Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chemical Journal of Chinese Universities》 2006-03
Add to Favorite Get Latest Update

Synthesis, Characterization and Catalytic Behavior of V-Si-β Molecular Sieves

YU Ling 1, HE Hong-Yun 1*, HE Chi-Jian 1, ZHU Hua-Yuan 1, WEN Jian-Jun 1, PANG Wen-Qin 2 (1. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China; 2. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130012, China)  
V-β molecular sieves through isomorphous replacement of Si by V in zeolite β were successfully synthesized via hydrothermal procedure. The synthesis conditions were as follows: the molar chemical composition of the mixture: 60SiO_ 2-xV_ 2O_ 5-y(TEA)_ 2O-zH_ 2O-wNH_ 4F ( 1≤x≤6, y≥16, 500≤z≤800, w≥5 ), reaction temperature 413 K, reaction time 12 d. The synthesized samples are characterized by XRD, IR, UV-Vis, TG, DTA and SEM. The results confirm that V-β molecular sieves contain a β phase of good species, and show the presence of V iron in the framework position. In the system the catalytic behavior of V-β molecular sieves in the hydroxylation of phenol with H_ 2O_ 2 as the oxidant was also investigated.
【Fund】: 湖南省自然科学基金(批准号:04JJ40011);; 吉林大学无机合成与制备化学国家重点实验室基金资助.
【CateGory Index】: O643.36
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 1 Hits
1 HOU Qi-jun (State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China);Greening of Surfactant Industry[J];Fine and Specialty Chemicals;2008-19
【Citations】
Chinese Journal Full-text Database 5 Hits
1 HE Hong-Yun , PANG Wen-Qin, MENG Xian-Ping (Department of Chemistry, Jilin University, Oiangchun, 130023);Studies on the Hydrothermal Synthesis and Structure of (Ga, Fe, B)-βZeolites[J];Chemical Research In Chinese Universities;1993-02
2 HE Hong\|Yun\+\{1,2\}, PANG Wen\|Qin\+\{1*\}, LIU Wu\|Yang\+3, DENG Feng\+3 (1. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130023, China; 2. The Institute of Chemistry and Chemical Engineering, Hun;Influence of the Synthesis Condition on the Crystallization of Fe-β Zeolite Molecular Sieves in the Absence of Aluminum[J];Chemical Research In Chinese Universities;2002-03
3 ZHOU Wei, CHUN Yuan*, XU Qin-Hua, WANG Cheng, DONG Jia-Lu (Department of Chemistry, Nanjing University, Nanjing 210093, China);A Novel Liquid-solid Isomorphous Substitution Route for Preparing Zeolite Ti-β[J];Chemical Research In Chinese Universities;2004-01
4 WEI Bo 1*, LIU Jian-Hong1, SUN Jian-Min2, XIN Ming-Hong2, HONG Wei-Liang1, XIAO Feng-Shou2, QIU Shi-Lun2 (1. Normal College, Shenzhen University, Shenzhen 518060, China; 2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China);Synthesis and Catalytic Properties of Large Single Crystal FeAPO-5 Molecular Sieves[J];Chemical Research In Chinese Universities;2005-03
5 DU Hong-Bin; TU Kun-Gang; ZHOU Qun; ZHOU Fen-Qi; PANG Wen-Qin(Key Laboratry of Inorganic Hydrothermal Synthesis, Jilin University,Changchun, 130023);Synthesis and Characterization of V-ZSM-5 Zeolites in Weak Acidic Medium[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1994-04
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 MA Bingli,CHUN Yuan~*,XU Qinhua,DONG Jialu(School of Chemistry and Chemical Engineering,Key Laboratory of Mesoscopic Chemistry of the Ministry of Education,Nanjing University,Nanjing 210093,Jiangsu,China);Preparation and Characterization of Amphiphilic HZSM-5 Zeolite with Various Si/Al Ratios[J];Chinese Journal of Catalysis;2005-11
2 MA Bingli,CHUN Yuan~*,XU Qinhua,DONG Jialu(Key Laboratory of Mesoscopic Chemistry of the Ministry of Education,School of Chemistry and ChemicalEngineering,Nanjing University,Nanjing 210093,Jiangsu,China);Preparation of Amphiphilic Zeolites with Various Pore Structure and Their Catalytic Performance for Phase-Boundary Reaction[J];Chinese Journal of Catalysis;2006-08
3 REN Yong-li, MI Zhen-tao (Key Laboratory for Green Chemical Technology, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China);Effect of Preparation Condition on Content of Frameworks-Site V Atoms in V-AlPO_4-5 Sieves and the Catalytic Activities for the Oxidation of Benzene[J];Journal of Molecular Catalysis;2005-01
4 LIU Yun Ling, WANG Xing Dong, PANG Wen Qin * [WT5”BX](Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China) [WT5HZ];Preparation and Characterization of SAPO-34 and SAPO-44 Molecular Sieves Membranes[J];Chemical Research In Chinese Universities;2000-10
5 HE Hong\|Yun\+\{1,2\}, PANG Wen\|Qin\+\{1*\}, LIU Wu\|Yang\+3, DENG Feng\+3 (1. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130023, China; 2. The Institute of Chemistry and Chemical Engineering, Hun;Influence of the Synthesis Condition on the Crystallization of Fe-β Zeolite Molecular Sieves in the Absence of Aluminum[J];Chemical Research In Chinese Universities;2002-03
6 BAI Ni1, ZHANG Ping1, GUO Yang-Hong1, LI Shou-Gui1, PANG Wen-Qin1 * , LUO Wei2, ZOU Guang-Tian2(1. State Key Lab of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China; 2. State Key Lab of Superhard Materials, Jilin U;Inclusion and Illuminant Property of Eosin Y into Mesoporous Molecular Sieve MCM-41 Film and Powder[J];Chemical Research In Chinese Universities;2002-05
7 MA Bing-Li, CHUN Yuan*, ZHOU Wei, PAN Jian, XU Qin-Hua, DONG Jia-Lu(Key Laboratory of Mesoscopic Materials of Ministry of Education, Department of Chemistry, Nanjing University, Nanjing 210093, China);Amphiphilic HZSM-5 Zeolite Catalyst for Hydration of Cyclohexene on Phase-boundary Interface[J];Chemical Research In Chinese Universities;2005-04
8 LIAO Ai-min(Chemical Industry Academy,East China University of Science and Technology,Shanghai 200237);Research on Mesoporous Molecular Sieves Catalyze Cyclohexene Oxidation[J];Hebei Chemical Engineering and Industry;2007-05
9 HE Chi-jian, LUO Zhi-ping, HE Hong-yun, FANG Zheng-fa (College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha, 410081,China);Studies on the Synthesis of Fe-β Zeolite by Using Nucleation Gel[J];Journal of Natural Science of Hunan Normal University;2004-01
10 Yang Senlin~1 Kong Liming~(1,2) Liu Xiaoqin~1 (1.College of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China; 2.College of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou 225009,China);Characterization of FeAPO-5 Molecular Sieve in the Presence of HF and Its Catalytic Performance for Phenol Hydroxylation[J];Chemical Reaction Engineering and Technology;2007-06
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 LI Juan~1 YAN Shi-cheng~2 LI Jian-wei~1 CHEN Biao-hua~1 DENG Wei~1(1.State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China;2.Jilin Vocational College of Industry and Technology,Jilin 132000,China);Dodecylbenzene synthesis by the alkylation of benzene with 1-dodecene over mesoporous zeolites[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2006-06
2 SHI Xiao-bo,FU Hai-ping,LI Chun-gen,WANG De-xian(Institute of Chemistry,Jiangxi Normal University,Nanchang 330027,China);Catalytic Performance of Bi_2Mo_3O_(12) for Hydroxylation of Phenol with Hydrogen Peroxide[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2003-01
3 YU Bing-chuan,WU Hong-te,ZHU Zhong-jun(College of Chemistry and Environmental Engineering,Yangtze University,Jingzhou434025,China);Preparation of complex catalyst SO~(2-)_4/ZrO_2-TiO_2 and its application in reaction for synthesis of alkyl polyglucoside[J];China Surfactant Detergent & Cosmetics;2005-01
4 XI Li-min~(1,2),REN Qi-long~2(1.Taizhou Technical College,Departement of Biological and Chemical Engineering,Taizhou 318000,China;2.Zhejiang University,National Laboratory of Secondary Resources Chemical Engineering,Hangzhou 310027,China);Preparation of fatty acid methyl ester catalyzed by solid acid from by-products of plam oil[J];China Surfactant Detergent & Cosmetics;2006-06
5 QI Xiaolan 1, LIU Xiyao 1, LIN Bingxiong 2(1 Research Institute of Yanshan Petrochemical Company, Beijing 102500, China; 2 Institute of Physical Chemistry, Peking University, Beijing 100871, China);Synthesis of β Zeolite Using TEABr Fluoride as Composite Template Ⅰ. Stability Phase Area on Thermodynamics of Crystallization[J];CHINESE JOURNAL OF CATALYSIS;2000-01
6 LI Gong 1,2, KAN Qiubin 1, TONG Huijuan 2, WU Tonghao 1*, XU Ning 1, WU Peng 1, WANG Dongyang 1 (1 College of Chemistry, Jilin University, Changchun 130023, Jilin, China; 2 Department of Chemical Engineering,Jiangsu Polytechnic University, Changzhou 213016, Jiangsu, China);Catalytic Performance of Nanometer MCM-49 Zeolite for Alkylation Reaction of Benzene with 1-Dodecene[J];Chinese Journal of Catalysis;2004-10
7 LIU Min1, GUO Xinwen 1* , GAO Jian1, WANG Xiangsheng1, LIU Xiumei2, HAN Xiuwen2, BAO Xinhe2(1 State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, Liaoning, China; 2 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China);Effect of Low-Temperature Crystallization on Physico-Chemical Properties of B-ZSM-5 and Ti-ZSM-5[J];Chinese Journal of Catalysis;2005-08
8 CHEN Song~(1,2*),XU Jie~1,YANG Yongrong~1,WANG Jingdai~1,ZHANG Xiaoping~2,ZHANG Kuixi~2(1 UNILAB Research Centre of Chemical Reaction Engineering,Zhejiang University,Hangzhou 312000,Zhejiang,China;2 Fushun Research Institute of Petroleum and Petrochemicals,SINOPEC,Fushun 113001,Liaoning,China);Nanometer β Zeolite Made from Mesoporous Zeolite and Its Hydrocracking Performance[J];Chinese Journal of Catalysis;2006-03
9 Ma, De-fu ; Gu, Shu-zhen and Yang, Rong-bin (Department of Chemical Engineering, Shanghai University of Engineering Science, Shanghai 200051 );STUDY ON THE CORRELATION BETWEEN SURFACE ACIDITY OF HZSM-5 ZEOLITES AND CATALYTIC ACTIVITY FOR n-BUTYL ACETATE SYNTHESIS IN LIQUID PHASE[J];CHINESE JOURNAL OF CATAL YSIS;1995-02
10 Zheng Wenzhi, Li Yuliang, Yu Guangqian, Li Xiaoli (Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);RESEARCH ON POLYMER SUPPORTED RARE EARTH METAL COMPLEXES ⅩⅠⅤ. Poly(Styrene Acrylamide) Supported NdCl 3 Complex in Catalytic Polymerization of Butadiene[J];CHINESE JOURNAL OF CATAL YSIS;1996-03
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Qiu Shilun, Pang Wenqin, Zhao Daqing (institute of Synthetic and Catalytic Chemistry, Jilin University, Changchun);Synthesis of B-ZSM-5 Zeolites in Slightly Acidic Medium[J];Chemical Research In Chinese Universities;1988-10
2 Xiang Shouhe, Wang Qiuying, Wang JingzhongWang Kebing, Li Hexuan (Department of Chemistry, Nankai University, Tianjin);Synthesis and Acidity of B-β Zeolite[J];Chemical Research In Chinese Universities;1989-07
3 Han Shuyun (Department of Chemistry, Qiugdao University, Qingdao)Yang Chuncai, Wei Quan (Department of Chemistry, Jilin University, Changchun)Yuan Hanzhen (Wuhan Institute of Physics, Academia Sinica, Wuhan);Studies on the Structure and Properties of Divalent Metal Aluminophosphate Molecular Sieve[J];Chemical Research In Chinese Universities;1990-04
4 Jiao Qingzhu, Pang Wenqin (Institute of Synthetic and Catalytic Chemistry of Jilin University, Changchun);Syntheses and Structures of Cr-ZSM-48 and V-ZSM-48 Molecular Sieves[J];Chemical Research In Chinese Universities;1990-08
5 HE Hong-Yun , PANG Wen-Qin, MENG Xian-Ping (Department of Chemistry, Jilin University, Oiangchun, 130023);Studies on the Hydrothermal Synthesis and Structure of (Ga, Fe, B)-βZeolites[J];Chemical Research In Chinese Universities;1993-02
6 WEI Bo, YU Ji Hong, DING Hong, SHAO Chang Lu, LI Xiao Tian, QIU Shi Lun  [WT5”BX](Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China) [WT5HZ];Studies on Phase Transition of Orthorhombic AlPO_4-5 Molecular Sieve by Infrared Spectra[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-06
7 LI Bao-Zong, GUO Yong-Min, PANG Wen-Qin(State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130023, China;Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, China);A Relationship Between Adsorption Heat and Structure ofAdsorbate Molecule in NaX Zeolite Molecular Sieves[J];Chemical Research In Chinese Universities;2002-04
8 LI Bao Zong, XU Wen Guo, QIU Shi Lun, PANG Wen Qin *, XU Ru Ren (Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Department of Chemistry of Jilin University, Changchun, 130023);Quantum chemical Calculation for Fluorine Ion Influence on Double Four membered Ring of Zeolite Molecular Sieves Structure[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1998-06
9 ZHOU Qun *, LI Bao Zong (Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou, 215006) QIU Shi Lun, PANG Wen Qin (Department of Chemistry, Jilin University, Changchun, 130023);Synthesis of Low Si/Al β Zeolite by Using Nucleation Gel[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1999-05
10 He, Hong-Yun Meng, Xian-Ping Zhou, Feng-Qi Pang, Wen-Qin(Department of Chemistry, Jilin University, Changchun, 130023);Synthesis and Structural Charactrization of Ultrafine Powder Ga-BETA Zeolite[J];Acta Chimica Sinica;1994-04
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved