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《Chemical Research In Chinese Universities》 2005-03
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Synthesis, Characterization and Catalytic Performence of La_(1-x)Ce_xSrNiO_4(0≤x≤0.7) in NO_x Decomposition

ZHU Jun-Jiang 1,2, XIAO De-Hai1, LI Jing1, YANG Xiang-Guang 1*, WU Yue1 (Laboratory of Material and Device, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China)  
A series of La_ 1-xCe_xSrNiO_4(0≤x≤0.3) oxides were synthesized through the citric method. It was found that the content of Ce in A-site of La_ 1-xCe_xSrNiO_4 could reach 30%. When La was partly replaced by Ce in La_ 0.7Ce_ 0.3SrNiO_4, the catalytic activity of NO decomposition was obviously improved not only in the absence of oxygen, but also in the presence of oxygen. The activity of La_ 0.7Ce_ 0.3SrNiO_4 in NO decomposition reached 42.2%(1 123 K)in the presence of 6.0%O_2, which indicated that La_ 1-xCe_xSrNiO_4 was a potential catalyst for NO removal.
【Fund】: 国家自然科学基金 (批准号 :2 0 1770 2 2 );; 国家“八六三”计划 (批准号 :2 0 0 1AA3 2 40 60 )资助 .
【CateGory Index】: O643.3
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