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《Chemical Journal of Chinese Universities》 2006-07
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Studies on Binding of Molecularly Imprinted Polymer Composite Membranes to Coumarin-3-carboxylic Acid as Template and Permeable Selectivity

MA Xiang-Xia~(1),HE Xi-Wen~(1),ZHANG Mo~(1), LI Wen-You~(1*),ZHANG Yu-Kui~(1,2*) (1.Department of Chemistry,Key Laboratory of Functional Polymer Materials,Ministry of Education,Nankai University,Tianjin 300071,China; 2.National Chromatographic Research & Analysis Center,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116011,China)  
Using coumarin-3-carboxylic acid as template molecule,molecularly imprinted polymer composite membranes with supporting membrane(polyvinylidene fluoride) were prepared through in situ polymerization by UV-irradiation.The polymer membranes were synthesized by using acrylamide as the hydrogen-bonding monomer and ethyleneglycol dimethacrylate(EDMA) or tris(hydroxymethyl) propane trimethacrylate(TRIM) as cross linker.By comparing adsorption and permeation of the membranes with EDMA or TRIM as cross linker,and different solvents,the imprinted membranes with TRIM as the cross lingker and acetonitrile as solvent showed a higher adsorption capability,and the imprinted membranes with TRIM as the cross lingker and acetonitrile-water(volume ratio 1∶9) as the solvent showed higher permeation selectivity to the template.
【Fund】: 国家自然科学基金(批准号:20375017和20445001)资助
【CateGory Index】: O631.3
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