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《Chemical Research In Chinese Universities》 2005-07
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Synthesis and Characterization of PPTA/MgAl-LDH Nanocomposite by in situ Polymerization

GUO Bing-Zhi, JIAO Qing-Ze+*(School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China)  
A poly(p-phenylene terephthalamide)(PPTA)/MgAl layered double hydroxides(MgAl-LDH) exfoliation nanocomposite was synthesized by in situ polymerization of p-phenylenediamine with terephthalate-pillared hydroxides, Mg-4Al-2(OH)-{12}. The samples thereby obtained were characterized by X-ray diffraction, transmission electron microscopy image and thermal analysis. The results show that the layers of terephthalate-pillared hydroxides are exfoliated and dispersed disorderly in the PPTA matrix, the crystallinity of nanocomposite was improved compared with the original {PPTA}. Thermogravimetric analysis indicates that the thermal stability of PPTA/MgAl-LDH decrease to a certain degree.
【Fund】: 国防“十五”计划预研基金项目(批准号:41328030507)资助.
【CateGory Index】: TB383;
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