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《Chemical Research In Chinese Universities》 2005-04
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Amphiphilic HZSM-5 Zeolite Catalyst for Hydration of Cyclohexene on Phase-boundary Interface

MA Bing-Li, CHUN Yuan*, ZHOU Wei, PAN Jian, XU Qin-Hua, DONG Jia-Lu(Key Laboratory of Mesoscopic Materials of Ministry of Education, Department of Chemistry, Nanjing University, Nanjing 210093, China)  
Amphiphilic HZSM-5 zeolite particles were prepared by a partial modification of the external surface of HZSM-5 zeolite with trimethylchlorosilane. These amphiphilic zeolite particles were oriented at the water-organic boundary when they were added to the mixture of cyclohexene and water or water with CCl_4. IR spectra indicated that the intensity of the band for the terminal silanols decreased significantly and the band for the methyl groups(C_H stretching vibration) emerged after modification, which gave a direct evidence that partial hydrophilic silanol groups on the surface of the zeolite were replaced by the hydrophobic alkylsilyl groups. This amphiphilic HZSM-5 zeolite exhibited a much higher catalytic activity than the parent HZSM-5 zeolite in the hydration of cyclohexene phase-boundary reaction without adding co-solvents and stirring. Because this phase-boundary reaction was proceeding through a channel-reaction mechanism, the hydrophobic HZSM-5 particles modified by trimethylchlorosilane also showed the better catalytic performance than the parent zeolite.
【Fund】: 国家自然科学基金青年基金(批准号:20203010);; 南京大学开放测试基金(批准号:0205001330)资助.
【CateGory Index】: O643
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