Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《CHEMICAL RESEARCH IN CHINESE UNIVERSITIES》 1995-08
Add to Favorite Get Latest Update

Studies on the Synthesis of Dipentyl Phthalate Using Hydrotalcite-Containing Rare Earth as a Catalyst

LI Lian-Sheng; MA Shu-Jie, HUI Jian-Bin, LIU Xin-Sheng,XU Ru-Ren(Department of Chemistry,Jilin Universtity,Changchun,130023) BAO Yu-Min (Department of Chemistry,Inner Mongolia Nationalities Teacher' s College)  
Synthesis of dipentyl phthalate using hydrotalcite-containing rare earth as a catalyst is studied in detail,involved influence of amount of the catalyst,mole ratio of phthalic anhydride to n-pentanol,reaction temperature and time on the conversion of phthalic anhydride to dipentyl phthalate. The results show that the catalyst has a high catalytic activity and high selectivity,and the conversion is up to 95%.La content in the catalyst may change in a certain range and the conversion of phthalic anhydride increases with increasing of La content.The surface area of the catalyst calcined at 400℃ is about 120 m2/g (BET/N2 technique). It has Lewis and Bronsted acid sites and the amount of Lewis acid is far more than that of Bronsted acid.The mole ratio of chemical composition of the catalyst is Mg:Al:La=6:(2-x):x, where 0≤x≤1.0.
【Fund】: 国家自然科学基金
【CateGory Index】: O625.523
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 10 Hits
1 AN Zhi-huan1,CHEN Tian-hu2,PENG Shu-chuan2(1.East China Engineering Science and Technology Co,Ltd.,Hefei 230024,China; 2.Dep.of Resource & Environment,Hefei University of Technology,Hefei 230009,China);Research of Ponceau 4R Anion Intercalated Mg/Al-LDH Crystal Lattice Structure[J];Anhui Chemical Industry;2011-01
2 Du Yibo He Jing Li Feng D G Evans Duan Xue Wang Zuoxin (Departmint of Applied Chemistry,Beijing University of Chemical Technology,Beijing,100029);The Preparation and Characterization of Hydrotalcite and Hydrotalcite like Compounds[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;1997-03
3 GOU Guo-Jing 1,2*, MA Pei-Hua1, CHU Min-Xiong1 (1. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810003, China; 2. Graduate School, Chinese Academy of Sciences, Beijing 100039, China);Dynamics of Intercalation of B_4O_5(OH)_4~(2-) Anion into Layered Double Hydroxides Intercalated by Cl~- Anion[J];Chemical Research In Chinese Universities;2005-03
4 YU Qin-Qin, WANG Shu, BAI Rong-Xian, MEI Fu-Ming, LI Guang-Xing* (Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074, China);Transesterification of Dimethyl Carbonate and Phenol Catalyzed by Zn-Al Hydrotalcite[J];Chemical Research In Chinese Universities;2005-08
5 GE Hong-yu, MA Wei-xing (Department of Chemical Engineering,Huaihai Instiute of Technology, Lianyungang 222005, Jiangsu China);Synthesis of ethyl 4-biphenylacetate catalyzed by SO~(2-)_4-MoO_3-TiO_2[J];Industrial Catalysis;2004-12
6 He Nanfeng, Cheng Yanxiang,Li Hua (College of Chemistry and Chemical Engineering,Henan University,Kaifeng,475001);A Study on Derivative UV-Spectrophotometric Method of Benzyl Alcohol and Benzaldehyde in Benzyl Alcohol Injection[J];JOURNAL OF HENAN UNIVERSITY (NATURAL SCIENCE);1997-02
7 Liao Dezhong, He Jieyu, Zhong Ming (Department of Chemical Engineering, Yueyang Normal College, Yueyang, Hunan 414000, China);Esterifications of Carboxylic Acids with Alcohols over A New Solid Acid[J];Chemistry;2003-05
8 GOU, Guo Jing , a,b MA, Pei Hua a CHU, Min Xiong a ( a Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008) ( b Graduate School, Chinese Academy of Sciences, Beijing 100039);Preparation and Basic Properties of Layered Double Hydroxides Intercalated by Chloride Anion[J];Acta Chimica Sinica;2004-21
9 YANG Hong-li,LI Wei-min,ZHENG Xiao-lin,LIN Xi-ping,WU Guo-ying (Department of Chemical Engineering,Jiangsu Polytechnic University,Changzhou 213164,China);Preparation of Hydrotalcite and the Application in Transesterification Reaction[J];Journal of Jiangsu Polytechnic University;2007-02
10 Yang Guiying,Liu Wenxia(Shandong Key Laboratory of Paper Engineering,Shandong Institute of Light Industry,Jinan,China,250353);The Preparation and Application of Hydrotalcite[J];China Non-Metallic Mining Industry Herald;2007-03
【Citations】
Chinese Journal Full-text Database 1 Hits
1 LI Lian-Sheng , HUI Jian-Bin, LIU Xin-Sheng, LIU Xiao-XunZHANG Yan-Qiu, XU Ru-Ren (Department of Chemistry, Jilin University, Changchun, 130023);Synthesis and Characterization of Hydrotalcite-Containing Rare Earth[J];Chemical Research In Chinese Universities;1993-08
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 BAO Yu-Min;LI Lian -Sheng ;MA Shu-Jie;XIONG De-Cheng;FU Ge-Yan;FENG Shou -Hua;XU Ru-Ren(Key Laboratory of Inorganic Hydrothermal Synthesis ,Jilin Uniuersity,Changchun,130023);Synthesis and Characterization of Hydrotalcite-like[Cd_xMg_(6-x)Al_2(OH)_(16)] ̄(2+)[S·2H_2O] ̄(2-)[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1996-03
2 Bao Yumin (College of science and Engineering, Inner Mongolia University for Nationalities, Tongliao 028043), Huaxue Shiji, 2003,25(2) ,104-106;Study on the luminescence quality of two-dimensional nano-luminous matter[J];Chemical Reagents;2003-02
3 Chen Chunxia 1,2 , Xu Chenghua 1, Feng Liangrong 1, Suo Jishuan 1, Qiu Fali 1 ( 1 Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041; 2 Graduate School of the Chinese Academy of Sciences, Beijing 100039);Catalytic Hydroxylation of Phenol over Pentatomic Hydrotalcite Prepared by Microwave Irradiation[J];Chemistry;2005-02
4 Yang Liangzhun, Du Lifen, Cao Fenglei, Chu Lianfeng and Jiang Jing (Biological and Chemical Engineering College, Shanghai Teacher's University, 201418);STUDY ON SYNTHESIS AND CATALYTIC BEHAVIOR OF HYDROTALCITELIKE COMPOUNDS FOR DEHYDROGENATION OF CYCLOHEXANOL TO CYCLOHEXANONE[J];Speciality Petrochemicals;2000-06
5 Yang Guiying,Liu Wenxia(Shandong Key Laboratory of Paper Engineering,Shandong Institute of Light Industry,Jinan,China,250353);The Preparation and Application of Hydrotalcite[J];China Non-Metallic Mining Industry Herald;2007-03
6 FU Ge-yan (College of Science and Engineering,Inner Mongolia University for Nationalities,Tongliao 028043,China);The Influence on Conductivity of the Metal Cation 〔Cdx Mg_(6-x)Al_2(OH)_(16)〕~(2+)〔S·2H_2O〕~(2-)[J];Journal of Inner Mongolia University for Nationalities(Natural Sciences,Quarterly);2001-04
7 FU Ge-yan (College of Science and Engineering,Inner Mongolia University for Nationalities,Tongliao 028043,China);Influence of Photoluminescence by Cd~(2+) Ion and Ni~(2+) Ion Content in the Host[J];Journal of Inner Mongolia University for Nationalities(Natural Sciences,Quarterly);2002-03
8 FANG Yutang,GUO Jinghua,LI Dayan,GAO Xuenong(Key Laboratory of Enhanced Heat Transfer & Energy Conservation,Ministry of Education,South China University of Technology,Guangzhou 510640,Guangdong,China);Characterization and performance of rare-earth modified molecular sieve[J];CIESC Journal;2011-06
9 Hou Wanguo,Li Zhiying,Song Shu'e,Sun Dejun (State Key Lab.for Colloid and Interface Chem.,of State Ministry of Education, Shandong Univ.,Jinan);STUDIES ON PREPARATION AND PROPERTIES OF Zn La Al HYDROXIDE NANOPARTICLES BY COPRECIPITATION[J];JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE EDITION);1999-03
10 YANG Gang, LONG Xiang-Yun (School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China);Preparation and Characterization of Layered Compound of Na_3Sb_3P_2O_(14)[J];Journal of Inorganic Materials;2001-03
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Qiu Tingsheng,Cheng Xianxiong,Hao Zhiwei,Luo Xianping (Southern Institute of Metallurgy,Ganzhou 341000,China);Present Situation and Development for Wastewater Containing Cadmium Treatment Technology[J];Sichuan Nonferrous Metals;2002-04
2 HU Xing,ZOU Guo-lin (College of Life Sciences, Wuhan University, Wuhan 430072, China);Biodegradable Polymeric Nanoparticles as Drug Delivery Systems[J];Amino Acids & Biotic Resources;2003-02
3 Zhao Donglin, Ph. D Dept of Material Science and Engineering, North Western Polytechnical University, Xi′an, P O Box 572,710072 Zhou Wancheng;RADAR ABSORBING COATING MATERIALS AND COATING STRUCTURE DESIGN[J];ORDNANCE MATERIAL SCIENCE AND ENGINEERING;1998-04
4 ZHOU Yan ting LI Feng DU Yi Bo D G Evans DUAN Xue (?Department of Applied Chemistry, Beijing University of Chemical Technology, Beijing 100029, China);The structure and catalytical property of layered double oxides and the application for preparing 1-methyl-2-ethoxyethyl acetate[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;2000-01
5 ZHANG Qiang LU Jie bin (College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China);Thermal stability and fluid properties of Poly(vinyl chloride) filled with hydrotalcite[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;2002-01
6 LI Lei ZHANG Chun ying DUAN Xue (The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China);Factors effecting UV absorbing property of nano-sized Zn-Al composite oxides[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;2002-02
7 WEN Zheng1 LI Lei1 CHEN DaZhou2 (1.School of Science,Beijing University of Chemical Technology,Beijing 100029;2.National Research Center for Certified Reference Materials,Beijing 100013,China);Preparation and characterization of materials obtained by co-intercalation of coumarin-3-carboxylic acid and 9-anthracene carboxylic acid into layered double hydroxides[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2007-05
8 Du Yibo He Jing Li Feng D G Evans Duan Xue Wang Zuoxin (Departmint of Applied Chemistry,Beijing University of Chemical Technology,Beijing,100029);The Preparation and Characterization of Hydrotalcite and Hydrotalcite like Compounds[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;1997-03
9 ZHANG Yong 1, HUANG Zhi-rong 1, FENG Zeng-guo 1, ZHANG Ai-ying 1, YE Ling 2, XU Rui-xing 2 (1.School of Material Science and Engineering, Beijing Institute of Technology, Beijing100081, China; 2.School of Primary Medicine, Capital Medical University, Beijing100054, China);Synthesis and Characterization of Polyether Ester Elastomer Based on Poly(Ethylene Glycol Terephthalate) and Poly (Butylene Terephthalate) with Different Soft Segment Length[J];Journal of Beijing Institute of Technology;2003-01
10 MA Yun,LIU Cun-hai~* (Chemistry & Chemical Engineering, Shaanxi University of Science & Technology, Xianyang 712081, China);Recovery and Application of Chrome from the High Concentration Wastewater[J];Surface Technology;2004-03
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LE Jin-dong,YU Shao-ming (School of Chemical Engineering,Hefei University of Technology,Hefei 230009,China);Treatment of Wastewater Containing Pb~(2+) by Synthesizing HTLCs in-situ[J];Anhui Chemical Industry;2010-01
2 GAO Deng-zheng et al(College of Chemical and Environmental Engineering,SUST,Qingdao,Shandong 266510);Preparation of Biodiesel from High Fatty Acid Oil by Heterogeneous Catalysis with Solid Acid and Solid Base[J];Journal of Anhui Agricultural Sciences;2010-03
3 ZHOU Yan ting LI Feng DU Yi Bo D G Evans DUAN Xue (?Department of Applied Chemistry, Beijing University of Chemical Technology, Beijing 100029, China);The structure and catalytical property of layered double oxides and the application for preparing 1-methyl-2-ethoxyethyl acetate[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;2000-01
4 LI Lei ZHANG Chun ying DUAN Xue (The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China);Factors effecting UV absorbing property of nano-sized Zn-Al composite oxides[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;2002-02
5 Wu Zheng Wei Min Zhang Fa zhi Shen Jun Duan Xue (The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China);Controllable study of interlayer distance of tartaric acid intercalated LDHs[J];Journal of Beijing University of Chemical Technology;2004-04
6 FENG Lin-sheng1 WANG Ge2 LI Feng1 WANG Yong-qiang1 David G Evans1 DUAN Xue1 (1.The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029; 2.School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China);Intercalation of molybdenum(Ⅵ)-containing complex anion into zinc aluminum layered double hydroxide carbonate[J];Journal of Beijing University of Chemical Technology;2005-04
7 CAO Yong GUO CanXiong WU DaMing(Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China);The conformation of sodium dodecylsulfate pillars in layered double hydroxides[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2007-02
8 Du Yibo He Jing Li Feng D G Evans Duan Xue Wang Zuoxin (Departmint of Applied Chemistry,Beijing University of Chemical Technology,Beijing,100029);The Preparation and Characterization of Hydrotalcite and Hydrotalcite like Compounds[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;1997-03
9 ZHAO Yun,HE Yang,JIN Zhong-bao,JIAO Qing-ze(School of Chemical Engineering and Environment,Beijing Institute of Technology,Beijing 100081,China);Catalytic Properties of Calcined Mg/Al Layered Double Hydroxides in the Synthesis of Glycol Ethers[J];Transactions of Beijing Institute of Technology;2009-04
10 YU SHan-xin1, LIU Mei-yan1, GUAN Shi-bin1, WEN Rui-ming2 (1. College of Chemistry and Chemical Engineering, Hunan Normal University, CHangsha Hunan 410081; 2. Department of Chemistry and Environmentally Engineering, Hunan City University, Yiyang Hunan 413000);Progress on Synthesis of Cyclohexanone 1,2-propylene Ketal Catalyzed by Solid Acid[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-03
China Proceedings of conference Full-text Database 3 Hits
1 GOU Guo-jing BAO Feng-juan YAO Hui-qin ZHENG Zhi-xiang XU Hong-ping (School of Basic Medical Science,Ningxia Medical College,Yinchuan 750004,China);Structure-capability relation of MgAl layered double hydroxide[A];[C];2008
2 Wu Mao-ying Tang Yu-fei Luo Yong- xin (Faculty of Chemical and Light Industry, Guangdong Univ.of Technol.,Guangzhou 510090,China);The Structure, Properties and Synthesis methods of Hydrotalcites and Its Application as Additives of Plastics[A];[C];2005
3 Xia Wei, Yu Ranbo, Yao Jianxi , Chen Yunfa , Wang Dan(Key Laboratory of Multi-Phase Reaction, Institute of Process Engineering Chinese Academy of Sciences, Beijing 100080, China;Graduate University of Chinese Academy of Sciences, Beijing 100039, China; Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083, China);Preparation and Electrochemical Property of Porous Iron Oxyhydroxide[A];[C];2006
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved