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《Chemical Journal of Chinese Universities》 2012-04
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Molecular Recognition Mechanism of Chiral(S)-Ibuprofen's Hydrogen Bonds Self-assembly Imprinted Polymer

SUN Yan,WANG Bing(State Key Laboratory of Hollow Fiber Membrane Materials and Processes,Ministry of Education,School of Environmental and Chemical Engineering,Tianjin Polytechnic University,Tianjin 300160,China)  
A series of imprinted polymer was synthesized using chiral(S)-ibuprofen with a single polarity group as the template molecular.The calculated results of UV indicated the complex ratio of host-guest was 1∶ 1.IR analysis result revealed in the pre-assembly process and re-adsorption process,the blue-shifted hydrogen bonds and red-shift hydrogen bonds were formed between template molecule and functional monomer,respectively.The isotherm results indicated that the specificity binding capacity was 37.92 μmol/g,and the imprinted factor of the polymer was 3.06.The chiral separation experiment indicated that compared with(R)-ibuprofen,(S)-ibuprofen template polymer exhibited significant adsorption selectivity for(S)-ibuprofen.Also,the separation factor was 1.79.
【Fund】: 天津市自然科学基金重点项目(批准号:10JCZDJC21900)资助
【CateGory Index】: O631.3
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