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《Chemical Research In Chinese Universities》 2005-06
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Synthesis and Characterization of Water-soluble Zinc Porphyrin Complex and Its Interaction with CT DNA

KANG Jing-Wan~*, WU Hai-Xia, LU Xiao-Quan, SU Bi-Quan, ZHOU Lin (Department of Chemistry, Northwest Normal University, Lanzhou 730070, China)  
A porphyrin 5,10,15,20-tetrakisporphyrin and its Zn complex(TPPBr(Zn)) were synthesized and characterized. The interaction of TPPBr(Zn) with CT DNA was studied by UV-Vis spectroscopy, fluorescence spectra, circular dichroic spectrum and viscosity measurements. The constant of TPPBr(Zn) binding to CT DNA is 2.64×10~5 L/mol. The results suggest that the porphyrin complex can bind to DNA by self-stacked outside binding and static binding.
【Fund】: 国家自然科学基金(批准号:20275031 20335030);; 西北师范大学创新工程(批准号:KJCXGC-01)资助.
【CateGory Index】: O627.23
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