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《Chemical Journal of Chinese Universities》 2007-03
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Synthesis of MCM-36 Molecular Seive and Studies on Catalytic Performance of MCM-36 on Benzene Alkylation with Propylene

ZHANG Yu1,2, XING Hai-Jun1, WU Shu-Jie1, WU Peng1, YANG Piao-Ping1, JIA Ming-Jun1, WU Tong-Hao1, SUN Chia-Chung 3(1. College of Chemistry, Jilin University, Changchun 130021, China; 2. Department of Chemical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, China; 3. State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130021, China)  
Pillared layered MCM-36 zeolites were prepared from MCM-22 and MCM-49 precursors with polymeric silica as the pillaring agent, respectively. The structure and acid properties of samples were studied by means of N2 adsorption, XRD, and FTIR. A higher BET specific surface area and a significant mesopore volume is obtained for MCM-36(A). The amount of Brnsted and Lewis acid sites in MCM-36(A) decreases obviously compared to MCM-22 resulting from the same precursor. For MCM-36(B) synthesized from MCM-49 precursor, the intensity of low angle XRD peak is lower than that of MCM-36(A), and the amount of acid sites decreases moderately compared to MCM-49. Under our operation conditions, the MCM-36(A) zeolite shows a higher activity and selectivity to cumene than MCM-22 zeolite. MCM-36(B) exhibits a higher activity but lower selectivity to cumene compared to MCM-36(A). Combined with the characterization results of acidic properties and textural parameters, we suppose that the increase of the selectivity to cumene in MCM-36 should be mainly due to the decrease of the density of Brnsted acidity, while the improvement of the catalytic activity of MCM-36 can be mainly assigned to the presence of a larger amount of structurally accessible acid sites in this material.
【Fund】: 国家自然科学基金(批准号:20273025);; 吉林省科技厅科研基金(批准号:20040572)资助
【CateGory Index】: O621.2
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