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《CHEMICAL RESEARCH IN CHINESE UNIVERSITIES》 1994-08
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The Theory of Cyclic Voltammetric Reversible Wave at Polyaniline Thin Film-Coated Electrode and Its Experimental Verification

YIN Bin;SUN Qiang;ZHANG Zu-Xun(Department of Chemistry,Nanjing University,Nanjing,210008)  
The theoretical equation of reversible wave in cyclic linear sweep voltammetry on polyaniline thin film-coated electrode is described. The characters of the voltammogram curves are discussed in detail.Polyaniline films were deposited on the Pt electrode by oxidative polymerization of aniline at 0.01 0.10 mA/cm2 in 2.0 mol/L HCl solution containing 1.09 mol/L monomer. It has been found that the polyaniline film prepared in this manner was homogeneous and uniform in its thickness.In order to examine the validity of the equation, experimental studies were carried out at the PANI thin film-coated electrode in 10 mol/L HCl solution.The observed results are in good agreement with the theoretical ones.
【Fund】: 国家自然科学基金,中国科学院长春应用化学研究所电分析化学开放实验室和南京大学分析测试中心资助
【CateGory Index】: O657.14
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