Zn/HZSM-5 catalysts was studied. C_1 conversion was very high, reaching 29%_35%. Selectivity of aromatic products reaches above 80% at 873 K and GHSV=3 L/(g·h) with n(C_1)/n(C_3)=1.0. The excellent conversion of C_1(34.8%) was obtained over 0.7%Mo+6%Zn/HZSM-5 catalyst at 873 K and n(C_1)/n(C_3)=1.0. The effects of time-on-stream and n(C_1)/n(C_3) on C_1 and C_3 conversion and the products distribution were analyzed in order to obtain information about C_1 incorporation into the aromatic products and the evolution of different species. C_1 incorporation was conclusively confirmed by the mass spectral analyses of aromatic products produced in a run with 13CH_4, which shows a significant 13C enrichment in the C_6H+_6, C_7H+_8 and C_8H+_ 10 fragments. The methane activation could result from its hydrogen-transfer reaction with alkenes. This process was hoped to provide a novel route for the chemical utilization of natural gas and refinery gas.
【Fund】: 国家自然科学基金 (批准号 :2 0 3 43 0 0 2 );; 浙江省自然科学基金 (批准号 :990 3 );; 中国石油天然气总公司基金资助
【CateGory Index】: O643.3
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【References】
Chinese Journal Full-text Database 9 Hits
1 YOU Hong-jun(College of Chemical Engineering,Liaoning University of Petrolem and Chenical Technology,Fushun 113001,China);Effects of Reaction Temperature on the Aromatization Reaction of Huabei C4 Liquefied Petroleum Gas[J];Journal of Guangdong University of Technology;2007-01
2 ZHANG Pei-Qing~(1*),GUO Hong-Chen~(2),WANG Xiang-Sheng~(2),GUO Xin-Wen~(2)(1.Institute of Applied Catalysis,Yantai University,Yantai 264005,China;2.State Key Laboratory of Fine Chemicals;Institute of Industrial Catalysts,Dalian University of Technology,Dalian 116012,China);Conversion of n-Octane over Modified Nano-crystallite ZSM-5 Catalyst[J];Chemical Journal of Chinese Universities;2006-05
3 ZHANG Pei-Qing 1*, GUO Hong-Chen2, ZHU Hong-Jie1, WANG Xiang-Sheng2, JIANG Xue-Mei1, WANG Ping1 (1. Institute of Applied Catalysis, Yantai University, Yantai 264005, China; 2. State Key Laboratory of Fine Chemicals, Institute of Industrial Catalysts, Dalian University of Technology, Dalian 116012, China);Conversion of Hydrocarbons over Nano-HZSM-5 Catalysts[J];Chemical Journal of Chinese Universities;2006-12
4 YOU Hongjun(Liaoning University of Petroleum & Chemical Technology,Fushun 113001,Liaoning,China);Aromatization of Huabei C_4 liquefied petroleum gas[J];Industrial Catalysis;2007-05
5 ZHU Yang (Department of Chemistry Engineering,Jingmen Technical College,Jingmen 448000,China);Direct conversion and use technologies of methane[J];Chemical Engineer;2007-08
6 GAO Yuan,BAI Ying-zhi,SHI Yan,ZHAO Li-xiang and LIU Lu(College of Petrochemical Technology,Liaoning University of Petroleum & Technology,Fushun 113001,China);Effect of Modification on Aromatization Performance of ZSM-5 Molecular Sieve[J];Chemistry and Adhesion;2009-02
7 XUE Ying~(1),WU Yu~(2*),WAN Jia-yi~(1)(1.College of Chemistry,Sichuan University Chengdu 610064;2.Sichuan Institute of Product Quality Supervision and Inspection,Chengdu 610031);Progress in Structure and Catalysis Properties of ZSM-5 Zeolites[J];Journal of Minayang Normal University;2005-05
8 YOU Hong-jun(Liaoning University of Petroleum and Chemical Technology,Fushun 113001,China);Effects of Feed Space Velocity on the Aromatization of Huabei C4 LPG[J];Natural Gas Chemical Industry;2007-01
9 ZHAO Yong-hua1,CAO Chun-yan2,WANG Hai-yan1,Wei Min1,MA Jun1(1.College of Petroleum and Chemical Technology,LiaoNing University of Petroleum and Chemical Technology,Fushun 113001,China;2.College of Chemistry and Chemical Technology,BoHai University,Jinzhou 121000,China);Research Progress in the Aromatization of Light Hydrocarbons over HZSM-5 Catalysts[J];Natural Gas Chemical Industry;2007-05
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 YANG Sheng yi,WANG Zhen jia,CHEN Xiao hong,XU Zheng, DONG Jin feng,HOU Yan bing,ZHANG Xi qing (Institute of Optoelectronic Technology, Northern Jiaotong University, Beijing 100044,China);Electroluminescent Devices Made from Poly(p-Phenylene Vinylene) Derivatives[J];SEMICONDUCTOR OPTOELECTRONICS;2000-02
2 Deng Jing-fa, Zhang Gui-rong, Yan Man-ming, Pan Hai-shui,Wang Huai-ming,(Department of Chemistry, Fudan University, Shanghai) and Dong Shu-zhong(Institute of Modern Physics, Fudan University, Shanghai);STUDIES ON THE ACIDIC PROPERTIES OF ZSM-5 TYPE ZEOLITES AND THE CATALYTIC CONVERSION OF ETHANOL TO ETHER[J];Chinese Journal of Catalysis;1987-04
3 YIN Shuangfeng, LIN Jie *, YU Zhongwei (Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China);Effect of Zinc Content on Properties of Zn/HZSM-5 Zeolite Catalyst[J];Chinese Journal of Catalysis;2001-01
4 SHU Yuying, TIAN Binglun, MA Ding, BAO Xinhe, XU Yide (State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, China);Methane Dehydro-Aromatization over Mo/HZSM-5 Catalyst Prepared by Different Methods[J];Chinese Journal of Catalysis;2001-02
5 WANG Liqin 1,2*, WANG Xiangsheng 1, GUO Xinwen 1, LI Gang 1, XIU Jinghai 1, LIU Song 1(1 State Key Laboratory of Fine Chemicals, Department of Catalytic Chemistry and Engineering, Dalian University of Technology, Dalian 116012, Liaoning, China; 2 Department of Chemical Engineering, Qiqihar University, Qiqihar 161006, Heilongjiang, China);Study on Crystallization Kinetics for Synthesis of TS-1 Zeolite and Its Catalytic Performance[J];Chinese Journal of Catalysis;2003-02
6 GUO Xinwen 1* , WANG Xiangsheng 1, SHEN Jianping 2, SUN Lu 2, SONG Chunshan 2 (1 State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, Liaoning, China; 2 Department of Energy & Geo Environmental Engineering, The Pennsylvania State University, University Park, PA 16802, USA);Methylation of 4-Methylbiphenyl with Methanol over Metal Oxide-Modified HZSM-5 Zeolite Catalysts[J];Chinese Journal of Catalysis;2003-05
7 ZHANG Peiqing 1, WANG Xiangsheng 1*, GUO Hongchen 1, ZHU Wenliang 1, ZHAO Leping 2, HU Yongkang 2(1 State Key Laboratory of Fine Chemicals; Institute of Industrial Catalysts, Dalian University of Technology, Dalian 116012, Liaoning, China; 2 Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun 113001, Liaoning, China);Performance of Modified Nano-crystallite ZSM-5 Catalysts for Removing Olefins in Gasoline[J];Chinese Journal of Catalysis;2003-08
8 WANG Weijia *, LU Lijun, ZONG Baoning, SHU Xingtian(Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China);Preparation of New Structured FeZSM-5/Raney Fe Catalyst for DeNO_x[J];Chinese Journal of Catalysis;2003-10
9 ZHANG Peiqing 1, WANG Xiangsheng 1* , GUO Hongchen 1, XU Zhoubo 1, ZHAO Leping 2, HU Yongkang 2(1 State Key Laboratory of Fine Chemicals and Institute of Industrial Catalysts,Dalian University of Technology, Dalian 116012, Liaoning, China;2 Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun 113001, Liaoning, China);Influence of Hydrothermal Treatment on Acid Property and Catalytic Performance of Nano-HZSM-5 Zeolite for Reducing Olefins in Gasoline[J];Chinese Journal of Catalysis;2003-12
10 SHANG Yongchen 1,2, ZHANG Wenxiang 1, LI Tong 2, WU Tonghao 1*(1 College of Chemistry, Jilin University, Changchun 130023, Jinlin, China; 2 Department of Chemistry, Harbin Normal University, Harbin 150080, Heilongjiang, China);Isomerization of 1-Butene on MCM-49 Molecular Sieve Catalyst[J];Chinese Journal of Catalysis;2004-02
China Proceedings of conference Full-text Database 1 Hits
1 YOU Hong-jun XU Chun-ming GAO Jin-shen LIU Zhi-chang YAN Ping-xiang (State Key Laboratory of Heavy Oil Processing,University of Petroleum,Changping Beijing 102249,China)$$$$;Study on the aromatization reaction of gasoline and compound C_4[A];[C];2005
【Secondary References】
Chinese Journal Full-text Database 7 Hits
1 DING Chun-Hua, WANG Xiang-Sheng*, GUO Xin-Wen(State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China);Effect of Hydrothermal Treatment of MCM-22 Catalyst on the Acidity, Pore Structure and Alkylation Properties of Toluene with Methanol[J];Chemical Journal of Chinese Universities;2007-05
2 WANG Kunyuan,WANG Xiangsheng(State Key Laboratory of Fine Chemicals,Department of Catalytical Chemistry and Engineering,Dalian University of Technology,Dalian 116012,Liaoning,China);Research development on nanoscale ZSM-5 zeolites[J];Industrial Catalysis;2008-02
3 GAO Yuan,BAI Ying-zhi,SHI Yan,ZHAO Li-xiang and LIU Lu(College of Petrochemical Technology,Liaoning University of Petroleum & Technology,Fushun 113001,China);Effect of Modification on Aromatization Performance of ZSM-5 Molecular Sieve[J];Chemistry and Adhesion;2009-02
4 ZHANG Zhen-li, ZHOU Ya-song, LI Chang-xi, XU Chun-ming(State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing 102249, China);Hydroisomerization and aromatization of n-octane over HZSM-5/Hβ composite zeoliue[J];Journal of Fuel Chemistry and Technology;2008-02
5 Zhang Fei,Jiang Jianzhun,Zhang Mingsen,Yang Yuanyi(Beijing Research Institute of Chemical Industry,SINOPEC,Beijing 100013,China);Preparation and Modification of Catalyst for Conversion of Methanol to Light Olefins[J];Petrochemical Technology;2006-10
6 LI Yu-ning1,3,XIE Su-juan1,NA Ying-zi2,WANG Qing-xia1,XU Long-ya1(1.Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China;2.Fushun Petrochemical Company,CNPC,Fushun 113001,China;3.Graduate School of the Chinese Academy of Sciences,Beijing 100039,China);The Hydroisomerization and Aromatization of 1-Hexene over Potassium Modified MCM-22 Zeolite[J];Natural Gas Chemical Industry;2007-06
7 Yao Lei1,Wu Weizhong1,Zhou Mingqiu2,Qiu Zhaorong1(1.Department of Chemical Engineering Jiangsu Polytechnic University,Fine Chemical Technology Key Laboratory of Jiangsu,Changzhou 213016;2.Aromatics Plant of Yangzi Petrochemical Company);STUDY ON THE ATMOSPHERIC AROMATIZATION OF BACK WASHING LIQUID FROM AROMATICS EXTRACTION[J];Petroleum Processing and Petrochemicals;2009-06
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